DOI QR코드

DOI QR Code

시설재배 쪽파와 부추에서 살충제 Bifenthrin과 Chlorfenapyr의 잔류특성 비교

Comparision of the Residue Property of Insecticide Bifenthrin and Chlorfenapyr in Green Onion and Scallion under Greenhouse Condition

  • 박종우 ((주)분석기술과 미래) ;
  • 손경애 (국립농업과학원 농산물안전성부) ;
  • 김태화 ((주)분석기술과 미래) ;
  • 채석 ((주)분석기술과 미래) ;
  • 심재룡 ((주)분석기술과 미래) ;
  • 배병진 ((주)한국생물안전성연구소) ;
  • 이해근 ((주)한국생물안전성연구소) ;
  • 임건재 (국립농업과학원 농산물안전성부) ;
  • 김진배 (국립농업과학원 농산물안전성부) ;
  • 김장억 (경북대학교 응용생명과학부)
  • 투고 : 2012.11.07
  • 심사 : 2012.12.11
  • 발행 : 2012.12.31

초록

일시에 수확하는 경채류 중 쪽파와 부추에 대한 살충제 bifenthrin와 chlorfenapyr의 잔류특성을 비교 조사하였다. 수확일을 기준으로 각각 1주일 간격으로 2회 살포한 후 수확당일, 수확 3일 전, 수확 7일 전, 수확 10일 전 및 수확 14일 전에 시료를 수거하여 잔류량을 조사하였다. 수확당일의 잔류량을 기초하여 작물 중 농약살포액의 부착량을 환산한 결과, 쪽파의 경우 123.0-125.5 mL/kg, 그리고 부추에서는 70.0-74 mL/kg으로 조사되어 쪽파가 부추에 비해 더 많은 살포액이 부착될 수 있는 것으로 나타났다. 각 작물에서 bifenthrin과 chlorfenapyr의 생육기간 중 농약의 분해소실 정도를 조사한 결과, 쪽파에서 bifenthrin의 분해소실곡선은 y = 1.0334 $e^{-0.0602x}$ ($R^2$= 0.8606), chlorfenapyr는 y = 2.2603 $e^{-0.0519x}$ ($R^2$= 0.9043)이었으며, 부추에서는 bifentrhin의 경우, y = 0.7693 $e^{-0.1823x}$ ($R^2$= 0.9756), chlorfenapyr는 y = 1.2940 $e^{-0.1051x}$ ($R^2$= 0.9782)으로 나타났다. 이 분해소실곡선을 이용하여 각 작물에서 두 농약의 분해반감기를 조사한 결과, bifenthrin의 경우, 쪽파에서 분해반감기는 11.51일이었으며, 부추에서는 3.80일로서 쪽파에서의 분해 반감기가 더 긴 것으로 나타났으며, chlorfenapyr의 경우에서도 쪽파 13.35일, 부추 6.59일로 쪽파에서의 분해반감기가 더 길었다. 쪽파와 부추에서 두 농약의 잔류특성이 비교되었을 때 농약살포 후 살포액의 부착량과 작물생육기간 중 농약의 분해반감기는 부추에서보다는 쪽파에서 더 많거나 긴 것으로 나타났다.

In order to use in the classification of minor crop for the mutual application of safe use guideline, it was compared a green onion with a scallion on the residue property of insecticide bifenthrin and chlorfenapyr. After pesticides were applied 2 times with 1 week interval in that day of harvest, 3 days, 7 days, 10 days and 14 days before harvest, vegetables were harvested, and the residue of pesticides was investigated. Base on the residue in that day of harvest, the deposit of spray solution in vegetables was calculated. The deposit of spray solution of bifenthrin was 123.0 mL/kg in a green onion, and 74 mL/kg in a scallion. In case of chlorfenapyr, it was calculated 126.5 mL/kg in a green onion, and 70.0 mL/kg in a scallion. When the amount of the deposit of both pesticides was compared a green onion with a scallion, it was higher in a green onion. On the other hand, it was estimated the predicted dissipation curve of pesticides in a green onion and a scallion during cultivation. The dissipation curve of bifenthrin was y = 1.0334 $e^{-0.0602x}$ ($R^2$= 0.8606) in a green onion, and y = 0.7693 $e^{-0.1823x}$ ($R^2$= 0.9756) in a scallion. In case of chlorfenapyr, it was y = 2.2603 $e^{-0.0519x}$ ($R^2$= 0.9043) in a green onion, and y = 1.2940 $e^{-0.1051x}$ ($R^2$ = 0.9782) in a scallion. The half-life of bifenthrin was 11.51 days in a green onion, and 3.80 days in a scallion, respectively. Also, it was estimated half-life in chlorfenapyr, it was 13.35 days in a green onion, and 6.59 days in a scallion, respectively. The half-life of both pesticides in a green onion was longer than in a scallion. When both vegetables were compared with the residue property, the deposit of spray solution and half-life of dissipation in a green onion were more than those in a scallion.

키워드

참고문헌

  1. Ghidiu, G. M. and P. E. Neary (1994) An Extension Perspective of the Minor Use Crops Pesticide Problem in Vegetable Production. J Extension. 32(1), http://www.joe.org/joe/1994-june/a5.php.
  2. Jung, Y. H., J. E. Kim, J. H. Kim, Y. D. Lee, C. H. Im and J. Y. Huh (2004) New Pesticides. pp. 341-361, Sigma Press Inc., Korea.
  3. Kim, J. B., B. H. Song, J. C. Chun, G. J. Im and Y. B. Im (1997) Effect of Sprayable Formulations on Pesticide Adhesion and Persistence in Several Crops. The Korean Journal of Pesticide Science 1(1):35-40.
  4. Korea Crop Protection Association (2010) Guideline of Pesticides Use. pp.526, Samjeong Press Inc., Korea.
  5. Kwon, H. Y., J. H. Kim, H. D. Lee, Y. B. Ihm, K. S. Kyung, I. H. Park and J. Choi (2004) Estimate of Pesticide Residues in Tomato Varieties using Ratio of Surface Area Weight. The Korean Journal of Pesticide Science 8(1):30-37.
  6. Marin, A., J. Oliva, C. Garcia, S. Navarro and A. Barba (2003) Dissipation Rates of Cyprodinil and Fludioxonil in Lettuce and Table Grape in the Field and under Cold Storage Conditions. J. Agric. Food Chem. 51(16):4708-4711. https://doi.org/10.1021/jf021222e
  7. Ministry for Food, Agriculture, Agricultural and Marine Products Quality Control Act (2006) Act 9117. Chapter 2.
  8. Lee, H. D., K. S. Kyung, H. Y. Kwon, Y. B. Ihm, J. B. Kim, S. S. Park and J. E. Kim (2004) Residue characteristics hexaconazole and chlorothalonil in several friuts. The Korean Journal of Pesticide Science 8(2):107-111.
  9. Lee, J. H., H. W. Park, Y. S. Keum, C. H. Kwon, Y. D. Lee and J. H. Kim (2008) Dissipation Pattern of Boscalid in Cucumber under Greenhouse Condition. The Korean Journal of Pesticide Science 12(1):67-73.
  10. Lee, M. G., M. G. Hong, K. S. Park, D. M. Choi, M. H. Lim and S. R. Lee (2005) Procedures in Establishing Residue Limits of Pesticides on Food Crops in Korea. Korean Society of Food Science and Technology 37(4):685-694.
  11. Park, G. S., M. H. Im, D. M. Choi, J. Y. Jeong, M. I. Chang, K. I. Kwon, M. K. Hong and C. W. Lee (2005) Establishment of Korean Maximum Residue Limits for Pesticides in Foods. The Korean Journal of Pesticide Science 9(1):51-59.

피인용 문헌

  1. Residual Characteristics and Safety Assessments of Bifenthrin, Carbendazim and Metconazole in Angelica gigas Nakai vol.21, pp.1, 2017, https://doi.org/10.7585/kjps.2017.21.1.97
  2. Study on Residual Properties of Dimethomorph and Pyraclostrobin in the Amaranthus (Amaranthus mangostanus L.) vol.22, pp.3, 2018, https://doi.org/10.7585/kjps.2018.22.3.166
  3. Residual Characteristics and Safety Assessments of the Fungicide Fenhexamid in Some Minor Crops vol.22, pp.4, 2018, https://doi.org/10.7585/kjps.2018.22.4.363
  4. 소면적 재배 작물 들깻잎 중 살충제 Bifenthrin과 Chlorfenapyr의 잔류양상 vol.34, pp.3, 2012, https://doi.org/10.5338/kjea.2015.34.3.29
  5. Residual Characteristic of Fungicide Tebuconazole in Chinese chives(Allium tuberosum R.) under Greenhouse Condition vol.23, pp.3, 2012, https://doi.org/10.7585/kjps.2019.23.3.220
  6. Reduction of Pesticide Residues in Korean melon after Washing and Peeling vol.24, pp.1, 2012, https://doi.org/10.7585/kjps.2020.24.1.51