DOI QR코드

DOI QR Code

Gas sensing characteristics of carbon nanotube gas sensor using a diaphragm structure

다이아프램 구조를 이용한 탄소나노튜브 가스 센서의 가스 감응 특성

  • Cho, Woo-Sung (Department of Electronic Engineering, Korea University) ;
  • Moon, Seung-Il (Department of Electronic Engineering, Korea University) ;
  • Kim, Young-Cho (Department of Electronic Engineering, Chungwoon University) ;
  • Park, Jung-Ho (Department of Electronic Engineering, Korea University) ;
  • Ju, Byeong-Kwon (Department of Electrical Engineering, Korea University)
  • Published : 2006.01.31

Abstract

The micro-gas sensor based on carbon nanotubes (CNTs) was fabricated and its gas sensing characteristics on nitrogen dioxide ($NO_{2}$) have been investigated. The sensor consists of a heater, an insulating layer, a pair of contact electrodes, and CNT-sensing film on a micromachined diaphragm. The heater plays a role in the temperature change to modify sensor operation. Gas sensor responses of CNT-film to $NO_{2}$ at room temperature are reported. The sensor exhibits a reversible response with a time constant of a few minutes at thermal treatment temperature of $130^{\circ}C$.

Keywords

References

  1. H. Dai, 'Carbon nanotubes: synthesis, integration, and properties', Ace. Chem. Res., vol. 35, pp. 1035-1044, 2002 https://doi.org/10.1021/ar0101640
  2. Y. Takao, K. Miyazaki, Y. Shimizu, and M. Egashira, 'High ammonia sensitive semiconductor gas sensors with double-layer structure and interface electrodes', J Eleetrochem. Soc., vol. 141, pp. 1028-1033, 1994 https://doi.org/10.1149/1.2054836
  3. 김승렬, 윤동현, 홍형기, 권철한, 이규정, '산화물 반도체형 후막 가스 센서의 이산화질소 감지 특성', 센서학회지, 제6권, 제6호, pp. 451-457, 1997
  4. A. Mandelis and C. Christofides, Physics, Chemistry, and Technology of Solid State Gas Sensor Devices. New York: Wiley, 1993
  5. O. H. Elibol, D. Morisette, D. Akin, J. P. Denton, and R. Bashir, 'Integrated nanoscale silicon sensors using top-down fabrication', Appl. Phys. Lett., vol. 83, pp. 4613-4615, 2003 https://doi.org/10.1063/1.1630853
  6. F. Zee and J. W. Judy, 'Micrornachined polymer-based chemical gas sensor array', Sens. Actuators B, vol. 72, pp. 120-128, 2001 https://doi.org/10.1016/S0925-4005(00)00638-9
  7. J. Kong, N. R. Franklin, C. Zhou, M. G Chapline, S. Peng, K. Cho, and H. Dai, 'Nanotube molecular wires as chemical sensors', Science, vol. 287, pp. 622-625, 2000 https://doi.org/10.1126/science.287.5453.622
  8. P. Qi, O. Verrnesh, M. Grecu, A. Javey, Q. Wang, H. Dai, S. Peng, and K. J. Cho, 'Toward large arrays of multiplex functionalized carbon nanotube sensors for highly sensitive and selective molecular detection', Nano Lett., vol. 3, pp. 347-351, 2003 https://doi.org/10.1021/nl034010k
  9. S. Santucci, S. Picozzi, F. Di Gregorio, L. Lozzi, C. Cantalini, L. Valentini, J. M. Kenny, and B. Delley, '$NO_2$ and CO gas adsorption on carbon nanotubes: experiment and theory', J Chem. Phys., vol. 119, pp. 10904-10910, 2003 https://doi.org/10.1063/1.1619948
  10. L. Valentini, L. Lozzi, C. Cantalini, I. Armentano, J. M. Kenny, L. Ottaviano, and S. Santucci, 'Effects of oxygen annealing on gas sensing properties of carbon nanotube thin films', Thin Solid Films, vol. 436, pp. 95-100, 2003 https://doi.org/10.1016/S0040-6090(03)00517-0
  11. C. Cantalini, L. Valentini, L. Lozzi, I. Armentano, J. M. Kenny, and S. Santucci, '$NO_2$ gas sensitivity of carbon nanotubes obtained by plasma enhanced chemical vapor deposition', Sens. Actuators B, vol. 93, pp. 333-337, 2003 https://doi.org/10.1016/S0925-4005(03)00224-7
  12. K. GOng, K. Zeng, and C. A. Grimes, 'A wireless, passive carbon nanotube-based gas sensor', IEEE Sensor J., vol. 2, pp. 82-88, 2002 https://doi.org/10.1109/JSEN.2002.1000247
  13. O. K. Varghese, P. D. Kichamber, D. Cong, K. G. Ong, and C.A. Grimes, 'Gas sensing characteristics of multi-wall carbon nanotubes', Sens. Actuators B, vol. 81, pp. 32-41, 2001 https://doi.org/10.1016/S0925-4005(01)00923-6
  14. 김민수, 윤광현, 허증수, '단층 탄소나노튜브의 일산화질소 가스에 대한 감응특성과 열 처리 효과', 센서학회지, 제13권, 제4호, pp. 137-142, 2004
  15. S. Peng, K. J. Cho, P. Qi, and H. Dai, 'Ab initio study of CNT $NO_2$ gas sensor', Chem. Phys. Lett., vol. 387, pp. 271-276, 2004 https://doi.org/10.1016/j.cplett.2004.02.026
  16. I. Simon, N. Barsan, M. Bauer, and U. Weimar, 'Micromachined metal oxide gas sensors: opportunities to improve sensor performance', Sens. Actuators B, vol. 73, pp. 1-26, 2001 https://doi.org/10.1016/S0925-4005(00)00639-0
  17. M. Baroncini, P. Placidi, G. C. Cardinali, and A. Scorzoni, 'Thermal characterization of a microheater of micromachined gas sensors', Sens. Actuators A, vol. 115, pp. 8-14, 2004 https://doi.org/10.1016/j.sna.2004.03.012
  18. C. J. Lee, D. W. Kim, T. J Lee, Y. C. Choi, Y. S. Park, Y. H. Lee, W. B. Choi, N. S. Lee, G. S. Park, and J. M. Kim, 'Synthesis of aligned carbon nanotubes using thermal chemical vapor deposition', Chem Phys. Lett., vol. 312, pp. 461-468, 999 https://doi.org/10.1016/S0009-2614(99)01074-X

Cited by

  1. Hydrogen sensor of SWNT-PdOxsystem using the vacuum filtering deposition method vol.19, pp.2, 2010, https://doi.org/10.5369/JSST.2010.19.2.087