A Study on the pH-, pNa- and pK-Sensing Properties of K and Al Coimplanted SiO$_2$ Thin Films

K 및 Al 이중이온주입된 SiO$_2$ 박막의 pH, pNa 및 pK 농도 감지특성에 관한 연구

  • Published : 2003.07.01

Abstract

Silicon dioxide (SiO$_2$) layers were fabricated on Si$_3$N$_4$/SiO$_2$/Si layer structures by low pressure chemical vapor deposition (LPCVD). Potassium and aluminum were then coimplanted by implanting potassium ions with the energy of 100 [keY] and dose of 5x10$^{16}$ [cm ̄$^2$] and 1x10$^{17}$ [cm ̄$^2$] into an aluminum buffer layer on the SiO$_2$Si$_3$N4/SiO$_2$/Si structure. The pH, pNa, and pK ion sensitivities of the resulting layers were investigated and compared to those of as-deposited silicon dioxide layer. The pK-sensitivity of the silicon dioxide was enhanced by the K and Al coimplantation. On the contrary, the pH and pNa-sensitivities of the coimplanted silicon dioxides were quite lower than that of the as-deposited silicon dioxide.

Keywords

References

  1. P. Bergveld, 'Development, operation, and application of the Ion-Sensitive Field-Effect Transistor as a tool for electrophysilology', IEEE Trans. Biomed. Eng. Vol. 19, No.5, pp.342-351, 1972 https://doi.org/10.1109/TBME.1972.324137
  2. P. Bergveld, 'Thirty years of ISFETOLOGY: What happened in the past 30 years and what may happen in the next 30 years', Sensors and Actuators, B88, pp.1-20, 2003 https://doi.org/10.1016/S0925-4005(02)00301-5
  3. T. Kuriyama and J. Kimura, 'Integrated multibiosensors fabricated on SOS chip', Chemical Sensor Technology, Vo1.2, Elsevier Amsterdam-Oxford-New York-Tokyo, pp.191-204, 1988
  4. Yu.G. Mourzina, J. Schubert, W. Zander, A Legin, Yu.G. Vlasov, H. Lueth, M.J. Schoening, 'Development of multi sensor systems based on chalcogenide thin film chemical sensors for the simultaneous mutlicomponent analysis of metal ions in complex solutions', Electrochimica Acta, Vol.47, pp.251-258, 2001 https://doi.org/10.1016/S0013-4686(01)00563-1
  5. A. Ismail, T. Harada, T. Yoshinobu, H. Iwasaki, M.J. Schoening, H. Lueth, 'Investigation of pulsed laser-deposited $Al_2O_3$ as a high pH-sensitive layer for LAPS-based biosensing applications', Sensors and Actuators, B71, pp.169-172, 2000 https://doi.org/10.1016/S0925-4005(99)00380-9
  6. L. Bousse, D. Hafeman, and N. Tran, 'Time-dependance of the chemical response of silicon nitride surfaces', Sensors and Actuators, B1, pp.361-367, 1990 https://doi.org/10.1016/0925-4005(90)80231-N
  7. K.-M. Chen, G.-H. Li, L.-X. Chen, and Y. Zhu, 'Improvement of structural instabilities of the ion-sensitive field-effect transistor (ISFET)', Sensors and Actuators, B13-14, pp.209-211, 1993 https://doi.org/10.1016/0925-4005(93)85363-F
  8. T. Mikolajick, R. Kuehnhold, and H. Ryssel, 'The pH-sensing properties of tantalum pentoxide films fabricated by metal organic low pressure chemical vapor deposition', Sensors and Actuators, B44, pp.262-267, 1997 https://doi.org/10.1016/S0925-4005(97)00166-4
  9. A.S. Poggosian, 'The super-nernstian pH Sensitivity of $Ta_2O_5$-Gate ISFETs', Sensors and Actuators, B7, pp.367-370, 1992 https://doi.org/10.1016/0925-4005(92)80326-S
  10. G. Eisenman, 'Glass electrodes for hydrogen and other cations', Marcel Dekker INC., New York, 1967
  11. M.T. Pham and W. Hoffmann, 'Ion-sensitive membranes fabricated by the ion-beam technique', Sensors and Actuators, 5, pp.217-228, 1984 https://doi.org/10.1016/0250-6874(84)80012-8
  12. M.T. Pham, 'Characterization of ion-implanted gate insulator films for use as ion-selective membrane in ISFETs', Sensors and Actuators, A7, pp.576-579, 1992 https://doi.org/10.1016/0925-4005(92)80367-7
  13. T. Ito, H. Inagaki, and I. Igarashi, 'ISFETs with the ion-sensitive membranes fabricated by ion implantation', IEEE Trans. on Electron Devices, Vol.35, No.1, pp.56-64, 1988 https://doi.org/10.1109/16.2415
  14. B. Hajji, P. Temple-Boyer, J Launay, T. do Canto, A Martinez, 'pH, pK and pNa detection properties of $SiO_2/Si_3N_4$ ISFET chemical sensors', Microelectronics Reliability, 40, pp.783-786, 2000 https://doi.org/10.1016/S0026-2714(99)00285-1
  15. A Errachid, J. Bausells, N.Zine, H. Jaffrezic, C. Martelet, N. Jaffrezic-Renault, M. Charbonnier, 'Anlaytical features of $K^+$ -sensitive membrane obtained by implantation in silicon dioxide films', Materials Science and Engineering, C21, pp.9-13, 2002 https://doi.org/10.1016/S0928-4931(02)00054-1