금속광산지역 오염 토양/지하수의 복원기술 동향

Emerging Remediation Technologies for the Contaminated Soil/Groundwater in the Metal Mining Areas

  • 김경웅 (광주과학기술원 환경공학과 지질환경 비소제어 연구실)
  • 발행 : 2004.02.01

초록

환경오염저감 및 제어기술은 환경/방재 기술분야로 포스트 반도체 주력산업의 고도화분야에 해당되며, 그 중 오염토양 및 지하수 복원기술은 앞으로 많은 수요가 예상되는 핵심기술이라 할 것이다. 국내의 경우 폐금속광산이 다수 존재하며 이로 인한 중금속 및 비소오염문제가 심각해지고 있는 시점에서 이를 복원하기 위한 최신기술의 동향을 알아보는 것이 필요할 것이다. 현재 이 분야의 선진국인 미국 및 유럽각국에서의 기술개발은 2차적인 오염을 유발하지 않을 청정기술의 개발과 개발기술의 현장적용에 초점이 맞추어 지고 있는 추세이다. 여기에 최근에 개발되어진 신기술중에 이러한 장점으로 인해 주목받고 있는 기술인 전기동력학 기술, 투수성 반응벽체기술, 고형화/안정화기술, 박테리아를 이용한 생체흡착기술, 박테리아를 이용한 용출기술, 식물정화기술을 소개하고자 한다.

Pollution reduction and/or control technology becomes one of the pressing post-semiconductor research field to lead an advanced industrial structure. Soil/groundwater remediation techniques may act as a core technology which will create many demands on pollution reduction areas. A plenty numbers of abandoned metal mines were left without any remediation action in Korea, and it may be potential sources of heavy metal and As contamination in the ecosystem. In order to bring this soil contamination to a settlement, the emerging soil/groundwater remediation techniques should be introduced. Main research topics in the United States and Europe move towards the clean remediation technology without any secondary impact and the feasible application of developing technique into the field scale study. With these advantages, several soil/groundwater techniques such as electrokinetic soil processing, permeable reactive barrier, stabilization/solidification, biosorption, soil flushing with biosurfactant, bioleaching and phytoremediation will be summarized in this paper.

키워드

참고문헌

  1. 국가기술지도 국가과학기술위원회
  2. Environ. Sci. and Technol. v.27 Principles of electrokinetic remediation Acar,Y.B.;Alshawabkeh,A.N. https://doi.org/10.1021/es00049a002
  3. Environ. Sci. and Technol. v.31 Microbial mobilization of arsenic from sediments of the Abergona waershed Ahmann,D.;Krumholz,L.;Hemond,H.;Lovely,D.;Morel,F. https://doi.org/10.1021/es970124k
  4. Water Environment Research v.72 Phytoremediation of 1,4-dioxin by hybrid poplar tress Aitchison,E.W.;Kelley,S.L.;Alvarez,J.J.;Schnoor,J.L. https://doi.org/10.2175/106143000X137536
  5. J. Geotech. Eng. v.122 Electrokinetic remediation. Ⅱ: Theoretical model Alshawabkeh,A.N.;Acar,Y.B. https://doi.org/10.1061/(ASCE)0733-9410(1996)122:3(186)
  6. J. Environ. Eng. v.125 Practical aspects of in-situ electrokinetic extraction Alshawabkeh,A.N.;Yeung,A.T.;Bricka,M.R. https://doi.org/10.1061/(ASCE)0733-9372(1999)125:1(27)
  7. J. of Environ. Eng. v.123 Zero-valent iron for the in-situ remediation of selected metals in ground-water Cantrell,K.J.;Kaplan,D.I. https://doi.org/10.1061/(ASCE)0733-9372(1997)123:5(499)
  8. Management Committee Meetings: Plant biotechnology for the removal of organic pollutants and toxic metals from wastewaters and contaminated sites Strategies for selection in phytoremediation Grosse,W.;Stuhlfauth-Roisch,U.;Cheng,S.;Vidakovic-Cifrek,Z.
  9. supported by the U.S Dep. of Energy, Cooperative Agreement No. DEFC04-95AL85832 Literature Review: Phytoaccumulation of Chromium, Uranium, and Plutonium in Plant Systems Hossner,L.R.;Loeppert,R.H.;Newton,R.J.;Szaniszlo;Attrep,M.Jr.
  10. PhD dissertation, Texas A&M Univ. Electrokinetic remediation of heavy metal contaminated soils Hsu,C.N.
  11. Sci. Tot. Environ. v.219 Paradigm of metal accumulation in rooted aquatic vascular plants Jackson,L.J. https://doi.org/10.1016/S0048-9697(98)00231-9
  12. Environ. Sci. and Technol. v.33 Arsenite and arsenate adsorption on ferryhydrite: surface charge reduction and net OH-release stoichiometry Jain,A.;Raven,K.P.;Loeppert,R.H. https://doi.org/10.1021/es980722e
  13. Sep. Sci. and Technol. v.28 Electrokinetic processing for the removal of radionuclides in soils Kim,K.H.;Kim,S.O.;Lee,C.W.;Lee,M.H.;Kim,K.W.
  14. Environ. Sci. and Techol. v.37 Stabilization of available arsenic in highly contaminated mine tailings using iron Kim,J.Y.;Davis,A.P.;Kim,K.W. https://doi.org/10.1021/es020799+
  15. Water Research v.36 Pilot scale study on the ex situ electrokinetic removal of heavy metals from municipal wastewater sludges Kim,S.O.;Moon,S.H.;Kim,K.W.;Yun,S.T. https://doi.org/10.1016/S0043-1354(02)00141-0
  16. Crit. Rev. Environ. Control v.21 A review of arsenic in ground water Korte,N.E.;Fernando,q. https://doi.org/10.1080/10643389109388408
  17. 4th Int'l Symp. on AEM Colloid barrier formation by nanoscale hematite particles Ko,I.W.;Kim,J.Y.;Kim,K.W.
  18. Colloids Surface v.191 Nanoscale iron particles for complete reduction of chlorinated ethane Lien,H.L.;Zhzng,W.X. https://doi.org/10.1016/S0927-7757(01)00767-1
  19. Engrg. Geology v.60 Remediation technologies for metal-contaminated soils and groundwater: an evaluation Mulligan,C.N.;Yong,R.N.;Gibbs,B.F. https://doi.org/10.1016/S0013-7952(00)00101-0
  20. Appl. Environ. Microbiol. v.55 Bacterial sorption of heavy metals Mullen,M.D.;Wolf,D.C.;Ferris,F.G.;Beveridge,T.J.;Flemming,C.A.;Bailey,G.W.
  21. Geomicrobiology v.15 A brief review of microbial arsenate reduction Newman,D.K.;Ahmann,D.;Morel,F.M.M. https://doi.org/10.1080/01490459809378082
  22. Applied Geochem v.15 Mechanism of arsenic release to groundwater, Bangladesh and West Bengal Nickson,R.T.;McAtrhur,J.M.;Ravenscroft,P.;Burgess,W.G.;Ahmed,K.M. https://doi.org/10.1016/S0883-2927(99)00086-4
  23. Unit operations and processes in environmental engineering Reynolds,T.D.;Richards,P.A.
  24. EPA/540/2-88/004 Technology screening guide for contaminated surface soils U.S.EPA
  25. EPA/540/2-91/009 Superfund Engineering Issue: Treatment of lead-contaminated soils U.S.EPA
  26. EPA 542-F-98-011 A Citizen's Guide to Phytoremediation. Office of Solid Waste and Emergency Response (5102G) U.S.EPA
  27. Sci. Total Environ. v.289 Electrokinetic soil remediation-critical overview Virkutyte,J.;Sillanpaa,M.;Latostenmaa,P.
  28. Biosorption of Heavy Metals Removal and recovery of heavy metals by biosorption Volesky,B.;Volesky,B.(ed.)
  29. Biotechnol. Prog. v.11 Biosorption of heavy metals Volesky,B.;Holan,Z.R. https://doi.org/10.1021/bp00033a001