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Microstructure and Magnetic State of Fe3O4-SiO2 Colloidal Particles

  • Kharitonskii, P.V. (Saint Petersburg Electrotechnical University "LETI") ;
  • Gareev, K.G. (Saint Petersburg Electrotechnical University "LETI") ;
  • Ionin, S.A. (Saint Petersburg Electrotechnical University "LETI") ;
  • Ryzhov, V.A. (National Research Centre "Kurchatov Institute") ;
  • Bogachev, Yu.V. (Saint Petersburg Electrotechnical University "LETI") ;
  • Klimenkov, B.D. (Saint Petersburg Electrotechnical University "LETI") ;
  • Kononova, I.E. (Saint Petersburg Electrotechnical University "LETI") ;
  • Moshnikov, V.A. (Saint Petersburg Electrotechnical University "LETI")
  • 투고 : 2015.05.02
  • 심사 : 2015.08.24
  • 발행 : 2015.09.30

초록

Colloidal particles consisted of individual nanosized magnetite grains on the surface of the silica cores were obtained by two-stage sol-gel technique. Size distribution and microstructure of the particles were analyzed using atomic force microscopy, X-ray diffraction and Nitrogen thermal desorption. Magnetic properties of the particles were studied by the method of the longitudinal nonlinear response. It has been shown that nanoparticles of magnetite have a size corresponding to a superparamagnetic state but exhibit hysteresis properties. The phenomenon was explained using the magnetostatic interaction model based on the hypothesis of iron oxide particles cluster aggregation on the silica surface.

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