Electrochemical Characteristics of Ruthenium Oxide Electrode-Organic Electrolyte System

유기전해액에서 루테늄산화물 전극의 전기화학적 특성

  • 도칠훈 (한국전기연구원 전지연구그룹) ;
  • 최상진 (한국전기연구원 전지연구그룹) ;
  • 문성인 (한국전기연구원 전지연구그룹) ;
  • 윤문수 (한국전기연구원 전지연구그룹) ;
  • 육경창 ((주)기노리텍) ;
  • 김상길 (성남전자공업(주))
  • Published : 2002.07.08

Abstract

Electrochemical capacitor made with metal oxide electrode uses rapid and reversible protonation/deprotonation of metal oxide material under the aqueous acidic solution, generally. Electrochemical stability window of aqueous electrolyte-type capacitor is narrow compared to that of organic electrolyte-type capacitor. Electrochemical characteristics of electrochemical capacitor made with metal oxide electrode and lithium cation based organic electrolyte were evaluated. Electrochemical capacitor based on $RuO_2$ electrode material and 1M $LiPF_6$ in mixed solvents of EC, DEC, and EMC has anodic and cathodic specific capacitance of 145 and 142 F/g-$RuO_2{\cdot}nH_2O$, respectively, by using cyclic voltammetry with scan rate of 2 mV/sec g-$RuO_2$ in potential range of 2.0~4.2V(Li|$Li^+$).

Keywords