• Journal of Convergence for Information Technology
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• v.11 no.2
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• pp.117-123
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• 2021

The effects of electrolyte concentration on the electrochemical properties of Fe4[Fe(CN6)]3(FeHCF) as a novel active material for the electrode of aqueous zinc-ion batteries was investigated. The electrochemical reactions and structural stability of the FeHCF electrode were significantly affected by the electrolyte concentration. In the electrolyte solutions of 1.0-7.0 mol dm-3, the charge-discharge capacities increased with increasing electrolyte concentration, however gradually decreased as the cycle progressed. On the other hand, in the 9.0 mol dm-3 electrolyte solution, the initial capacity was relatively small, however showed good cyclability. Additionally, the FeHCF electrode after five cycles in the former electrolyte solutions, had a change in crystal structure, whereas there was no change in the latter electrolyte solution. This suggests that the performance of the FeHCF electrode is greatly influenced by the hydration structure of zinc ions present in electrolyte solutions.

• Journal of the Korean Electrochemical Society
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• v.16 no.1
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• pp.9-18
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• 2013

Components of zinc-air battery and their problems are explained. Energy density of zinc air battery is superior to other commercial ones including Li-ion batteries. Cycle life of the zinc air batteries is poor because of irreversible redox reactions on both electrodes. In order to improve the performance of the zinc air battery, catalysts, passivation, and the new structure of electrodes should be developed to optimize several reactions in an electrode. Multidisciplinary efforts, such as mechanics, corrosion science, composite materials are necessary from the beginning of the research to obtain a meaningful product.

• Journal of environmental and Sanitary engineering
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• v.16 no.3
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• pp.87-95
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• 2001

We've been investegated to find the optimum operation condition of electrlysis which have an influance on disposal efficiency of heavy metals. When we electrolyzed the testing wastewaters containing each 250mg/L of Cr and Zn ions, we exerimented with using variables like as pH, NaCl, electrode gap, electric current strength, the number of electrodes, after fastening positive electrode plate with Al, Fe, Ti and negative electrode plate with Stainless Steel Plate.

• Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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• 2008.10a
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• pp.640-643
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• 2008

In this work, a novel tunable MIM capacitor with the meshed electrode is proposed first in order to improve the tunability characteristics using fringe fields. The capacitors were fabricated on a low-resistivity Si substrate employing lead zinc niobate (PZN) thin film dielectric. The fabricated capacitor with the meshed electrode, whose line width and spacing was $2.5{\mu}m$, achieved the effective capacitance tunability of 31 % that is higher value of 18.5 % than that of the conventional capacitor with the rectangular-type electrode.

• Korean Journal of Metals and Materials
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• v.46 no.8
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• pp.495-505
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• 2008

With the high proportion of zinc coated steels in body-in-white assembly, newly developed surface roughness textured galvannealed steel sheets have been introduced. In this study, zinc coated and surface roughness textured steel sheets were welded by resistance spot welding to investigate its weldability including electrode wear test. Based on the results of tensile-shear test, nugget diameter changes, and electrode tip growth test, it was clear that both surface roughness textured steels (GA-T and GA-E) showed good weldability. Also, there was no large difference in weldability and electrode wear behavior between GA-T and GA-E steels which have different surface roughness morphology. An analysis of electrode degradation showed Fe and Zn penetration through the electrode tip surface at 2400 welds reached $55{\sim}60{\mu}m$ and $75{\sim}80{\mu}m$, respectively. Therefore, there is no significant effect of surface roughness morphology on spot weldability of surface roughness textured galvannealed steel sheets. However, slight difference in thickness of alloying layers existing on electrode tip was found between GA-T and GA-E steels.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2009.06a
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• pp.183-183
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• 2009

본 연구에선 ITO에 사용되는 Indium의 양을 줄이기 위해 ITO와 유사한 성질을 보이는 조성인 Indium - Zinc - Tin Turnary compound를 연구하였다. 각 조성은 Indium - Zinc - Tin Turnary compound를 기본으로 하여 Zinc site에 이종원소인 Al2O3와 Ga2O3를 doping함에 따라 변화되는 전기적 특성을 살며보았다. 분석에 사용한 Ceramic pellet은 일반적인 Ceramic process를 거쳐 제작되었다. 각 조성의 전기적 특성은 TCR meter와 Hall effect analyser를 이용하여 측정하였고, X-ray diffraction measurements(XRD), Scanning Electron microscope(SEM)를 이용하여 결정학적 특성을 분석하였다.

• Journal of the Korean Chemical Society
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• v.55 no.4
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• pp.575-580
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• 2011

It was investigated into the effects on zinc corrosion of the rotation speed of Zn-RDE and the oxygen concentration in borate buffer solution. Zinc corrosion was heavily influenced on the rotation speed of electrode and the oxygen concentration. We have suggested the disproportion reaction following the reversible one electron transfer as the corrosion mechanism of zinc.

• Korean Journal of Materials Research
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• v.30 no.12
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• pp.687-692
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• 2020

A zinc-air battery consists of a zinc anode, an air cathode, an electrolyte, and a separator. The active material of the positive electrode is oxygen contained in the ambient air. Therefore, zinc-air batteries have an open cell configuration. The external condition is one of the main factors for zinc-air batteries. One of the most important external conditions is temperature. To confirm the effect of temperature on the electrochemical properties of zinc-air batteries, we perform various analyses under different temperatures. Under 60 ℃ condition, the zinc-air cell shows an 84.98 % self-discharge rate. In addition, high corrosion rate and electrolyte evaporation rate are achieved at 60 ℃. Among the cells stored at various temperature conditions, the cell stored at 50 ℃ delivers the highest discharge capacity; it also shows the highest self-discharge rate (65.33 %). On the other hand, the cell stored at 30 ℃ shows only 2.28 % self-discharge rate.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.20 no.9
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• pp.798-801
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• 2007

Multilayer transparent electrodes, having a much lower electrical resistance than the widely used transparent conducting oxide electrodes, were prepared by using radio frequency magnetron sputtering. The multilayer structure consisted of five layers, indium tin oxided (ITO)/zinc oxide (ZnO)/Ag/zinc oxide (ZnO)/ITO. With about 50 nm thick ITO films, the multilayer showed a high optical transmittance in the visible range of the spectrum and had color neutrality. The electrical and optical properties of ITO/ZnO/Ag/ZnO/ITO multilayer were changed mainly by Ag film properties, which were affected by the deposition process of the upper layer. Especially ZnO layer was improved to adhesion of Ag and ITO. A high quality transparent electrode, having a resistance as low as and a high optical transmittance of 91% at 550 nm, was obtained. It could satisfy the requirement for the flexible OLED and LCD.

• Journal of the Korean institute of surface engineering
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• v.52 no.3
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• pp.123-129
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• 2019

With recent demand for the renewable energy resources, we conducted a research on the energy conversion and storage device of supercapacitor. The hybrid graphene-zinc oxide(GZO) electrodes for the supercapacitors (SCs) were fabricated and investigated. To increase the electrical conductivity of the GZO electrode, the rapid thermal annealing(RTA) in $Ar/H_2$(10%) atmosphere was applied and the effect was examined by comparing it with RTA at Ar atmosphere. In Raman spectroscopy, the electrodes annealed at 400? in $Ar/H_2$ atmosphere showed a lower ratio of D/G peak than that of annealed at Ar atmosphere, and had a larger specific capacitance(Sc) in the cyclic voltammetry(CV), and a lower the equivalent series resistance(ESR) in the electrochemical impedance spectroscopy(EIS). The reason seems to come from the better mixing of the graphene and zinc oxide by the RTA in $Ar/H_2$(10%).