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Simultaneous reduction and functionalization of graphene oxide by polyallylamine for nanocomposite formation

  • Kim, Young-Kwan (Department of Chemistry, Korea Advanced Institute of Science and Technology) ;
  • Min, Dal-Hee (Department of Chemistry, Seoul National University)
  • Received : 2011.08.15
  • Accepted : 2011.12.10
  • Published : 2012.01.31

Abstract

A novel strategy for the simultaneous reduction and functionalization of graphene oxide (G-O) was developed using polyallylamine hydrochloride (PAAH) as a multi-functional agent. The G-O functionalization by PAAH was carried out under basic conditions to catalyze the epoxide ring opening reaction of G-O with abundant amine groups of PAAH. We found that G-O was not only functionalized with PAAH but also reduced under the reaction condition. Moreover, the synthesized PAAH-functionalized G-O sheets were soluble in water and applicable to the synthesis of nanocomposites with gold nanoparticles.

Keywords

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