Macromolecular Research

The Polymer Society of Korea (한국고분자학회)
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Self-doped Carboxylated Polyaniline: Effect of Hydrogen Bonding on the Doping of Polymers

  • Kim, Seong-Cheol (School of Textiles, Yeungnam University) ;
  • Whitten, James (The Center for Advanced Materials, Polymer Science Program, Departments of Chemistry and Physics, University of Massachusetts Lowell) ;
  • Kumar, Jayant (The Center for Advanced Materials, Polymer Science Program, Departments of Chemistry and Physics, University of Massachusetts Lowell) ;
  • Bruno, Ferdinando F. (Army Natick Soldier Development and Engineering Center) ;
  • Samuelson, Lynne A. (Army Natick Soldier Development and Engineering Center)
  • Published : 2009.09.25
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Abstract

This study examined the unique self-doping behavior of carboxylated polyaniline (PCA). The self-doped PCA was synthesized using an environmentally benign enzymatic polymerization method with cationic surfactants. XPS showed that HCl-doped PCA contained approximately 34% of protonated amines but self-doped PCA contained 9.6% of the doped form of nitrogen at pH 4. FTIR and elemental analysis showed that although the PCA was doped with the proton of strong acids at low pH via the protonation of amines, the self-doping mechanism of PCA at pH > 4 was mainly due to hydrogen bonding between the carboxylic acid group and amine group.

Keywords

References

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