Bulletin of the Korean Chemical Society

  • 제30권10호
  • /
  • Pages.2338-2340
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  • 2009
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  • 0253-2964(pISSN)
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  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
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Swellable Submicrospheres of Ionic Palladium(II) Complexes Containing Decylmethylbis(m-pyridyl)silane

  • Ryu, Yoon-Kyong (Department of Chemistry and Chemistry Institute for Functional Materials, Pusan National University) ;
  • Kim, Cho-Rong (Department of Chemistry and Chemistry Institute for Functional Materials, Pusan National University) ;
  • Kim, Chi-Won (Department of Chemistry and Chemistry Institute for Functional Materials, Pusan National University) ;
  • Noh, Tae-Hwan (Department of Chemistry and Chemistry Institute for Functional Materials, Pusan National University) ;
  • Jung, Ok-Sang (Department of Chemistry and Chemistry Institute for Functional Materials, Pusan National University)
  • 발행 : 2009.10.20
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초록

Ionic palladium(II) complex containing a long aliphatic chain, [(tmeda)$PdL]_2(PF_6)_4$ (tmeda = N,N,N',N'-tetramethylethylenediamine; L = decylmethylbis(m-pyridyl)silane) allowed to form a puckered submicrosphere morphology without any template or additive. The puckered spheres reversibly adsorb and desorb dioxane molecules. Coligand and cosolvent effects on the formation of submicrospherical morphology were observed.

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