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http://dx.doi.org/10.5012/bkcs.2011.32.9.3400

A New Rhodamine B-coumarin Fluorochrome for Colorimetric Recognition of Cu2+ and Fluorescent Recognition of Fe3+ in Aqueous Media  

Tang, Lijun (College of Chemistry and Chemical Engineering, Liaoning Key Laboratory for the Synthesis and Application of Functional Compounds, Bohai University)
Li, Fangfang (College of Chemistry and Chemical Engineering, Liaoning Key Laboratory for the Synthesis and Application of Functional Compounds, Bohai University)
Liu, Minghui (College of Chemistry and Chemical Engineering, Liaoning Key Laboratory for the Synthesis and Application of Functional Compounds, Bohai University)
Nandhakumar, Raju (Department of Chemistry, Karunya University)
Publication Information
Bulletin of the Korean Chemical Society / v.32, no.9, 2011 , pp. 3400-3404 More about this Journal
Abstract
A new rhodamine B-coumarin conjugate (1) capable of recognizing both $Cu^{2+}$ and $Fe^{3+}$ using two different detection modes have been designed and synthesized. The metal ion induced optical changes of 1 were investigated in $CH_3CN-H_2O$ (1:1, v/v, HEPES 50 mM, pH = 7.0) solution. Sensor 1 exhibits selective colorimetric recognition of $Cu^{2+}$ and fluorescent recognition of $Fe^{3+}$ with UV-vis and fluorescence spectroscopy, respectively. Moreover, both of the $Cu^{2+}$ and $Fe^{3+}$ recognition processes are observed to be barely interfered by other coexisting metal ions.
Keywords
Chemosensor; Colorimetric; Fluorescent; Rhodamine B; Recognition;
Citations & Related Records
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Times Cited By Web Of Science : 2  (Related Records In Web of Science)
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