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Korean Society of Photoscience (한국광과학회)
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Crystal Structure Dependence for Reactivities of B12-TiO2 Hybrid Catalysts with Anatase and Rutile Forms

  • Shimakoshi, Hisashi (Department of Chemistry and Biochemistry, Graduate School of Engineering, Kyushu University) ;
  • Nagami, Yoko (Department of Chemistry and Biochemistry, Graduate School of Engineering, Kyushu University) ;
  • Hisaeda, Yoshio (Department of Chemistry and Biochemistry, Graduate School of Engineering, Kyushu University)
  • Received : 2015.03.02
  • Accepted : 2015.03.10
  • Published : 2015.03.01
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Abstract

The debromination of phenethyl bromide by the $B_{12}-TiO_2$ hybrid catalyst under UV light irradiation was investigated. The catalytic efficiency was dependent on the type of $TiO_2$. The anatase form of $TiO_2$ was superior to the rutile form of $TiO_2$. The selectivity of the product was also dependent on the crystal structure of $TiO_2$, and the rutile form of $TiO_2$ showed a high selectivity for the formation of the coupling product, 2,3-diphenylbutane, when compared to that of the anatase form of $TiO_2$.

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References

  1. Fox, M. A.; Dulay, M. T. Chem. Rev. 1993, 93, 341-357. https://doi.org/10.1021/cr00017a016
  2. Hoffmann, M. R.; Martin, S. T.; Choi, W.; Bahnemann, D. W. Chem. Rev. 1995, 95, 69-96. https://doi.org/10.1021/cr00033a004
  3. Fujishima, A.; Rao, T. N.; Tryk, D. A. J. Photochem. Photobiol., C 2000, 1, 1-21. https://doi.org/10.1016/S1389-5567(00)00002-2
  4. Ohtani, B. J. Photochem. Photobiol. C: Photochem. Rev. 2010, 11, 157-178. https://doi.org/10.1016/j.jphotochemrev.2011.02.001
  5. Shimakoshi, H.; Sakumori, E.; Kaneko, K.; Hisaeda, Y. Chem. Lett. 2009, 38, 468-469. https://doi.org/10.1246/cl.2009.468
  6. Shimakoshi, H.; Nishi, M.; Tanaka, A.; Chikama, K.; Hisaeda, Y. Chem. Lett. 2010, 39, 22-23. https://doi.org/10.1246/cl.2010.22
  7. Shimakoshi, H.; Abiru, M.; Kuroiwa, K.; Kimizuka, N.; Watanabe, M.; Hisaeda, Y. Bull. Chem. Soc. Jpn. 2010, 83, 170-172. https://doi.org/10.1246/bcsj.20090234
  8. Shimakoshi, H.; Abiru, M.; Izumi, S.; Hisaeda, Y. Chem. Commun. 2009, 6427-6429.
  9. Izumi, S.; Shimakoshi, H.; Hisaeda, Y. Dalton Trans. 2010, 39, 3302-3307. https://doi.org/10.1039/b921802e
  10. Shimakoshi, H.; Hisaeda, Y. ChemPlusChem 2014, 79, 1250-1253. https://doi.org/10.1002/cplu.201402081
  11. Proinsias, K. o; Giedyk, M.; Gryko, D. Chem. Soc. Rev. 2013, 42, 6605-6619. https://doi.org/10.1039/c3cs60062a
  12. Gruber, K.; Puffer, B.; Krautler, B. Chem. Soc. Rev. 2011, 40, 4346-4363. https://doi.org/10.1039/c1cs15118e
  13. Hisaeda, Y.; Shimakoshi, H. in Handbook of Porphyrin Science, Vol. 10 (Eds.: Kadish, K. M.; Smith, K. M.; Guilard R.), World Scientific Singapore, 2010, 313-370.
  14. Buckel, W.; Golding, B. T. Annun. Rev. Microbiol. 2006, 60, 7-49.
  15. Brown, K. L. Chem. Rev. 2005, 105, 2075-2149. https://doi.org/10.1021/cr030720z
  16. Toraya, T. Chem. Rev. 2003, 103, 2095-2127. https://doi.org/10.1021/cr020428b
  17. Banerjee, R.; Ragsdale, S. W. Annu. Rev. Biochem. 2003, 72, 209-247. https://doi.org/10.1146/annurev.biochem.72.121801.161828
  18. Murakami, Y.; Hisaeda, Y.; Kajihara, A.; Ohno, T. Bull. Chem. Soc. Jpn. 1984, 57, 405-411. https://doi.org/10.1246/bcsj.57.405
  19. Murakami, Y,; Hisaeda, Y.; Kajihara, A. Bull. Chem. Soc. Jpn. 1983, 56, 3642-3647. https://doi.org/10.1246/bcsj.56.3642
  20. Parussulp, A. L. A.; Bonacin, J. A.; Toma, S. H.; Araki, K.; Toma, H. E. Langmuir, 2009, 25, 11269-11271. https://doi.org/10.1021/la902551k
  21. A. Sclafani, J. M. Herrmann, J. Phys. Chem., 1996, 100, 13655-13661. https://doi.org/10.1021/jp9533584
  22. T. Luttrell, S. Halpegamage, J. Tao, A. Kramer, E. Sutter, M. Batzill, Sci. Rep., 2014, 4, 4043-4050.
  23. W. Kim, T. Tachikawa, G. Moon, T. Majima, W. Choi, Angew. Chem. Int. Ed. 2014, 53, 14036-14041. https://doi.org/10.1002/anie.201406625

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