Browse > Article
http://dx.doi.org/10.5857/RCP.2015.4.1.9

Crystal Structure Dependence for Reactivities of B12-TiO2 Hybrid Catalysts with Anatase and Rutile Forms  

Shimakoshi, Hisashi (Department of Chemistry and Biochemistry, Graduate School of Engineering, Kyushu University)
Nagami, Yoko (Department of Chemistry and Biochemistry, Graduate School of Engineering, Kyushu University)
Hisaeda, Yoshio (Department of Chemistry and Biochemistry, Graduate School of Engineering, Kyushu University)
Publication Information
Rapid Communication in Photoscience / v.4, no.1, 2015 , pp. 9-11 More about this Journal
Abstract
The debromination of phenethyl bromide by the $B_{12}-TiO_2$ hybrid catalyst under UV light irradiation was investigated. The catalytic efficiency was dependent on the type of $TiO_2$. The anatase form of $TiO_2$ was superior to the rutile form of $TiO_2$. The selectivity of the product was also dependent on the crystal structure of $TiO_2$, and the rutile form of $TiO_2$ showed a high selectivity for the formation of the coupling product, 2,3-diphenylbutane, when compared to that of the anatase form of $TiO_2$.
Keywords
cobalamin; $B_{12}$; $TiO_2$; crystal form; anatase; rutile;
Citations & Related Records
연도 인용수 순위
  • Reference
1 Fox, M. A.; Dulay, M. T. Chem. Rev. 1993, 93, 341-357.   DOI
2 Hoffmann, M. R.; Martin, S. T.; Choi, W.; Bahnemann, D. W. Chem. Rev. 1995, 95, 69-96.   DOI   ScienceOn
3 Fujishima, A.; Rao, T. N.; Tryk, D. A. J. Photochem. Photobiol., C 2000, 1, 1-21.   DOI   ScienceOn
4 Ohtani, B. J. Photochem. Photobiol. C: Photochem. Rev. 2010, 11, 157-178.   DOI   ScienceOn
5 Shimakoshi, H.; Sakumori, E.; Kaneko, K.; Hisaeda, Y. Chem. Lett. 2009, 38, 468-469.   DOI   ScienceOn
6 Shimakoshi, H.; Nishi, M.; Tanaka, A.; Chikama, K.; Hisaeda, Y. Chem. Lett. 2010, 39, 22-23.   DOI   ScienceOn
7 Shimakoshi, H.; Abiru, M.; Kuroiwa, K.; Kimizuka, N.; Watanabe, M.; Hisaeda, Y. Bull. Chem. Soc. Jpn. 2010, 83, 170-172.   DOI   ScienceOn
8 Shimakoshi, H.; Abiru, M.; Izumi, S.; Hisaeda, Y. Chem. Commun. 2009, 6427-6429.
9 Izumi, S.; Shimakoshi, H.; Hisaeda, Y. Dalton Trans. 2010, 39, 3302-3307.   DOI   ScienceOn
10 Shimakoshi, H.; Hisaeda, Y. ChemPlusChem 2014, 79, 1250-1253.   DOI
11 Proinsias, K. o; Giedyk, M.; Gryko, D. Chem. Soc. Rev. 2013, 42, 6605-6619.   DOI   ScienceOn
12 Gruber, K.; Puffer, B.; Krautler, B. Chem. Soc. Rev. 2011, 40, 4346-4363.   DOI   ScienceOn
13 Hisaeda, Y.; Shimakoshi, H. in Handbook of Porphyrin Science, Vol. 10 (Eds.: Kadish, K. M.; Smith, K. M.; Guilard R.), World Scientific Singapore, 2010, 313-370.
14 Buckel, W.; Golding, B. T. Annun. Rev. Microbiol. 2006, 60, 7-49.
15 Brown, K. L. Chem. Rev. 2005, 105, 2075-2149.   DOI   ScienceOn
16 Toraya, T. Chem. Rev. 2003, 103, 2095-2127.   DOI   ScienceOn
17 Banerjee, R.; Ragsdale, S. W. Annu. Rev. Biochem. 2003, 72, 209-247.   DOI   ScienceOn
18 Murakami, Y.; Hisaeda, Y.; Kajihara, A.; Ohno, T. Bull. Chem. Soc. Jpn. 1984, 57, 405-411.   DOI
19 Murakami, Y,; Hisaeda, Y.; Kajihara, A. Bull. Chem. Soc. Jpn. 1983, 56, 3642-3647.   DOI
20 Parussulp, A. L. A.; Bonacin, J. A.; Toma, S. H.; Araki, K.; Toma, H. E. Langmuir, 2009, 25, 11269-11271.   DOI   ScienceOn
21 A. Sclafani, J. M. Herrmann, J. Phys. Chem., 1996, 100, 13655-13661.   DOI   ScienceOn
22 T. Luttrell, S. Halpegamage, J. Tao, A. Kramer, E. Sutter, M. Batzill, Sci. Rep., 2014, 4, 4043-4050.
23 W. Kim, T. Tachikawa, G. Moon, T. Majima, W. Choi, Angew. Chem. Int. Ed. 2014, 53, 14036-14041.   DOI   ScienceOn