Micro-Raman Spectroscopy and Cathodoluminescence Study of Cross-section of Diamond Film

  • Wang, Chun-Lei (State Key Lab. of Superhard Materials, Jilin University) ;
  • Akimitsu Hatta (Department of Electrical Engineering, Osaka University) ;
  • Jaihyung Won (Department of Electrical Engineering, Osaka University) ;
  • Jaihyung Won (Department of Electrical Engineering, Osaka University) ;
  • Nan Jinang (Department of Electrical Engineering, Osaka University) ;
  • Toshimichi Ito (Department of Electrical Engineering, Osaka University) ;
  • Takatomo Sasaki (Department of Electrical Engineering, Osaka University) ;
  • Akio Hiraki (Department of Electrical Engineering, Osaka University) ;
  • Zengsun Jin (Department of Electrical Engineering, Osaka University)
  • 발행 : 1997.03.01

초록

Diamond film (24$\mu\textrm{m}$) were prepared by Microwave Plasma Chemical Vapor Deposition method from a reactive CO/H$_2$ mixtures. Micro-Raman spectroscopy and micro-cathodoluminescence study were carried out along the crosssection and correlated to SEM observation. CL image of cross-section was also investigated. Peak position, FWHM of Raman spectrum were determined using Lorentzing fit. The stress in this sample is 0.4~0.7 GPa compressive stress, and along the distance the compressive stress reduced. The Raman peak broadening is dominated by phonon life time reduction at grain boundaries and defect sites. Defects and impurities were mainly present inside the film, not at Silicon/Diamond interface.

키워드

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