폴리머 (Polymer(Korea))

  • 제31권5호
  • /
  • Pages.385-392
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  • 2007
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  • 0379-153X(pISSN)
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  • 2234-8077(eISSN)
한국고분자학회 (The Polymer Society of Korea)
권호 표지

Poly(N-vinylpyrrolidone)이 그래프트된 Poly(3-hydroxybutyrate-co-3-hydroxyvalerate) 공중합체의 합성 및 결정화 거동

Preparation and Crystallization Behavior of Poly(3-hydroxybutyrate-co-3-hydroxyvalerate) Grafted with Poly(N-vinylpyrrolidone)

  • Wang, Wei (College of Biological & Chemical Engineering, Jiaxing University) ;
  • Zhang, Yu (State Key Laboratory for Modification of Chemical Fiber & Polymeric Materials, College of Materials Science & Engineering, Donghua University) ;
  • Chen, Yanmo (State Key Laboratory for Modification of Chemical Fiber & Polymeric Materials, College of Materials Science & Engineering, Donghua University)
  • 발행 : 2007.09.30
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초록

Poly (N-vinylpyrrolidone) (PVP) groups were grafted onto a poly(3-hydroxybutyrate-co-3-hydroryvalerate) (PHBV) backbone in order to modify its properties and synthesize a novel biocompatible copolymer. The crystallization behavior of PHBV and grafted PHBV was investigated by differential scanning calorimetry (DSC) and polarized optical microscopy (POM). During the cooling-induced crystallization process, the crystallization temperature and the crystallization rate of the grafted PHBV decreased with increasing PVP weight fraction. On the heating scans of all grafted PHBV samples, a new crystallization exothermic peak appeared at almost the same temperature, suggesting the operation of a recrystallization process, while the melting temperature ($T_m$) and the apparent enthalpy of fusion (${\Delta}H_f$) were not affected by graft modification. During the isothermal crystallization process at the same temperature, the presence of side PVP groups decreased the spherulitic growth rate and the spherulitic band spacing with increasing PVP weight fraction in samples.

키워드

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