The Effect of Crystallization of SLS Glass for Bulletproof Materials

방탄소재 활용을 위한 SLS 유리 결정화의 효과

  • Received : 2009.09.10
  • Accepted : 2009.11.20
  • Published : 2010.01.05

Abstract

For application of transparent bulletproof materials, the SLS(soda-lime-silicate) glass was heated by 2-step crystallization. The DTA curve for SLS glass revealed the nucleation and crystal growth temperature at about $575^{\circ}C$ and $675^{\circ}C$, respectively. The crystallized glass was heated at various conditions(temperature, time). As a result, the maximum nucleation and crystal growth rates were $3.8\times10^5/mm^3{\cdot}hr$ at $575^{\circ}C$ and 20.58nm/min at $680^{\circ}C$, respectively. The bending strength, fracture toughness and vickers hardness were 451.7MPa, $0.9388MPa{\cdot}m^{1/2}$, and $693.9H_v$ which were 201%, 31%, and 22% higher than parent glass, respectively. Surface image and transmittance of crystallized SLS glass were analyzed by optical microscopy and UV/VIS/NIR spectrophotometer. Transmittance of crystallized SLS glass at visible-range(200~800nm) was not changed.

Keywords

References

  1. M. Roskosz, M. J. Toplis and P. Richet, Kinetic vs. Thermodynamic Control of Crystal Nucleation and Growth in Molten Silicates, Journal of Non-Crystalline Solid, Vol. 352, pp. 180-184, 2006. https://doi.org/10.1016/j.jnoncrysol.2005.11.009
  2. V. P. Pukh, L. G. Baikova, M. F. Kireenko, L. V. Tikhonova, T. P. Kazannikova, and A. B. Sinani, Atomic Structure and Strength of Inorganic Glasses, Physis of the Solid State, Vol. 47, No. 5, pp. 876-881, 2005. https://doi.org/10.1134/1.1924848
  3. M. Suszy, L. Krajczyk and Z. Mazurkiewicz, TEM Studies of Silver Nanoparticles in Phase-Separated Soda Lime Silicate Glasses, Materials Chemistry and Physsics, Vol. 81, pp. 404-406, 2003. https://doi.org/10.1016/S0254-0584(03)00033-6
  4. S. M. Song, S. Y. Choi, Y. K. Lee, Crystallization Property Effects in Ge30Se60Te10 Glass, J. Non-Cryst. Solids, Vol. 217, pp. 79-82, 1997 https://doi.org/10.1016/S0022-3093(97)00136-1
  5. S. B. Sohn, Y. K. Lee, S. Y. Choi, Controlled Crystallization and Characterization of Cordierite Glass-Ceramics for Magnetic Memory Disk Substrate, Journal of Materials Science, Vol. 35, pp. 4815-4821, 2000. https://doi.org/10.1023/A:1004876829705
  6. S. B. Sohn and S. Y. Choi, Crystallization Behavior in the Glass System $MgO-Al_{2}O_{3}-SiO_{2}$ : Influence of $CeO_{2}$ Addition, Journal of Non-Crystalline Solid, Vol. 282, pp. 221-227, 2001. https://doi.org/10.1016/S0022-3093(01)00344-1
  7. S. Y. Choi, G. H. Frischat, Influence of Crystallization on Some Properties of $ZrF_{4}-BaF_{2}-YF_{3}-AlF_{3}$ Glasses, J. Non-Cryst. Solids, Vol. 129, pp. 133-136, 1991 https://doi.org/10.1016/0022-3093(91)90088-N
  8. H. J. Kim, M. K. Lee, S. Y. Choi, A Study on the Transparent Armor Materials with High Efficiency Nano Ceramics(Contract No. : UD080040GD), 2nd-Year Research Report of Agency for Defense Development, 2009.