Korean Chemical Engineering Research

  • 제47권4호
  • /
  • Pages.410-417
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  • 2009
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  • 0304-128X(pISSN)
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  • 2233-9558(eISSN)
한국화학공학회 (The Korean Institute of Chemical Engineers)
권호 표지

MCM41에 담지된 Imidazole 촉매에 의한 Glycidyl Methacrylate와 이산화탄소의 반응속도론

Reaction Kinetics of Carbon Dioxide and Glycidyl Methacrylate using a Ionic Liquid Catalyst of Imidazole Immobilized on MCM41

  • 손영식 (부산대학교 화학공학과) ;
  • 박문기 (대구한의대학교 한방제약공학과) ;
  • 김건우 (부산울산지방중소기업청 기업환경개선과) ;
  • 박상욱 (부산대학교 화학공학과)
  • Son, Young-Sik (Division of Chemical Engineering, Pusan National University) ;
  • Park, Moon-Ki (Department of Pharmaceutical Engineering, Daegu Haany University) ;
  • Kim, Gun-Woo (Business Environment Improvement Division, Busan-Ulsan Regional Office of Small and Medium Business Administration) ;
  • Park, Sang-Wook (Division of Chemical Engineering, Pusan National University)
  • 투고 : 2009.03.25
  • 심사 : 2009.06.18
  • 발행 : 2009.08.31
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초록

중간세공크기(mesopore)의 MCM41에 Imidazole을 담지시킨 CP-MS41 고체 입자의 촉매를 사용하여 GMA 용액에 $CO_2$를 흡수시켜 $CO_2$의 흡수기구로부터 GMA와 $CO_2$의 반응속도론을 고찰하였다. 대기압에서 회분식 흡수조를 사용하여 임펠러의 교반속도, 50 rpm, 촉매, 2 g, 반응온도, 60, 70, $80^{\circ}C$, GMA의 농도, $0.1{\sim}3.0kmol/m^3$, 용제, DMA, NMP, DMSO에서 측정한 $CO_2$의 흡수속도와 경막설에 의한 물질수지식을 사용하여 반응속도상수를 구하였다.

Carbon dioxide was absorbed into GMA solution in a stirred flat cell using mesoporous catalyst Imidazole-CP-MS41, which was synthesized by CP-MCM41 with imidazole. Experiments were carried out at a batch-type absorber with different conditions, varying reaction temperature, concentration of GMA, solvent but maintaining 50 rpm of agitation speed and 2 g of catalyst. Absorption rate of $CO_2$ was used to obtain the kinetics based on the film theory using zwitterion mechanism with 2 elementary reaction and the kinetics were correlated with the solubility parameter of the solvents.

키워드

과제정보

연구 과제 주관 기관 : 대구한의대학교

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