Textile Coloration and Finishing (한국염색가공학회지)

The Korean Society of Dyers and Finishers (한국염색가공학회)
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Dyeability of Cationized PET Fabrics to Acid Dyes via Photografting

광그라프트로 양이온화된 PET 직물의 산성 염료에 대한 염색성

  • Son, Jung-A (School of Advanced Materials and System Engineering, Kumoh National Institute of Technology) ;
  • Jang, Jin-Ho (School of Advanced Materials and System Engineering, Kumoh National Institute of Technology)
  • 손정아 (금오공과대학교 신소재시스템공학부 나노바이오텍스타일공학과) ;
  • 장진호 (금오공과대학교 신소재시스템공학부 나노바이오텍스타일공학과)
  • Published : 2008.04.27
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Abstract

PET fabrics were cationized via photografting under continuous UV irradiation with a cationic monomer. The grafted PET was dyed with three acid dyes. Effect of dye concentration, dyeing time, temperature and pH on acidic dyeing of the cationized PET fabrics was assessed to find optimal dyeing condition. The cationized fabrics was successfully dyed at $75^{\circ}C$ under pH 5.5. However the dyeing sites of the grafted fabrics were nearly occupied above 5%owf dye concentration and the rapid exhaustion of the anionic dyes was observed. The dyeability of the cationized PET fabrics was increased proportionally with increasing percent grafting because of the introduction of ionic attraction between quaternary ammonium groups and acid dyes. Lower dyeability both at alkaline and pH 3 condition attributed to negative zeta potentials of the grafted fabrics and the reduced charge of the acid dyes respectively.

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References

  1. M. Lewin and E. M. Pearce, "Handbook of Fiber Chemistry", Marcel Dekker, NY, pp.2-62, 1985
  2. S. J. Kim, A Study on the Optical Properties and Surface Properties of Polyester/Wool Fabrics, Textile Sci. Eng., 36(11), 806-814 (1999)
  3. T. K. Kim, Y. J. Lim, J. D. Seok and K. H. Cho, Incrase in Color Depth of polyester Fiber by Alkali Treatment and Analysis of the Surface Structure, J. Korean Soc. Dyers & Finishers, 11(5), 300-307(1999)
  4. K. W. Jung and Y. W. Huh, A Study on Dyeing Mechanism of Cationic Dyeable Polyester Fibers with Cationic Dyes, Textile Sci.Eng., 18, 23-40(1981)
  5. T. K. Kim, S. H. Yoon, S. Y. Shin, Y. J. Lim and K. M. Cho, The Physical Properties and the Dyeability od the Easily Dyeable Polyester Yarn under Atomospheic Pressure, J. Korean Soc. Dyers & Finishers, 13(6), 391-396(2001)
  6. E. D. Seo, Surface Modification of Polyacrylonitrile by Low-temperature Plasma, J. Korean Soc. Dyers & Finishers, 19, 45-52(2007)
  7. H. W. Kim, C. Y. Kim and P. K. Pak, Modification of Polymer Surface by Corona Discharge and the Subsequent Graft Polymerization of Acrylamide, J. Korean Soc. Dyers & Finishers, 5, 26-32(1993)
  8. J. Jang, M. Kim, and Y. Jeoung, Cationic Dyeable Treatment of PET and PTT Fabrics by Continuous $UV/O_3$ Irradiation, Textile Sci. Eng., 40(5), 424-430(2003)
  9. J. Zhang, E. Uchida, Y. Uyama, and Y. Ikada, Adhesive Interaction in Aqueous Media between Polymer Surface Grafted with Anionic and Cationic Polymer Chains, Langmuir, 11, 1688-1692(1995) https://doi.org/10.1021/la00005a043
  10. J. Jang, Textile Finishing Technology Using Ultraviolet Curing, Fiber. Technol. Ind., 7, 303-321(2003)
  11. E. Uchida, Y. Uyama, and Y. Ikada, Sorption of Low-Molecular-Weight Anions into Thin Polycation Layers Grafted onto a Film, Langmuir, 9, 1121-1124(1993) https://doi.org/10.1021/la00028a040
  12. J. Jang, S. W. Ko and C. M. Carr, Investigation of the Improved Dyeability of Cationised Cotton via Photografting with UV active Cationic Monomers, Color Technol., 117, 139-146(2001) https://doi.org/10.1111/j.1478-4408.2001.tb00052.x
  13. J. Jang and J. A. Son, Cationization of PET Fabrics via Continuous Photograftiong of [3-(Methcaryloylamino)propyl]trimethylamm onium Chloride, Textile Sci. Eng., 44(6), 312-318(2007)
  14. E. Uchida, Y. Uyama, and Y. Ikada, Zeta Potential of Polycation Layers Grafted onto a Film Surface, Langmuir, 10, 1193-1198(1994) https://doi.org/10.1021/la00016a037
  15. W. K. Sung, A Study on the One Bath Two Step Dyeing of Nylon/Cationised Cotton Blends with Acid dye/direct dye, J. Korean Soc. Dyers & Finishers, 12(1), 44-51(2002)
  16. J. Jang and Y. Jeong, Nano Roughening of PET and PTT Fabrics via Continuous UV/ $O_3$ Irradiation, Dyes & Pigments, 69, 137-143(2006) https://doi.org/10.1016/j.dyepig.2005.02.010