• The Journal of the Petrological Society of Korea
• /
• v.28 no.4
• /
• pp.237-249
• /
• 2019

The volcanic rocks around the Jayang caldera are classified in an order such as Jukjang Volcanics, Doil Rhyolite, Unjusan Tuff and Rhyolite intrusions. By the SHRIMP U-Pb zircon datings from zircons, eruption ages of the Unjusan Tuff are constrained as 66.65±0.96 Ma in the intracaldera, and 66.08±0.62 Ma in the extracaldera outflow, and intrusion age of the ring dike is investigated as 60.74±0.66 Ma. The age data indicate that the caldera was collapsed between 66.08 Ma and 60.74 Ma, just before the dike intruded after the explosive eruption of the Unjusan Tuff. The Jayang caldera shows the composite igneous process of a perfect volcanic cycle passing from ash-flow tuffs through caldera collapse into ring dikes in the Jayang area.

• The Journal of the Petrological Society of Korea
• /
• v.2 no.2
• /
• pp.104-121
• /
• 1993

Fission track (FT) thermochronological analyses on Mesozoic granites provide new information about cooling and uplift histories in Southeast Korea. Twenty-nine new FT sphene, zircon and apatite ages and seven track length measurements are presented for eleven granite samples. Measured mineral ages against assumed closure temperatures yield cooling rates for each sample. Relatively rapid (7-$15^{\circ}C$/Ma) and simple cooling patterns from the middle Cretaceouss (ca. 90-100 Ma) granites are caused mainly by a high thermal contrast between the intruding magma and country rocks at shallow crustal levels (ca. 1-2.5 km-depths). On the contrary, a slow overall cooling (1-$4^{\circ}C$/Ma) of the Triassic to Jurassic granites (ca. 250-200 Ma), emplaced at deep depths (>>9 km), may mainly depend upon very slow denudation of the overlying crust. The uplift history of the Triassic Yeongdeog Pluton in the Yeongyang Subbasin, west of the Yangsan Fault, is characterized by a relatively rapid uplift (~0.4 mm/a) before the total unroofing of the pluton in the earliest Cretaceous (~140 Ma) followed by a subsidence (~0.2mm/a) during the Hayang Group sedimentation. Stability of original FT zircon ages (156 Ma) and complete erasure of apatite ages suggest a range of 3 to 5.5 km for the basin subsidence. Since 120 Ma up to present, the Yeongyang Subbasin has been slowly uplifted (~0.04 mm/a). The FT age patterns of Jurassic granites both from the northeastern wing of the Ryeongnam Massif and from the northern edge of the Pohang-Kampo Block indicate that the two geologic units have been slowly uplifted with a same mean rate (~0.04 mm/a) since early Cretaceous. Estimates of Cenozoic total uplifts since 100 Ma are different: Ryeongnam Massif (~6 km)=Pohang-Kampo Block (~6 km)>Yeongyang Subbasin(~4 km).

• Analytical Science and Technology
• /
• v.25 no.1
• /
• pp.3-6
• /
• 2012

$xZrO_2-(1-x)SiO_2$ glass precursor with relatively high concentration of zirconium propoxide in metal alkoxide solution was obtained by sol-gel method and then heated at various temperature from 500 to $1,100^{\circ}C$ to investigate the effect of the thermal treatment on the crystalline structure of the glass precursor. Based on X-ray diffraction analysis, the crystalline peak was started to develop at temperature higher than $600^{\circ}C$, and the crystalline phase was considerably increased at $850^{\circ}C$ or higher. With increasing the thermal treatment temperature, the characteristic peaks, such as baddelyite, tetragonal-$ZrO_2$ and zircon, was shown at $35^{\circ}$, $50^{\circ}$ and $60^{\circ}$ of $2{\theta}$.

• Economic and Environmental Geology
• /
• v.7 no.3
• /
• pp.87-100
• /
• 1974

This paper deals with grain size analysis, heavy mineral analysis and trace element analysis of the recent sediments of Han River basin between Cheongpyong, Gyeonggi province and Seoul. For each location the samples are taken at river shoreline, river berm and river dune. The size analysis discloses that the mean values range from $-1.37{\phi}$ to $-1.60{\phi}$, sorting values range from 0.25 to 1.84, skewness values range from -0.44 to 0.51 and kurtosis values range from -0.1 to 1.75. Based on the textural parameters, the dune sand can be distinguished from the shoreline-berm sand. The content of heavy minerals of each sample ranges from 0.04 to 4.7%. The principal heavy minerals are ilmenite, magnetite, leucoxene, garnet, amphibole, pyroxene, kyanite, zircon, monazite, tourmaline, epidote, limonite, and minor minerals are apatite, sillimanite, andalusite and olivine. In general, dune sand samples contain more heavy minerals than the samples of shoreline or berm sand. This suggests that the heavy mineral concentration is affected by wind action more than by any other causes. The content of ilmenite and leucoxene decreases, whereas the content of zircon and epidote increases as it approaches the downstream region. The differences result from the variance of geological occurrences. The emission spectrochemical analysis and colorimetry analysis revealed that the content of Ni and V in the heavy minerals of the study area are higher than those of other stream sediments in Korea. On the other hand the content of Cu, Ph, Zn, Mo, W, P, Mn, Cr, Ag and Sn are lower in the study area. It has been observed also that the contents of all the elements except for Bi are higher in this area than the samples of marine sediments of Yellow Sea.

• The Journal of the Petrological Society of Korea
• /
• v.22 no.2
• /
• pp.197-208
• /
• 2013

The Namwon and Sunchang granites are neighbouring plutons intruding the Yeongnam massif and the Okcheon metamorphic belt, respectively in the southwestern part of the Korean peninsula. In this study, SHRIMP zircon U-Pb ages are determined from these plutons. The results show that the emplacement age of the Namwon granite is $185.8{\pm}0.9(2{\sigma})$ Ma. We obtained $175.0{\pm}2.0(2{\sigma})$ Ma from the northern part and $179.8{\pm}0.9(2{\sigma})$ Ma from the central part of the Sunchang granite, yielding $177.4{\pm}1.3(2{\sigma})$ Ma as the average age of the pluton. Such age results confirm that the Honam shear zone, which cause marked deformation of the Sunchang granite, was active after ca. 175 Ma.

• Resources Recycling
• /
• v.25 no.3
• /
• pp.49-54
• /
• 2016

In this study, zircon sand is separated into zirconia and silica by using the Ar-$H_2$ arc plasma refining. And then silica is removed from it by the microwave leaching method to produce a high pure zirconia. Plasma melting consist of two sequential processes; reduction process with Ar gas only followed by refining process with Ar-$H_2$ gas. After cooling in chamber. The solid phase obtained at $240^{\circ}C$ were found to be composed of 20% sulfuric acid solution. The solution was used as a leaching solution with microwave irradiation to obtain a high purity zirconia.

• The Journal of the Petrological Society of Korea
• /
• v.15 no.3 s.45
• /
• pp.119-127
• /
• 2006

Detrital zircons in iron-bearing quartzite of the Seosan Croup from southeastern part of the Cyeonggi Hassif were analysed for SHRIHP U-Pb ages. Among 42 analyses, 38 data yield concordant ages (less tan 10 % discordancy), and they concentrated at 1781~1898 Ma (n=19), $1781{\sim}1898\;Ma(n=19),\;1935{\sim}1941\;Ma(n=4),\;1996\;Ma,\;2120\;Ma\;2403{\sim}2459\;Ma(n=5)$, 2661 Ma and 3198 Ma. The data indicate that sedimentation of iron-bearing quartzite should be after ca 1.78 Ga (the youngest detrital zircon age), and argue against some of conventional idea that iron-bearing quartzite of the Seosan Group might be correlated with the Archean iron-bearing quartzite in the North China Craton.

• The Journal of Engineering Geology
• /
• v.32 no.2
• /
• pp.295-310
• /
• 2022

The Weolaksan and Sokrisan granites yield high SiO₂ and alkali (Na₂O+K₂O) contents and low CaO and P₂O₅ contents. The Al saturation index is ≥1.3, which indicates that the granites are peraluminous. The mean U and Th contents are 8.3 and 39.3 ppm, respectively, higher than typical Mesozoic granites in South Korea and about twice the global mean for granitic rocks. The causes of such high radioelement contents are related to high degrees of fractionation and the crustal origin of the granites. U- and Thbearing radioactive minerals occur in the granites include zircon, thorite, monazite, xenotime, fergusonite and uraninite. The fact that the mean Th/U ratio of the granites (5.4) is similar to the global average crustal value suggests that the radioelement contents of granite were controlled by the crustal source material. Given the correlation of Zr, Y, and heavy rare earth elements for U and Th, radioelements are more likely hosted by xenotime than zircon and monazite.

• The Journal of the Petrological Society of Korea
• /
• v.10 no.3
• /
• pp.179-189
• /
• 2001

The determination of trace concentration of U, Th and Pb was carried out for chemical dating of zircon and monazite by electron microprobe. Detection limit and error range should be considered to measure characteristic X-rays of M-line from those minerals, which are low in the ionization of atom and low peak intensity in the spectrum. The element of U, Th and Pb were simultaneously measured with 3 spectrometers equipped with PET crystal to reduce a total counting time and error due to drift of instrumental operating condition. Detection limit could be improved from increase of the peak/background ratio through adjusting pulse height analyzer about 1000 mv baseline. Under permissible maximum analytical conditions, theoretical detection limit of U, Th and Pb is down to 30 ppm (99% confidence level). The analytical result was maintained at a relative error $\pm$10% ($2{\sigma}$) in 800 ppm Pb, $\pm$5% ($2{\sigma}$) in 2330 ppm U and $\pm$10% ($2{\sigma}$) in dating from a single measurement of zircon at 15 keV and 100 nA. However, for the precise dating of zircon and monazite, if it is considered a 3 $\mu\textrm{m}$ spatial resolution, <100 ppm ($3{\sigma}$) detection limit and <$\pm$10% ($2{\sigma}$) relative error, optimum analytical conditions are given as 15~20 keV accelerating voltage, 100~200 nA beam current and 300~1200 sec total counting time. To reduce material damage by high current, there is need to be up to 3~5 $\mu\textrm{m}$ of electron beam diameter, or to use arithmetic average of multiple measuring at a shorter counting time. A younger or relatively low concentration rocks can be dated chemically by lower detection limit and improved precision resulted from increase of current and measuring time.

• The Journal of the Petrological Society of Korea
• /
• v.22 no.2
• /
• pp.83-115
• /
• 2013

Erroneous fission-track (FT) ages caused by an inappropriate calibration in the initial stage of FT dating were redefined by re-experiments and zeta calibration using duplicate samples. Revised FT zircon ages newly define the formation ages of Yucheon Group rhyolitic-dacitic tuffs as Late Cretaceous to Early Paleocene ($78{\pm}4$ Ma to $65{\pm}2$ Ma) and Gokgangdong rhyolitic tuff as Early Eocene ($52.1{\pm}2.3$ Ma). In case of the Early Miocene volcanics, FT zircon ages from a dacitic tuff of the upper Hyodongri Volcanics ($21.6{\pm}1.4$ Ma) and a dacitic lava of the uppermost Beomgokri Volcanics ($21.3{\pm}2.0$ Ma) define chronostratigraphies of the upper Beomgokri Group, respectively in the southern Eoil Basin and in the Waeup Basin. A FT zircon age ($19.8{\pm}1.6$ Ma) from the Geumori dacitic tuff defines the time of later dacitic eruption in the Janggi Basin. Based on FT zircon ages for dacitic rocks and previous age data (mostly K-Ar whole-rock, partly Ar-Ar) for basaltic-andesitic rocks, reference ages are recommended as guides for stratigraphic correlations of the Miocene volcanics and basements in SE Korea. The times of accumulation of basin-fill sediments are also deduced from ages of related volcanics. Recommended reference ages are well matched to the whole stratigraphic sequences despite complicated basin structures and a relative short time-span. The Beomgokri Group evidently predates the Janggi Group in the Eoil-Waeup basins, while it is placed at an overlapped time-level along with the earlier Janggi Group in the Janggi Basin. Therefore, the two groups cannot be uniformly defined in a sequential order. The Janggi Group of the Janggi Basin can be evidently subdivided by ca. 20 Ma-basis into two parts, i.e., the earlier (23-20 Ma) andesitic-dacitic and later (20-18 Ma) basaltic strata.