보존과학회지 (Journal of Conservation Science)

  • 제29권3호
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  • Pages.197-207
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  • 2013
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  • 1225-5459(pISSN)
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  • 2287-9781(eISSN)
한국문화재보존과학회 (The Korean Society Of Conservation Science For Cultural Heritage)
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이산화질소(NO2) 농도에 따른 전통직물의 손상 특성

Damage Characteristics of Korean Traditional Textiles by Nitrogen Dioxide (NO2) Concentrations

  • 김명남 (국립문화재연구소 보존과학연구실) ;
  • 임보아 (국립문화재연구소 보존과학연구실) ;
  • 김서진 (국립해양문화재연구소 수중발굴과) ;
  • 이선명 (국립문화재연구소 보존과학연구실)
  • Kim, Myoung Nam (Conservation Science Division, National Research Institute of Cultural Heritage) ;
  • Lim, Bo A (Conservation Science Division, National Research Institute of Cultural Heritage) ;
  • Kim, Seojin (Underwater Excavation & Conservation Division, National Research Institute of Maritime Cultural Heritage) ;
  • Lee, Sun Myung (Conservation Science Division, National Research Institute of Cultural Heritage)
  • 투고 : 2013.06.03
  • 심사 : 2013.09.04
  • 발행 : 2013.09.20
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초록

이산화질소($NO_2$) 농도에 따른 전통직물의 손상특성을 정량적으로 확인하고자 가스 열화실험을 수행하였다. 견, 면, 모시, 삼베의 무염색직물 시편, 천연염색(적색, 황색, 청색, 흑색)직물 시편을 온도 $20^{\circ}C$, 습도 50%, 환기횟수 1/hr 조건의 가스부식시험기 챔버 내에서 $NO_2$ 0.01, 0.1, 1, 10, 100, 1000 ppm 농도로 각각 1일 노출한 후 광학적, 화학적, 물리적 측정방법으로 손상도를 평가하였다. 이 결과, 전통직물은 $NO_2$ 1 ppm/day에서 색차 증가, 변퇴색등급 저하가 나타났고, 10 ppm/day에서 질산이온($NO_3{^-}$) 농도 증가, pH 감소, 카르보닐기 및 C-$NO_2$ 작용기 증가가 나타났으며, 100 ppm/day에서 인장강도 감소가 나타났다. 또한 무염색직물에서는 견, 삼베의 색차 증가, 삼베의 $NO_3{^-}$ 증가 및 인장강도 감소가 크게 나타났고, 염색직물에서는 청색, 황색직물의 색차 증가, 황색직물의 $NO_3{^-}$ 증가, 삼베, 모시의 인장강도 감소가 크게 나타났다. 이를 통해 $NO_2$에 의한 전통직물의 광학적, 화학적, 물리적 손상농도는 각각 1 ppm/day, 10 ppm/day, 100 ppm/day임을 도출하였다.

The gas acceleration test was conducted to identify the deterioration of Korean traditional textiles caused by $NO_2$. Total 20 specimens were prepared using 4 different materials (silk, cotton, ramie, hemp) after dyeing with 5 colors (undyed, red, yellow, blue, black). The specimens were exposed to 0.01, 0.1, 1, 10, 100, and 1000 ppm $NO_2$ gas in the test chamber at $20^{\circ}C$, 50% RH for 1 day. Optical, chemical, and physical evaluation was carried out after the exposure. In the case of Korean traditional textile, color difference increased at 1 ppm/day, $NO_3{^-}$ concentration, carbonyl and C-$NO_2$ functional group increased while pH decreased at 10 ppm/day and tensile strength weakened at 100 ppm/day. when it comes to undyed textile, alteration of color difference on silk and hemp cloth, $NO_3{^-}$ concentration and tensile strength on hemp cloth was remarkable. In addition, color difference on blue and yellow textile, $NO_3{^-}$ concentration increase of yellow textile and tensile strength decrease of hemp cloth & ramie cloth were significant. The results suggest that critical $NO_2$ concentration of optical, chemical, and physical damage on Korean traditional textiles are 1ppm/day, 10 ppm/day, 100 ppm/day respectively.

키워드

참고문헌

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피인용 문헌

  1. Studies on the Accelerated Aging Characteristics of Paper Records by Gaseous Air Pollutants vol.47, pp.4, 2015, https://doi.org/10.7584/ktappi.2015.47.4.151
  2. Damage Characteristics of Korean Traditional Textiles by Acetaldehyde vol.32, pp.3, 2016, https://doi.org/10.12654/JCS.2016.32.3.03