Macromolecular Research

  • 제11권2호
  • /
  • Pages.128-131
  • /
  • 2003
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  • 1598-5032(pISSN)
  • /
  • 2092-7673(eISSN)
한국고분자학회 (The Polymer Society of Korea)
권호 표지

Synthesis and Surface Structure of Polyester-block-Poly(dimethylsiloxane)-block-Polyester Copolymers

  • Lee, Won-Ki (Division of Chemical Engineering, Pukyong National University) ;
  • Park, Sang-Bo (Division of Chemical Engineering, Pukyong National University) ;
  • Lee, Jin-Kook (Department of Polymer Science & Engineering, Pusan National University)
  • 발행 : 2003.04.01
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초록

Triblock copolymers of poly(dimethylsiloxane) (PDMS) middle block and degradable polyester end blocks were synthesized by the ring open polymerization initialed by alcohol groups of PDMS. Surface composition of the triblock copolymers is measured by angle-dependent electron spectroscopy for chemical analysis. The PDMS blocks are segregated in the topmost surface region and constituted up to 90 mol% of the surface, even though the overall bulk PDMS concentrations of the block copolymers is 6% or less. This result suggests that the bulk property of degradable polyesters is essentially unchanged due to the high surface segregation of PDMS.

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참고문헌

  1. J. Appl. Polym. Sci. v.15 C. Y. Kim;J. Evans;D. A. I. Goring https://doi.org/10.1002/app.1971.070150607
  2. J. Mater. Sci. v.14 D. Briggs;D. M. Brewis;M. B. Koniecko https://doi.org/10.1007/BF00549306
  3. Macromolecules v.16 X. D. Feng;Y. H. Sun;K. Y. Qin
  4. Bull. Korean Chem. Soc. v.8 M. K. Kim;S. H. Yuk;M. S. Jhon
  5. Macromolecules v.22 M. B. Clark, Jr.;C. A. Brukhardt;J. A. Gradella, Jr. https://doi.org/10.1021/ma00202a020
  6. Macromolecules v.25 X. Chen;J. A. Gardella, Jr.;P. L. Kumler https://doi.org/10.1021/ma00050a035
  7. Korea Polym. J. v.5 J. H. Lee;Y. M. Ju;S. K. Kim;S. T. Lee;Y. W. Park
  8. Polymer(Korea) v.22 H. W. Kim;S. S. Kim;J. M. Kim
  9. Bull. Korean Chem. Soc. v.22 W. K. Lee;N. J. Jo;C. S. Ha
  10. Macromolecules v.34 W. K. Lee;I. Losito;J. A. Gardella, Jr.;W. L. Hicks, Jr. https://doi.org/10.1021/ma0000327
  11. Korea Polym. J. v.9 C. S. Ha;W. K. Lee;W. J. Cho;T. Ougizawa;T. Inoue
  12. Macromol. Biosci. v.1 W. K. Lee;Y. Doi;C. S. Ha https://doi.org/10.1002/1616-5195(20010301)1:3<114::AID-MABI114>3.0.CO;2-N
  13. Properties of Polymers D. W. van Krevelen
  14. J. Polym. Sci. Polym. Chem. Ed. v.27 I. Yilgor;W. P. Steckle, Jr.;E. Yilgor;R. G. Freelin;J. S. Riffle https://doi.org/10.1002/pola.1989.080271110
  15. Macromolecules v.31 J. Chen;J. A. Gardella, Jr. https://doi.org/10.1021/ma980639b