Deposition condition of YBCO films by continuous source supplying MOCVD method

연속 연료공급식 MOCVD법으로 증착시킨 YBCO 박막의 증착조건

  • 김호진 (성균관대 신소재공학과 & 원자력연구소) ;
  • 주진호 (성균관대 신소재공학과) ;
  • 최준규 (한국원자력연구소 원자력재료기술개발부) ;
  • 전병혁 (한국원자력연구소 원자력재료기술개발부) ;
  • 김찬중 (한국원자력연구소 원자력재료기술개발부)
  • Published : 2004.09.01

Abstract

YBa$_2$Cu$_3$$O_{7-x}$ (YBCO) films were deposited on MgO(100) and SrTiO$_3$(100) single crystal substrates by cold-wall type MOCVD method using continuous source supplying system. Under the deposition temperature of 740∼76$0^{\circ}C$, c-axis oriented YBCO films were obtained. In case of the YBCO films deposited on MgO (100) single crystal substrate, the critical temperature (T$_{c}$) was under 81 K regardless of the deposition conditions, whereas T$_{c}$ of the YBCO films deposited on SrTiO$_3$(100) single crystal substrate was 83∼84 K. The critical current (I$_{c}$) of the YBCO film deposited on SrTiO$_3$(100) single crystal substrate for 30 min was 49 A/cm-width and the critical current density (J$_{c}$) was 0.82 MA/$\textrm{cm}^2$ to film thickness of 0.6 ${\mu}{\textrm}{m}$. I$_{c}$ increased to 84.4 A/cm-width as the deposition time increased to 50 min, but J$_{c}$ decreased to 0.53 MA/$\textrm{cm}^2$ to film thickness of 1.8 ${\mu}{\textrm}{m}$.rm}{m}$.

Keywords

References

  1. A. Goyal, D. P. Norton, J. D. Budai, M. Paranthaman, E. D. Specht, D. M. Kroeger, D. K. Christen, Q. He, B. Saffian, F. A. List, D. F. Lee, P. M. Martin, C. E. Klaubunde, E. Harfield, V. K.Sikka, 'High critical current density superconducting tapes by epitaxial deposition of $YB_{a2}$$CU_3$$O_x$ thick films on biaxially textured metals', Appl. Phys. Lett. 69-12 (1996) 1795
  2. David. P. Norton, Amit Goyal, John. D. Budai, David K. Christen, Donald M. Kroeger, Eliot D. Specht, Qing He, Bernd Saffian, M. Paranthaman, Charles E. Klaubunde, Dominic F. Lee, Brian C. Sales, Fred A. List, 'Epitaxial $YB_{a2}$$CU_3$ $O_7$on Biaxially Textured Nickel (001): An Approach to Superconducting Tapes with High Critical Current Density', Science, 274 (1996) 755
  3. Y. Iijima, N. Tanabe, O. Kohno, Y. Ikeno, 'In-plane aligned $YB_{a2}$$CU_3$$O_{7-x}$ thin films deposited on polycrystalline metallic substrates', Appl. Phys. Lett. 60-6 (1992) 769
  4. X. D. Wu, S. R. Foltyn, P. N. Arendt, W. R. Blumenthal, I. H. Campbell, J. D. Cotton, J. Y. Coutler, W. L. Hults, M. P. Maley, H. F. Safar, and J. L. Smith, 'Properties of $YB_{a2}$$CU_3$$O_{7-y}$ thick films on flexible buffered metallic substrates', Appl. Phys. Lett., 67 (1995) 2397
  5. E. D. Specht, F. A. List, D. F. Lee, K. L. More, A. Goyal, W. B. Robbins and D. O'Neill, 'Uniform texture in meter-long $YB_{a2}$$CU_3$$O_7$tape', Physica C, 382 (2002) 342
  6. S. R. Foltyn, P. N. Arendt, R. F. DePaula, P. C. Dowden, J. Y. Coulter, J. R. Groves, L. N. Haussamen, L. P. Winston, Q. X. Jia and M. P. Maley, 'Development of meter-long YBCO coated conductors produced by ion beam assisted deposition and pulsed laser deposition', Physica C, 341-348 (2000) 2305
  7. Kazuomi Kakimoto, Yasuhiro Iijima and Takashi Saitoh, 'Fabrication of long-Y123 coated conductors by combination of lEAD and PLD', Physica C, 392-396 (2003) 783
  8. A. D. Berry, D. K. Gaskill, R. T. Holm, E. J. Cukauskas, R. Kaplan and R. L. Henry, 'Formation of high Tc superconducting films by organometallic chemical vapor deposition', Appl. Phys. Lett. 52-20 (1988) 1743
  9. O. Stadel, J. Schmidt, G. Wahl, C. Jimenez, F. Weiss, M. Krellmann, D. Selbmann, N. V. Markov, S. V. Samoylenkov, O. Yu. Gorbenko and A. R. Kaul. 'Continuous YBCO deposition onto moved tapes in liquid single source MOCVD systems'. Physica C, 341-348 (2000) 2477
  10. G. Wahl, M. Pulver, W. Decker and L. Klippe, 'CVD processes for coatings and surface modifications', Surface and Coating Technology, 100-101 (1998) 132
  11. S. Donet, F. Weiss, J. P. Senateur, P. Chaudouet, A. Abrutis, A. Teiserskis, Z. Saltyte, D. Selbmann, J. Eickemeyer, O. Stadel, G. Wahl, C. Jimenez, U. Miller, 'YBCO films on buffered Ni RABiT substrates by pulsed injection MOCVD', Physica C. 372-376 (2002) 652
  12. O. Stadel, J. Schmidt. G. Wahl, F. Weiss, D. Selbmann. J. Eickemeyer, O. Yu. Gorbenko. A. R. Kaul. C. Jimenez, 'Continuous YBCO deposition by MOCVD for coated conductors', Physica C. 372-376 (2002) 751
  13. S. Aoki, T. Yamaguchi, Y. Iijima, O. Kohno, S. Nagaya and T. Inoue, 'Characteristics of high Jc Y-Ba-Cu-O tape on metal substrate prepared by chemical vapor deposition', IEEE Transactions on Applied Superconductivity, 3-1 (1993) 1691
  14. K. Onabe. H. Akata, K. Higashiyama. S. Nagaya and T. Saitoh. 'Superconductingproperty of $YB_{a2}$$CU_3$$O_x$ films formed on silver substrates by continuous chemical vapor deposition technique'. IEEE Transactions on Applied Superconductivity, 11-1 (2001) 3150
  15. Eko H. Sujiono. P. Arifin and M. Barmawi, '$YB_{a2 $$CU_3$$O_{7-8}$ thin films deposited by a vertical MOCVD reactor', lvIaterials Chemistry and Physics, 73 (2002) 47
  16. B. Schulte, M. Maul, P. Haussler. W. Becker. M. Schmeiz, M. Steins and H. Adrian, 'Compositional effects in $Y_x$$Ba_y$$Cu_z$$O_{7-8}$ thin films prepared by metal-organic chemical vapour deposition", J. of Alloys Comp., 195 (1993) 299
  17. R Hiskes, S. A. Dicarolis. J. L. Young. S.S. Laderman, R.D. Jacowitz and R.C. Taber. 'single source metalorganic chemical vapor deposition of low microwave surface resistance $YB_{a2}$$CU_3$$O_7$, Appl. Phys. Lett.. 59 (1991) 606
  18. W. Decker, Yu Erokin, O. Gorbenko. I. Graboy, A. Kaul, A. Nurnberg. M. Pulver. R. Stolle. and G. Wahl. Proc. E-MRS Meeting Strasbourg, (1993)
  19. S. A. Degterov, Proc. Int. Worshop MSU-HTSCII, Moscow, (1991) 142
  20. F. Weiss, K. FrOhlich, R. Haase, M. Labeau, D. Selbmann, J. P. Senateur and O. Thomas, 'Preparation of $YB_{a2}$$CU_3$$O_7$ films by low pressure MOCVD using liquid solution sources', J. of Dephysique lV, (1993) 321
  21. Klippe L. and Wahl G.. 'Preparation of superconducting YBCO films on polycrystalline YSZ substrates by single-source MOCVD', Ints. Phys. Conf Ser., 148 (1995) 611
  22. T. Morishita, 'Evaluation of a-axis oriented $YB_{a2}$$CU_3$$O_y$ thin film', Advances in Superconductivity, 9 (1996) 1017
  23. Y. Yoshida, Y. Ito, H. Nagai, Y. Takai and I. Hirabayashi, 'Preparation of a-axis oriented $YB_{a2}$$CU_3$$O_{7-y}$ films by metalorganic chemical vapor deposition using liquid sources', Physica C, 282-287 (1997) 595
  24. T. Ushida, K Higashiyama, I. Hirabayashi and S. Tanaka, 'Preparation of selectivity controlled a-axis oriented YBCO films by laser MOCVD', Supercond. Sci. Technol.. 4 (1991) 445
  25. S. Matsuno, F. Uchikawa and S. Utsunomiya, 'Metalorganic chemical vapor deposition using a single solution source for high Jc $YB_{a2}$$CU_3$$O_{7-x}$ superconducting films', Appl. Phys. Lett.. 60 (1992) 2427