Journal of the Korean Applied Science and Technology (한국응용과학기술학회지)

The Korean Society of Applied Science and Technology (한국응용과학기술학회)
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Kinetic Investigation of Styrene Derivatives Oxidation Mechanism by Mn(III)-porphyrin

Mn(III)-porphyrin에 의한 Styrene 유도체의 산화반응 메카니즘 연구

  • Na, Hun-Gil (Department of Chemistry, Daejin University)
  • 나훈길 (대진대학교 이공대학 화학과)
  • Published : 2002.09.30
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Abstract

The catalytic activities of several metalloporphyrin, wherein the porphyrins are TPP(5,lO,l5,20-Tetraphenyl-21H,23H-porphyrin) and (p-X)TPP (X =$CH_{3}O$, $CH_{3}$, F, Cl), are reported for the oxidation of styrene and it's derivatives. The electronic effects of substrates and porphyrins on the catalytic activity of metalloporphyrin containing the transition metal ion such as Mn(III) was discussed. Investigating the correlation between the Michaelis-Menten's rate parameters and the substituent constants, we are going to analyze the influences on the changes of catalytic activity or rate determining step during the processes of the formation and the dissociation of the M-oxo-olefin.

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References

  1. H. Yoon and C. J. Burrows, J. Am. Chem. Soc., 110, 4087 (1988) https://doi.org/10.1021/ja00220a086
  2. T. R. Wagler and C. J. Burrows, Tetrahedron Lett., 40, 5091 (1988)
  3. H. Ohtake, T. Higuchi, and M. Hirobe, J. Am. Chem. Soc., 114, 10660 (1992) https://doi.org/10.1021/ja00052a086
  4. J. A. S. J. Razenberg, R. J. M. Nolte, and W. Drenth, Tetrahedron Lett., 25, 789(1984) https://doi.org/10.1016/S0040-4039(01)80028-9
  5. D. Ostovic and T. C. Bruice, Acc. Chem Res., 25, 314 (1992) https://doi.org/10.1021/ar00019a007
  6. H. Lineweaver and P. Burk, J. Am. Chem. Soc., 56, 658 (1934) https://doi.org/10.1021/ja01318a036
  7. D. D. Perrin and W. L. F. Annago, 'In Purification of Laboratory Chemicals', 2nded., Pergamon Press, Oxford (1988)
  8. J. B. Kim, J. J. Leonard, and F. R, Longo, J. Am Chem Soc., 88, 3986(1972)
  9. H. Kobayashi, T. Higuchi, and Y. Kaizu, Bullutin of Chemical Society of Japan., 48, 3137 (1975) https://doi.org/10.1246/bcsj.48.3137
  10. R. D. Jones, D. A. Summerville, and F. Basolo, J. Am. Chem. Soc. 100, 4416 (1976) https://doi.org/10.1021/ja00482a017
  11. Maho. Bressan and Morvillo, Antonino. Inorg. Chem., 28, 950 (1989) https://doi.org/10.1021/ic00304a028
  12. H. C. Brown and Y. Okamoto, J. Am. Chern Soc, 80, 4979 (1958) https://doi.org/10.1021/ja01551a055
  13. H, H. Jaffe, Chem. Rev. 53, 191 (1953) https://doi.org/10.1021/cr60165a003