DOI QR코드

DOI QR Code

A Study on the Ultrasonic Response Characteristic of PVDF Organic Thin Film by Physical Vapor Deposition Method

진공증착법으로 제조된 PVDF 유기박막의 초음파 응답 특성에 관한 연구

  • Published : 2009.05.30

Abstract

The purpose of this paper is to discuss the fabrication of $\beta$-PVDF($\beta$-Polyvinylidene fluoride, $\beta$-PVF2) organic thin films through the vapor deposition method and to investigate the ultrasonic response properties of the organic thin films produced. Vapor deposition was performed under the following conditions : the temperature of evaporator, the applied electric field and the pressure of reaction chamber were $270^{\circ}C$, 142.4 kV/cm and $2.0{\times}10^{-5}\;Torr$, respectively. The results showed that the degree of crystallinity increased from 47% to 67.8% with an increase in the substrate temperature. In the case of a sensor response characteristic by varying the distance from 1cm to 100cm, the output voltage decreased from 0.615V to 0.4V.

본 논문의 목적은 진공증착법을 이용한 $\beta$-PVDF($\beta$-Polyvinylidene fluoride) 유기 박막의 제조와 제조된 유기 박막의 초음파 응답 특성을 연구하는데 있다. 진공 증착은 증발원 온도 $270^{\circ}C$, 인가 전계 142.4kV/cm, 진공도 $2.0{\times}10^{-5}Torr$에서 실시하였다. 기판온도의 증가에 따라서 결정화도는 47%에서 67.8%로 증가함을 알 수 있었다. 초음파 응답특성에서 거리를 1cm에서 100cm로 변화시켰을 경우, 출력전압은 0.615V에서 0.4V로 감소하였다.

Keywords

References

  1. S. Hurmila, H. Stubb, J. Pitkanen, K. Lahdenpera, and A. Penttinen, "Ultrasonic Transducers using PVDF" Ferroelectrics, Vol. 115, pp. 267-278 (1991) https://doi.org/10.1080/00150199108222384
  2. 奧居 德昌, "有機蒸着薄膜の分子配向特性" 日本 高分子學會誌, Vol. 26, No. 10, pp. 695-704 (1988)
  3. H. Kawai, "The Piezoelectricity of Poly(vinylidene fluoride)" Jpn. J. Appl. Phys., 8, pp. 975-976 (1969) https://doi.org/10.1143/JJAP.8.975
  4. T. T. Wang and Heinz von Seggern, "High electric field poling of electroded poly(vinylidene fluoride) at room temperature" J. Appl. Phys., Vol. 54, No. 8, pp. 4602-4604 (1983) https://doi.org/10.1063/1.332615
  5. 佐藤 裕亮, 丸山 統雄, "機能性高分子エレトレツト(とくにPVDF系)の新しい展開" 日本靜電氣學會紙, Vol. 11, No. 6, pp. 422-430 (1987)
  6. 徐日煥, "X-線 回折 分析" 半島出版社, pp. 226-228, 1993
  7. G. Natta, G. Allegra, I. W. Bassi, D. Sianesi, G. Caporticcio, and E. Torti, "Isomorphism Phenomena in Systems Containing Fluorinated Polymers and in New Fluorinated Copolymers" J. Polym. Sci. : Part A, Vol. 3, pp. 4263-4278 (1965) https://doi.org/10.1002/pol.1965.100031222
  8. P. D. Southgate, "Room-temperature Poling and Morphology Changes in Pyroelectric Poly (vinylidene Fluoride)" Appl. Phys. Lett., Vol. 28, No. 5, pp. 250-252 (1976) https://doi.org/10.1063/1.88727
  9. 金在汶, "高分子化學" 東明社, pp. 71-73, 1985
  10. 朴修弘, 李德出, "진공증착법을 이용하여 제조한 PVDF 유기 박막의 열적.전기적 안정 특성에 관한 연구" 韓國眞空學會誌, Vol. 8, No. 2, pp. 93-101, 1999

Cited by

  1. Fabrication of an Electrostrictive Fluorinated Terpolymer Sheet Applicable to Artificial Muscle Systems vol.20, pp.4, 2011, https://doi.org/10.5757/JKVS.2011.20.4.276