Journal of Korean Society on Water Environment (한국물환경학회지)

Korean Society on Water Environment (한국물환경학회)
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HAAs Formation by Chlorine Dose and Reaction Time and The Removal Effect of Precursors by The Advanced Oxidation Processes

염소주입량과 반응시간에 따른 HAAs 생성과 고도산화처리에 의한 전구물질 제거 영향

  • Kim, Kyoung-Suk (Department of Environmental Engineering, Yonsei University) ;
  • Oh, Byung-Soo (Department of Environmental Engineering, Yonsei University) ;
  • Ju, Seul (Department of Environmental Engineering, Yonsei University) ;
  • Kang, Joon-Wun (Department of Environmental Engineering, Yonsei University)
  • 김경숙 (연세대학교 환경공학과) ;
  • 오병수 (연세대학교 환경공학과) ;
  • 주설 (연세대학교 환경공학과) ;
  • 강준원 (연세대학교 환경공학과)
  • Published : 2004.03.30
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Abstract

This study investigated the effect of chlorine dose and chlorine reaction time for the formation of haloacetic acids (HAAs). According to the results, HAA formation was highly affected by chlorine dose and chlorine reaction time. HAA formation reached a plateau value at 30 mg/L of chlorine dose and 24 hr of chlorine reaction time. For the speciation of formed HAAs in the test water, the concentration of brominated-HAAs was significantly lower than that of chlorinated-HAAs because of low level of bromide ion concentration in the test water. It also investigated the removal efficiency of HAA precursors by several unit processes, such as ozone alone, UV alone, and combined ozone/UV system. Of them, ozone/UV system was proved as the best process to control the HAAs formation. The increase of the brominated-HAAs was observed during ozonation with and without UV irradiation showing the slight increase of total HAA concentrations.

Keywords

References

  1. 국립환경연구원, 고도정수 처리시 생성되는 브로메이트에 대한 조사 (1997)
  2. 신호상, 박치후, 암모니아가 염소소독력 및 소독부산물 생성에 미치는 영향, 한국물환경 학회지, 15(4), pp 489-498 (1999)
  3. 최희락, Bromide를 함유한 상수원수의 오존 처리시 bromate의 생성특성에 관한 연구, 연세대학교 석사학위논문 (2001)
  4. 채선하, 김충환, 조재원, 금강원수를 대상으로 하는 수 처리 공정에서 소독 부산물 생성특성 및 제거에 관한 연구, 대한환경공학회지, 22(9), pp. 1589-1600 (2000)
  5. Bryant, E. A., Fluton, G. P. and Budd, G. C., Disinfection alternatives for safe drinking water, Van Nostrand Reinhold, New York. pp.71 USA (1992)
  6. Chang, S. D., and Singer, P. C., The impact of ozonation on particle stability and the removal of TOC and THM precursors, Jour. AWWA., 83(3), pp. 11-26 (1991)
  7. Glaze, W. H., Peyton, G. R., Lin, S., Huang, R. Y., and Burleson, J. L., Destruction of pollutants in water with ozone in combinated with ultraviolet radiation. 2. Natural trihalomethane precursors, Envir.Sci.Tech., 16, pp. 454-458 (1982)
  8. Glaze, W. H., Howard, S. W. and Joseph, E. C., Evaluating the formation of brominated DBPs during ozonation, J. AWWA., 93(1), pp. 96-103 (1993)
  9. Haag, W. R., Hoigne, J., Ozonation of bromide containing waters: Kinetics of formation of hypobromous acid and bromate ion, Envir.Sci.Tech., 17(5), pp. 261-265 (1983)
  10. Joseph, G. J., Nancy, L. P., Kevin, M. R., Aieta, E. M., Stuart, W. D. and Michael, J. M., Ozonation:Assessing its role in the formation and control of disinfection by-products, J. AWWA., 80(8), pp. 74-84 (1989)
  11. Karanfil, T., Schlautman, M. A. and Erdogan, I., Survey of DOC and UV measurement practices with implications for SUVA determination, J. AWWA., 94(12), pp. 68-80 (2002)
  12. Langlais, B., Reckhow, D. A. and Brink, D. R., Ozone in water treatment: application and engineering, pp. 11-13, Lewis publishers, Denver. USA. (1991)
  13. Pontius, F., Complying with future water regurations, J. AWWA., 91(3), pp. 46-58 (1999)
  14. Singer, P. C., and Chang, S. D., Impact of ozone on the removal of particles, TOC, and THM precursors, AWWARF, Denver, USA, pp. 4 (1989)
  15. von Gunten, U., Hoigne, J., Bromate Formation during ozonation of Bromide-containing waters : Interaction of Ozone and Hydorxyl Radical Reactions, Envir.Sci.Tech., 28(7), pp. 1234-1242 (1994)