Bulletin of the Korean Chemical Society

  • 제26권9호
  • /
  • Pages.1415-1420
  • /
  • 2005
  • /
  • 0253-2964(pISSN)
  • /
  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
권호 표지
DOI QR코드

DOI QR Code

Removal of OH Spectral Interferences from Aqueous Solvents in Inductively Coupled Plasma-Atomic Emission Spectrometry (ICP-AES) with Ar Cryogenic Desolvation

  • Cho, Young-Min (Department of Chemistry, Korean National University of Education) ;
  • Pak, Yong-Nam (Department of Chemistry, Korean National University of Education)
  • 발행 : 2005.09.20
PDF 다운로드
⟨ 이전 논문 다음 논문 ⟩

초록

The spectral interferences of OH from aqueous solvents in ICP-AES have been studied and eliminated using a cryogenic argon trap. The prominent lines of Bi I 306.772 nm, Al I 309.271 nm, and V II 310.230 nm, which are very seriously overlapped with the OH band, were examined. With an extended torch and high tangential flow of 20 L/min, water vapor from air entrainment was prevented. The combination of a condenser and argon cryogenic trap was able to eliminated most of water vapor carried by the argon sample gas. Removal of OH spectral interference could extend the linearity of the calibration curve 5-10 times on the lower concentration for ICP-AES. Interference Equivalent Concentration (IEC) has been reduced to 5.6, 5.9, and 12.4 times for Bi, Al and V, respectively.

키워드

참고문헌

  1. Olesik, J. W.; Smith, L. J.; Williamsen, E. J. Anal. Chem. 1989, 61, 2002 https://doi.org/10.1021/ac00193a003
  2. Nixon, D. E. J. Anal. At. Spectrom. 1990, 5, 531 https://doi.org/10.1039/ja9900500531
  3. Tsukahara, R.; Kubota, M. Spectrochim. Acta 1990, 45B, 581
  4. Olson, K.; Haas, W. J.; Fassel, V. A. Anal. Chem. 1977, 49, 632 https://doi.org/10.1021/ac50012a032
  5. Douglass, K. O.; Fitzgerald, N.; Ingebrethsen B. J.; Tyson, J. F. Spectrochim. Acta 2004, 59B, 107
  6. Huang, M.; Kojima, H.; Shirasaki, T.; Hirabayashi, A.; Koizumi, H. Anal. Chim. Acta 2000, 413, 217 https://doi.org/10.1016/S0003-2670(00)00808-4
  7. Masson, P.; Vives, A.; Orignac D.; Prunet, T. J. Anal. At. Spectrom. 2000, 15, 543 https://doi.org/10.1039/a909651e
  8. Novotny, I.; Farinas, J. C.; Wang, J.; Poussel, E.; Mermet, J.-M. Spectrochim. Acta 1996, 51B, 1517
  9. Luo, S. K.; Berndt, H. Spectrochim. Acta 1994, 49B, 485
  10. Koropchak, J. A.; Winn, D. H. Appl. Spectrosc. 1987, 41, 1311 https://doi.org/10.1366/0003702874447338
  11. Hutton, R. C.; Eaton, A. N. J. Anal. At. Spectrom. 1987, 2, 595 https://doi.org/10.1039/ja9870200595
  12. Castilluno, T. M.; Vela, N. P.; Caruso, J. A.; Story, W. C. J. Anal. At. Spectrom. 1992, 7, 807 https://doi.org/10.1039/ja9920700807
  13. Tao, H.; Miyazaki, A. J. Anal. At. Spectrom. 1995, 10, 1 https://doi.org/10.1039/ja9951000001
  14. Yang, J.; Conver, T.; Koropchak, J. A.; Leighty, D. A. J. Anal. At. Spectrom. 1996, 11, 1491
  15. Brenner, I. B.; Zander, A.; Plantz, M.; Zhu, J. J. J. Anal. At. Spectrom. 1997, 12, 273 https://doi.org/10.1039/a605533h
  16. Sung, Y.; Lim, H. B. J. Anal. At. Spectrom. 2001, 16, 767 https://doi.org/10.1039/b101224j
  17. Pak, Y. N.; Koirtyohann, S. R. Bull. Korean. Chem. Soc. 1997, 18, 1167
  18. Alves, L. C.; Wiederin, D. R.; Houk, R. S. Anal. Chem. 1992, 64, 1155 https://doi.org/10.1021/ac00048a001
  19. Alves, L. C.; Allen, L. A.; Houk, R. S. Anal. Chem. 1993, 65, 2468 https://doi.org/10.1021/ac00066a011
  20. Minnich, M. G.; Houk, R. S. J. Anal. At. Spectrom. 1998, 13, 167 https://doi.org/10.1039/a704274d
  21. Wiederin, D. R.; Houk, R. S.; Winge, R. K.; D'Silva, K. N. Anal. Chem. 1990, 62, 1155 https://doi.org/10.1021/ac00210a012
  22. Alves, L. C.; Minnich, M. G.; Wiedrin, D. R.; Houk, R. S. J. Anal. At. Spectrom. 1994, 9, 399 https://doi.org/10.1039/ja9940900399
  23. Gustavsson, A. Spectrochim. Acta 1988, 43B, 917
  24. Boumans, P. W. J. M.; Vrakking, J. J. A. M. Spectrochim. Acta 1985, 40B, 1423
  25. Boumans, P. W. J. M.; Vrakking, J. J. A. M. Spectrochim. Acta 1985, 40B, 1107
  26. Crain, J. S.; Alvarado, J. J. Anal. At. Spectrom. 1994, 9, 1223 https://doi.org/10.1039/ja9940901223
  27. Minnich, M. G.; Houk, R. S.; Woodin, M. A.; Christiani, D. C. J. Anal. At. Spectrom. 1997, 12, 1345 https://doi.org/10.1039/a700172j
  28. Pin, C.; Telouk, P.; Imbert, J. L. J. Anal. At. Spectrom. 1995, 10, 93 https://doi.org/10.1039/ja9951000093
  29. Winge, R. K.; Fassel, V. A.; Peterson, V. J.; Floyd, M. A. Appl. Spectrosc. 1982, 36, 218
  30. Jakubowski, N.; Feldmann, I.; Stuewer, D. Spectrochim. Acta 1992, 47B, 107
  31. Garbarino, J. R.; Talor, H. E. Appl. Spectrosc. 1979, 33, 220 https://doi.org/10.1366/0003702794925732
  32. Saiwan, C. Ph.D. Thesis, Univ. of MO: 1991

피인용 문헌

  1. Atomic spectrometry update. Advances in atomic emission, absorption and fluorescence spectrometry, and related techniques vol.21, pp.6, 2006, https://doi.org/10.1039/b606486h
  2. Spectral interferences and their correction in atomic emission spectral analysis vol.85, pp.1, 2019, https://doi.org/10.26896/1028-6861-2019-85-1-ii-15-32