• Title/Summary/Keyword: Lindemann mechanism

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Kinetics of Reversible Consecutive Reactions

  • Park, Tae Jun
    • Bulletin of the Korean Chemical Society
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    • v.34 no.1
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    • pp.243-245
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    • 2013
  • Rate equations are exactly solved for the reversible consecutive reaction of the first-order and the time-dependence of concentrations is analytically determined for species in the reaction. With the assumption of pseudo first-order reaction, the calculation applies and determines the concentration of product accurately and explicitly as a function of time in the unimolecular decomposition of Lindemann and in the enzyme catalysis of Michaelis-Menten whose rate laws have been approximated in terms of reactant concentrations by the steady-state approximation.