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A New Rhodamine B-coumarin Fluorochrome for Colorimetric Recognition of Cu2+ and Fluorescent Recognition of Fe3+ in Aqueous Media

  • Tang, Lijun (College of Chemistry and Chemical Engineering, Liaoning Key Laboratory for the Synthesis and Application of Functional Compounds, Bohai University) ;
  • Li, Fangfang (College of Chemistry and Chemical Engineering, Liaoning Key Laboratory for the Synthesis and Application of Functional Compounds, Bohai University) ;
  • Liu, Minghui (College of Chemistry and Chemical Engineering, Liaoning Key Laboratory for the Synthesis and Application of Functional Compounds, Bohai University) ;
  • Nandhakumar, Raju (Department of Chemistry, Karunya University)
  • Received : 2011.06.14
  • Accepted : 2011.07.29
  • Published : 2011.09.20

Abstract

A new rhodamine B-coumarin conjugate (1) capable of recognizing both $Cu^{2+}$ and $Fe^{3+}$ using two different detection modes have been designed and synthesized. The metal ion induced optical changes of 1 were investigated in $CH_3CN-H_2O$ (1:1, v/v, HEPES 50 mM, pH = 7.0) solution. Sensor 1 exhibits selective colorimetric recognition of $Cu^{2+}$ and fluorescent recognition of $Fe^{3+}$ with UV-vis and fluorescence spectroscopy, respectively. Moreover, both of the $Cu^{2+}$ and $Fe^{3+}$ recognition processes are observed to be barely interfered by other coexisting metal ions.

Keywords

References

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