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http://dx.doi.org/10.5012/bkcs.2009.30.10.2338

Swellable Submicrospheres of Ionic Palladium(II) Complexes Containing Decylmethylbis(m-pyridyl)silane  

Ryu, Yoon-Kyong (Department of Chemistry and Chemistry Institute for Functional Materials, Pusan National University)
Kim, Cho-Rong (Department of Chemistry and Chemistry Institute for Functional Materials, Pusan National University)
Kim, Chi-Won (Department of Chemistry and Chemistry Institute for Functional Materials, Pusan National University)
Noh, Tae-Hwan (Department of Chemistry and Chemistry Institute for Functional Materials, Pusan National University)
Jung, Ok-Sang (Department of Chemistry and Chemistry Institute for Functional Materials, Pusan National University)
Publication Information
Bulletin of the Korean Chemical Society / v.30, no.10, 2009 , pp. 2338-2340 More about this Journal
Abstract
Ionic palladium(II) complex containing a long aliphatic chain, [(tmeda)$PdL]_2(PF_6)_4$ (tmeda = N,N,N',N'-tetramethylethylenediamine; L = decylmethylbis(m-pyridyl)silane) allowed to form a puckered submicrosphere morphology without any template or additive. The puckered spheres reversibly adsorb and desorb dioxane molecules. Coligand and cosolvent effects on the formation of submicrospherical morphology were observed.
Keywords
Coligand effects; Decylmethylbis(m-pyridyl)silane; Ionic palladium(II) complexes; Swellable submicrospheres;
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