한국이 탐사 중인 해저광물자원의 희유금속 함량과 의미

Rare Metal Contents and Their Implications of Seabed Mineral Resources Explored by Korea

  • 박상준 (한국해양연구원 심해.해저자원연구부) ;
  • 문재운 (한국해양연구원 심해.해저자원연구부) ;
  • 이경용 (한국해양연구원 심해.해저자원연구부) ;
  • 지상범 (한국해양연구원 심해.해저자원연구부)
  • Pak, Sang-Joon (Deep-sea & Marine Georesources Research Department, Korea Ocean Research & Development Institute) ;
  • Moon, Jai-Woon (Deep-sea & Marine Georesources Research Department, Korea Ocean Research & Development Institute) ;
  • Lee, Kyeong-Yong (Deep-sea & Marine Georesources Research Department, Korea Ocean Research & Development Institute) ;
  • Chi, Sang-Bum (Deep-sea & Marine Georesources Research Department, Korea Ocean Research & Development Institute)
  • 투고 : 2010.10.01
  • 심사 : 2010.10.20
  • 발행 : 2010.10.28

초록

한국이 현재 탐사하고 있는 해저광물자원의 유형은 망간단괴, 망간각, 다금속황화광체 등으로 구분된다. 망간단괴에 함유되어 있는 주요 희소금속은 Pt로 지각함량 대비 최대 400 배까지 부화되어 있다. 망간단괴의 총 희토류 함량은 0.037~0.302 REO %, 평균 0.12 REO %를 보인다. 망간각의 주요 희소금속은 Te 및 Pt로 각각 10800 배, 150배 정도의 부화량을 보인다. 총 희토류 함량은 0.013-0.387 REO %, 평균 0.18 REO %로 망간단괴 보다 다소 높은 함량을 보인다. 다금속화황광체의 주요 희소금속은 Se 및 In으로 각각 1300 배, 110 배의 높은 부화량을 보이며, 금(0.8~26.3 g/t), 은(0.9~348.0 g/t) 등의 귀금속이 함유된다. 해저광물자원에 함유되어 있는 희유금속은 채광 예상 금속 종인 Co, Ni, Cu 등의 채광 경제성을 높여 줄 것으로 생각되며 첨단산업을 위한 희유금속 확보 차원에서 의미가 있다.

Seabed mineral resources explored by Korea are categorized into major three types of deposit; manganese nodule, manganese crust and polymetallic sulfides. Pt displays high enrichment factors (400, ore/crust ratios) in manganese nodule. Rare earth oxide content in manganese nodule ranges from 0.037 to 0.302 REO % with mean value of 0.12 REO %. Both of Te and Pt are enriched elements in manganese crust, displaying enrichment factors of 10800 and 150, respectively. Rare earth oxide's contents of manganese crust are slightly higher than manganese nodule's (0.013~0.387 REO %, average = 0.18 REO %). Se and In are outstanding rare metals from seabed polymetallic sulfides, showing enrichment factors of 1300 and 110, respectively. Au (0.8~26.3 g/t) and Ag (0.9~348.0 g/t) are another enriched elements in polymetallic sulfides. The main concern at exploiting seabed mineral resource will be a securing rare metals for high-technology industries and rare metals from subsea mineral deposits will add economic values to commodity candidates such like Co, Ni and Cu.

키워드

참고문헌

  1. Arafura Resources Limited, website, http://www.arafuraresources.com.au/ (May, 2010)
  2. Banerjee, R. (2004). Manganese nodules as a possible source of precious metals. Current Science, v.87, p.278-279.
  3. Castor, S.B. and Hedrick, J.B. (2006) Rare earth elements. In Kogel, J. E., Trivedi, N.C., Barker, J.M. (eds.) Industrial Minerals and Rocks. 7th Edition. Society for Mining, Metallurgy and Exploration. Littleton, Colorado, p.769-792.
  4. Choi, Y.-J., Woo, K.-S., Park, S.-H., Jung, H.-S., Moon, J.- W. and Lee, K.-Y. (2001) Textural and geochemical characteristics of ferromanganes crusts from the Lomilik and Litapooki seamounts, Marchall islands, West Pacific. The Sea, v.6, p.13-26.
  5. Drew, L.J., Meng, Q. and Sun, W. (1990) The Bayan Obo iron-rare earth-niobium deposits, Inner Mongolia, China. Lithos, v.26, p.43-65. https://doi.org/10.1016/0024-4937(90)90040-8
  6. Hein, J.R., Conrad, T.A. and Staudigel, H. (2010) Seamount mineral deposits: A source of rare metals for high-technology industries. Oceanography, v.23, p.184-189. https://doi.org/10.5670/oceanog.2010.70
  7. Hein, J.R., Koschinsky, A. and Alliday, A.N. (2003) Global occurrence of tellurium-rich ferromanganese crusts and a model for the enrichment of tellurium. Geochim. Cosmochim. Acta, v.67, p.1117-1127. https://doi.org/10.1016/S0016-7037(02)01279-6
  8. Hein, J.R., Koschinsky, A. and McIntyre, B. (2005) The global enrichment of platinum group elements in marine ferromanganese crusts; In Tormanen, T. O., Alapieti, T.T. (eds.) Extended Abstracts, 10th International Platinum Symposium. Oulu, Finland, p.98- 101.
  9. Hein, J.R., Koschinsky, A., Bau, M., Manheim, F.T., Kang, J.-K. and Roberts, L. (2000) Cobaltrich ferromanganese crusts in the Pacific. In Cronan, D.S. (ed.) Handbook of Marine Mineral Deposits. CRC Press, Boca. p.239-279.
  10. Kawamoto, H. (2008). Japan's Policies to be adopted on Rare Metal Resources. Science & Technology Trends, v.27, p.57-76.
  11. Jeong, K.S., Kang, J.K. and Chough, S.K. (1994) Sedimnetary processes and manganese nodule formation in the Korea Deep Ocean Study (KODOS) area, western part of Clarion-Clipperton fracture zones, northeast equatorial Pacific. Marine Geology, v.122, p.125-150. https://doi.org/10.1016/0025-3227(94)90208-9
  12. Kang, J.-K. (1987) Mineralogy and internal structures of a ferromanganese crust from a seamount, Central Pacific. Jour. Ocean Soc. Korea, v.22, p.168-178.
  13. Kim, J., Moon, J.-W., Chi, S.-B., Ko, Y.-T. and Lee, H.-B. (2004) Chemical Speciations of Elements in the Fe- Mn Crusts by Sequential Extraction. Ocean and Polar Research, v.26, p.231-243. https://doi.org/10.4217/OPR.2004.26.2.231
  14. KIGAM (1988) Rare-earth mineralization in Kyemyungsan formation of Ogcheon group, Mt.Eorae area near Choongju city, middle Korea. In Study on geology and ore deposits for rare metals in Korea. KR-88-8A. 508p.
  15. KIGAM (2001) Mineralization and feasibility study of Fe-REE deposits in Hongcheon area, South Korea. 2000-R-TI02-P-01. 257p.
  16. KORDI (1996) Exploration deep-sea mineral resources (Part I). 1996 year report. 954p.
  17. KORDI (1998) Cruise report for Leg KODOS 97-4. BSPG 97272-00-1098-7. 140p.
  18. KORDI (1999) Exploration for manganese crusts in the southwestern Pacific. CRPM 99022-00-1207-7. 263p.
  19. KORDI (2001) Exploration for manganese crusts in the southwestern Pacific. CRPM 00052-00-1314-7. 290p.
  20. KORDI (2004) Exploration for hydrothermal deposits in the southwestern Pacific. CRPM 199-00-1584-5. 242p.
  21. KORDI (2006) Exploration for seafloor hydrothermal deposits and Fe-Mn crusts in the southwestern Pacific (Exploration part). 2005 year report. CRPM 36000-1799-5. 378p.
  22. Lee, K.-Y., Choi, S.-H. and Park, S.-H. (2002) Geochemistry of the hydrothemral chimneys in the Manus Basin, Southwestern Pacific Ocean. Econ. Eonviron. Geol., v.35, p.1-12.
  23. Lichtblau, A.F., Ravnaas, C., Storey, C.C., Hinz, P. and Bongfeldt, J. (2009) Report of Activities 2008, ResResident Geologist Program, Red Lake Regional Resident Geologist Report: Red Lake and Kenora Districts; Ontario Geological Survey, Open File Report 6232, 84p.
  24. Metal-Pages, website, http://www.metal-pages.com/ (April, 2010)
  25. Nam, K. H., Oh, W.Y. and Kwon, S.J. (2004) An Economic Feasibility Study of Manganese Nodule in Korea Area: Clarion-Clipperton Fracture Zone. Ocean and Polar Research, v.26, p.187-197. https://doi.org/10.4217/OPR.2004.26.2.187
  26. Nikolaev, A.I., Larichkin, F.D. and Nikolaeva, O.A. (2008) Choosing the technology of combined processing of titanium-rare-metal raw materials. Theoretical Foundations of Chemical Engineering, v.42, p.675-679. https://doi.org/10.1134/S0040579508050333
  27. Pak, S.J. (2009) Features of Seabed hydrothermal polymetallic deposits and their exploration and exploitation. Minerals and Industry, v.22 p.45-59.
  28. Park S.-H. and Yang, H.-C. (2009) A Technical and Economic Evaluation of Cobalt-rich Manganese Crusts. Ocean and Polar Research, v.31, p.167-176. https://doi.org/10.4217/OPR.2009.31.2.167
  29. Song, Y.-H., Kim, J.-W., Kim, H.-J. and Lee C.-T. (2001) The recovery of valuable metals from leachate of deep sea manganese nodule. J. Korean Ind. Eng. Chem., v.12, p.236-271.
  30. Taylor, S.R. (1964). The abundance of chemical elements in the continental crust - a new table. Geochim. Cosmochim. Acta, v.28, p.1273-1285. https://doi.org/10.1016/0016-7037(64)90129-2
  31. Taylor, S.R. and McLennan (1985). The continental crust: Its composition and evolution. Blackwell Scientific Publ., Oxford, England, 312p.
  32. Wiltshire, J.C., Wen, X.Y. and Yao, D. (1999) Ferromanganese Crusts near Johnston Island: Geochemistry, Stratigraphy and Economic Potential. Marine Georesources and Geotechnology, v.17, p.257-270. https://doi.org/10.1080/106411999273936
  33. Wu, C., Yuan, Z. and Bai, G. (1996) Rare earth deposits in China. In Jones, A.P., Wall, F., Williams, C.T. (eds.) Rare earth minerals: Chemistry, origin and ore deposits. Mineralogical Society Series no.7. Chapman and Hall, London, p.281-310.
  34. Yoon, C.H., Kim, I.K. Kwon, K.S. and Kwon, O.K. (1999) Analysis of unsteady state flow mechanism in pipe for hydraulic pumping system in deep-sea manganese nodules. Korean Soc. Geosystem Eng., v.36, p.33-41.