한국응용과학기술학회지 (Journal of the Korean Applied Science and Technology)

  • 제26권3호
  • /
  • Pages.362-369
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  • 2009
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  • 1225-9098(pISSN)
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  • 2288-1069(eISSN)
한국응용과학기술학회 (The Korean Society of Applied Science and Technology)
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Succinic Acid과 1,4-butanediol간의 에스테르화반응에서 Monobutyl Tinoxide 촉매의 영향

Effect of Monobutyl Tinoxide Catalyst in Esterification Reaction between Succinic Acid and 1,4-butanediol

  • 박근호 (창원대학교 화공시스템공학과) ;
  • 김덕술 (동명대학교 의용공학과)
  • Park, Keun-Ho (Dept of Chemical Engineering, Changwon National University) ;
  • Kim, Duck-Sool (Dept. of Biomedical Engineering, Tongmyong University)
  • 발행 : 2009.09.30
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초록

Esterification reaction between succinic acid and 1,4-butanediol was kinetically investigated in the presence of monobutyl tinoxide catalysts at $150{\sim}190^{\circ}C$. The reaction rates measured by the amount of distilled water from the reaction vessel. The esterification reaction was carried out under the first order conditions with respect to the concentration of reactants, respectively. The overall reaction order was 2nd. The linear relationship was shown between apparent reaction rate constant and reciprocal absolute temperature. By the Arrhenius plot the activation energy have been calculated as 87.567 kJ/mol under monobutyl tinoxide catalyst and also apparent reaction rate constant, k' was found to obey first kinetics with respect to the concentration of catalyst.

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참고문헌

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