Corrosion Science and Technology

The Corrosion Science Society of Korea (한국부식방식학회)
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Corrosion Behaviors of Structural Materialsin High Temperature S-CO2 Environments

  • Lee, Ho Jung (Department of Nuclear and Quantum Engineering, KAIST) ;
  • Kim, Hyunmyung (Department of Nuclear and Quantum Engineering, KAIST) ;
  • Jang, Changheui (Department of Nuclear and Quantum Engineering, KAIST)
  • Received : 2014.04.29
  • Accepted : 2014.04.29
  • Published : 2014.04.30
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Abstract

The isothermal corrosion tests of several types of stainless steels, Ni-based alloys, and ferritic-martensitic steels (FMS) were carried out at the temperature of 550 and $650^{\circ}C$ in SFR S-$CO_2$ environment (200 bar) for 1000 h. The weight gain was greater in the order of FMSs, stainless steels, and Ni-based alloys. For the FMSs (Fe-based with low Cr content), a thick outer Fe oxide, a middle (Fe,Cr)-rich oxide, and an inner (Cr,Fe)-rich oxide were formed. They showed significant weight gains at both 550 and $650^{\circ}C$. In the case of austenitic stainless steels (Fe-based) such as SS 316H and 316LN (18 wt.% Cr), the corrosion resistance was dependent on test temperatures except SS 310S (25 wt.% Cr). After corrosion test at $650^{\circ}C$, a large increase in weight gain was observed with the formation of outer thick Fe oxide and inner (Cr,Fe)-rich oxide. However, at $550^{\circ}C$, a thin Cr-rich oxide was mainly developed along with partially distributed small and nodular shaped Fe oxides. Meanwhile, for the Ni-based alloys (16-28 wt.% Cr), a very thin Cr-rich oxide was developed at both test temperatures. The superior corrosion resistance of high Cr or Ni-based alloys in the high temperature S-$CO_2$ environment was attributed to the formation of thin Cr-rich oxide on the surface of the materials.

Keywords

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