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http://dx.doi.org/10.12925/jkocs.2002.19.3.8

Kinetic Investigation of Styrene Derivatives Oxidation Mechanism by Mn(III)-porphyrin  

Na, Hun-Gil (Department of Chemistry, Daejin University)
Publication Information
Journal of the Korean Applied Science and Technology / v.19, no.3, 2002 , pp. 206-212 More about this Journal
Abstract
The catalytic activities of several metalloporphyrin, wherein the porphyrins are TPP(5,lO,l5,20-Tetraphenyl-21H,23H-porphyrin) and (p-X)TPP (X =$CH_{3}O$, $CH_{3}$, F, Cl), are reported for the oxidation of styrene and it's derivatives. The electronic effects of substrates and porphyrins on the catalytic activity of metalloporphyrin containing the transition metal ion such as Mn(III) was discussed. Investigating the correlation between the Michaelis-Menten's rate parameters and the substituent constants, we are going to analyze the influences on the changes of catalytic activity or rate determining step during the processes of the formation and the dissociation of the M-oxo-olefin.
Keywords
Mn(III)-porphyrin; styrene derivatives; oxidation mechanism;
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