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Kinetics of Reversible Consecutive Reactions

  • 투고 : 2012.09.25
  • 심사 : 2012.10.30
  • 발행 : 2013.01.20

초록

Rate equations are exactly solved for the reversible consecutive reaction of the first-order and the time-dependence of concentrations is analytically determined for species in the reaction. With the assumption of pseudo first-order reaction, the calculation applies and determines the concentration of product accurately and explicitly as a function of time in the unimolecular decomposition of Lindemann and in the enzyme catalysis of Michaelis-Menten whose rate laws have been approximated in terms of reactant concentrations by the steady-state approximation.

키워드

참고문헌

  1. Houston, P. Chemical Kinetics and Reaction Dynamics; McGraw-Hill: Singapore, 2001; p 61.
  2. Gradshteyn, I. S.; Ryzhik, I. M. Table of Integrals, Series, and Products; Academic Press: Orlando, 1980; p 68.
  3. Cole, S. L.; Wilder, J. W. SIAM J. Appl. Math. 1991, 51(6), 1489. https://doi.org/10.1137/0151074
  4. Metiu, H. Physical Chemistry, Kinetics; Taylor & Francis: New York, 2006; p 148.

피인용 문헌

  1. Chemical Kinetics of Consecutive and Parallel Reactions Both with a Reversible First Step vol.36, pp.9, 2015, https://doi.org/10.1002/bkcs.10428
  2. Mechanistic Studies on Alcoholysis of α-Keto esters vol.35, pp.12, 2013, https://doi.org/10.5012/bkcs.2014.35.12.3423