• 제목/요약/키워드: zircon

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청송 세계지질공원 내 백악기 일직층, 점곡층, 사곡층의 쇄설성 저어콘 U-Pb 연령: 퇴적시기와 기원지 (Detrital zircon U-Pb ages of the Cretaceous Iljik, Jeomgok, and Sagok formations in the Cheongsong Global Geopark, Korea: Depositional age and Provenance)

  • 채용운;최태진;백인성;김종선;김현주;정훈영;임현수
    • 한국지구과학회지
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    • 제42권1호
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    • pp.11-38
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    • 2021
  • 경상분지 하양층군의 퇴적시기와 기원지 변화를 밝히기 위해 청송 세계지질공원의 지질명소인 백석탄(일직층), 만안자암(점곡층), 신성리(사곡층) 지역에서 쇄설성 저어콘에 대한 U-Pb 연령측정을 실시하였다. 일직층에서는 백악기 저어콘이 발견되지 않고 쥐라기와 트라이아스기의 저어콘이 대부분이며, 선캄브리아 시대의 저어콘은 드물게 산출된다. 반면 점곡층과 사곡층은 백악기와 쥐라기, 고원생대의 저어콘이 우세하며 유사한 연령분포를 보인다. 점곡층과 사곡층의 백악기 저어콘에서 각각 103.2±0.3 Ma와 104.2±0.5 Ma의 가장 젊은 가중평균연령을 구했다. 연구결과에 의하면 점곡층 및 사곡층의 퇴적시기는 앨비안에 해당된다. 쇄설성 저어콘의 연령분포는 일직층과 점곡층 사이에 기원지의 중요한 변화가 있었음을 지시한다. 일직층은 주로 주변의 관입암체에서 퇴적물이 공급된 것으로 보이지만, 점곡층과 사곡층은 일본 남서부의 쥐라기 부가대의 비교적 젊은 퇴적단위로부터 기원한 것으로 해석된다.

단양 국가지질공원 기반암류의 SHRIMP 저어콘 U-Pb 연령 (SHRIMP Zircon U-Pb Ages of Basement Rocks in the Danyang National Geopark)

  • 정원석;한기운;김태환;엄현우;김윤섭
    • 광물과 암석
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    • 제33권4호
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    • pp.339-347
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    • 2020
  • 단양 국가지질공원 남쪽에 분포하는 기반암에서 저어콘 U-Pb 연령측정을 수행하였다. 연령 측정은 2개의 시료에서 실시하였으며, 이들 시료는 우흑질과 우백질이 뚜렷이 구분되는 혼성암질 편마암으로 흑운모±규선석±석류석+장석+석영의 광물조합을 가진다. 함규선석 및 함석류석 편마암시료에서 각각 수집한 저어콘 결정들에 대해 고분해능 이차이온질량분석기(SHRIMP)를 사용하여 U-Pb 동위원소 성분비를 측정하였으며, 이로부터 1870±10 Ma (2σ)와 1863±6 Ma (2σ)의 변성 연령을 구하였다. 1.87~1.86 Ga의 변성 연령은 영남육괴고원생대 고온-저압의 광역변성작용의 시기(1.87~1.85 Ga)와 일치한다. 저어콘 결정들의 상속핵 연령을 기반으로 두 시료에서 얻어진 최고 퇴적연령은 2.06 Ga로 혼성암질 편마암 모암의 퇴적시기는 2.06~1.87 Ga 사이일 것으로 추정된다.

$ZrO_2$$ZrSiO_4$ 첨가에 따른 Mullite/Zirconia 복합체의 치밀화 거동 및 강도 증진 (Densification Behaviour and Strengthening of Mullite/Ziroconia Composite with Addition of $ZrO_2$ or $ZrSiO_4$)

  • 김인섭;이승석;박주석;이경희;이병하
    • 한국세라믹학회지
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    • 제36권10호
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    • pp.1080-1086
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    • 1999
  • Mullite/zirconia composite was synthesized by adding zirconia and Zircon to mixture of Hapcheon kaolin(grade pink A) and aluminium nitrate salt in order to enhance strength of the mullite specimens. Kaolin and aluminium nitrate salt was mixed milled and calcined at 100$0^{\circ}C$ and then 5wt% mullite seed was added to increase mullite content. The influence of the additives(ZrO2 and ZrSiO4) and sintering temperature on the strength of the sintered specimens was investigated. The flexural strength of the specimens containing 10wt% zirconia was enhanced from 150MPa without the additive up to 300MPa after heat treatment at 156$0^{\circ}C$ In the case of addition of 15wt% zircon the strength of the specimens systhesized at 1$600^{\circ}C$ was 225 MPa.

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안정화 CdS-CdSe계 채료에 관한 연구 제2보$ ZrSiO_4-Cd(S_xS_{1-x})$ 의 합성 (A Study on Stabilized CdS-CdSe Red Stain A Study on Zircon Cadmium Sulphoselenide Stain)

  • 이종근;김종옥
    • 한국세라믹학회지
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    • 제23권4호
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    • pp.23-26
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    • 1986
  • The synthetic conditions of $ ZrSiO_4-Cd(S_xS_{1-x})$ stains from CdS, Se, $SiO_2$ , 4ZrO_2$ and Lif were investigated and the colors were examined. Colors of the stains prepared were yellow orange red pink ruby and violet in relation to both the content of CdS-Se in $ZrSiO_4$ and firing temperature. Colors of these series stains were thermally stabilized probably by the structural stability of zirconium silicate. Furthermore by the result of X-ray diffraction analysis it is assumed that color of the zircon cadmium sulphoselenide $ ZrSiO_4-Cd(S_xS_{1-x})$ stain is developed by neither the coloring ions in $ZrSiO_4$ lattice nor the solid solution of $ZrSiO_4$ and $Cd(S_xS_{1-x})$ but by the small crystals of $Cd(S_xS_{1-x})$ being occluded by the zirconium silicate during sintering process.

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Revised Geology and Geological Structures of the Northeastern Chungnam Basin in the Southwestern Korean Peninsula

  • Yujung Kwak;Seung-Ik Park;Jeong-Yeong Park;Taejin Choi;Eun Hye Jeong
    • 자원환경지질
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    • 제55권6호
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    • pp.597-616
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    • 2022
  • The Chungnam basin is a crucial area for studying the Mesozoic crustal evolutionary history of the Korean Peninsula. This study reports the revised geology and new isotopic ages from the northeastern Chungnam Basin based on detailed geological mapping and LA-ICP-MS zircon U-Pb analysis. Our renewed geologic map defines intra-basin, basin-bounding, and basement fault systems closely related to hydrothermal gold-bearing quartz vein injections. Here, we propose the directions of (micro)structural and geochronological future work to address issues on the relationship between the tectonic process, basin evolution, and hydrothermal fluid migration in the southwestern Korean Peninsula.

Effects of Coating Materials on Fluidity and Temperature Loss of Molten Metals from Runner Systems in Full Moulds.

  • Cho, Nam-Don;Kim, Yong-Hyun;Choi, Jung-Kwon
    • 한국주조공학회지
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    • 제10권1호
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    • pp.31-42
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    • 1990
  • The full mould casting process in one of the newly developed techniques which has many advantages. Unbonded sand mould has been prepared for the major mould and $CO^2$ gas mould has been used occasionally for comparison. Patterns were built up with expanded polystyrene and coated with three different materials. Silica, graphite and zircon were used for the coating layer. The effects on fluidity and temperature loss of molten metals were investigated. The molten metals were Al-5% Si alloy, Cu-30% Zn alloy and gray iron of approximately 4.0% of carbon equivalent. Experimental variables were runner section area, superheat, sprue height, coating materials, coating thickness and apparent density of EPS pattern. The effects of coating materials on fluidity and temperature loss of the molten metals during transient pouring are summarized as follows : As runner section area, superheat and sprue height increased, fluidity increased. Temperature loss decreased as runner section area and sprue height increased. However, reversed effects were observed in the case of superheat increment. The coating materials decreased the fluidity of each alloy in the order of silica, graphite and zircon. Zircon brought to the highest temperature loss among the coating materials used. The fluidity increased in the order gray iron, Cu-30% Zn and Al-5% Si alloy while temperature loss in the reverse order. Especially in case of reduced pressure process, the fluidity was increased apparently. Al-5% Si alloy showed the lowest temperature loss among the alloys. The increment of the apparent density of EPS pattern resulted in the fluidity decrease and temperature loss increase. The relation between fluidity and temperature loss of each alloy can be expressed by the following equation within the coating thickness limit of 0.5-1.5㎜. F^*={\frac{a}{T^*-b}}-c$ where, $F^*$ : fluidity in the Full mould, $T^*$ : temperature loss in the mould. a : parameter for full mould. b, c : constants.

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$Li_2O-Al_2O_3-SiO_2$계 소지내에 Zircon상 형성에 따른 내열 강화 특성 (A Study on the Thermal Resistance Strength with the Formation of the Zircon Phase in LAS System)

  • 전덕일;김정욱;이응상
    • 한국세라믹학회지
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    • 제29권12호
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    • pp.935-941
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    • 1992
  • The LAS system with good thermal properties has a narrow range of firing and sintering temperature near the melting point. So it is difficult to sinter LAS to dense sintered body. In this study, the petalite (Li2O.Al2O3.8SiO2) with good thermal properties, was taken as a base composition, and zironia was added in this composition to broaden the firing range, increase the mechanical strength, and control the thermal expansion. The thermal and mechanical properties were investigated. The results are as follows; 1. Zirconia phase was formed in LAS matrix and apparent porosity was decreased from 0.9% to 0.5%, and the mechanical strength was kincreased from 112 MPa to 190 MPa, by the densification of body. 2. The composition Li2O.Al2O3.8SiO2 has a negative thermal expansion, but the thermal expansion was changed from negative to positive with the densification and the increase of amount of synthesized zircon phase which had positive thermal expansion. The coefficient of thermal expansion, with the increase of the amount of additives, was low as -0.74~9.06$\times$10-7/$^{\circ}C$ in 20~$600^{\circ}C$, and 7.95~20.13$\times$10-7/$^{\circ}C$ in 20~80$0^{\circ}C$. 3. The mechanical strength of LZ15 (added with ZrO2.SiO2 15 wt%) composition thermal-shocked was stable in the temperature range of 0~$600^{\circ}C$, but rapidly decreased due to the increase of thermal expansion above $600^{\circ}C$.

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