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http://dx.doi.org/10.12925/jkocs.2009.26.3.16

Effect of Monobutyl Tinoxide Catalyst in Esterification Reaction between Succinic Acid and 1,4-butanediol  

Park, Keun-Ho (Dept of Chemical Engineering, Changwon National University)
Kim, Duck-Sool (Dept. of Biomedical Engineering, Tongmyong University)
Publication Information
Journal of the Korean Applied Science and Technology / v.26, no.3, 2009 , pp. 362-369 More about this Journal
Abstract
Esterification reaction between succinic acid and 1,4-butanediol was kinetically investigated in the presence of monobutyl tinoxide catalysts at $150{\sim}190^{\circ}C$. The reaction rates measured by the amount of distilled water from the reaction vessel. The esterification reaction was carried out under the first order conditions with respect to the concentration of reactants, respectively. The overall reaction order was 2nd. The linear relationship was shown between apparent reaction rate constant and reciprocal absolute temperature. By the Arrhenius plot the activation energy have been calculated as 87.567 kJ/mol under monobutyl tinoxide catalyst and also apparent reaction rate constant, k' was found to obey first kinetics with respect to the concentration of catalyst.
Keywords
esterification reaction; succinic acid; 1,4-butanediol; monobutyl tinoxide catalyst; activation energy;
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Times Cited By KSCI : 1  (Citation Analysis)
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