• Korean Journal of Environmental Agriculture
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• v.16 no.4
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• pp.327-332
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• 1997

This study was conducted to find out the effect for removal of $NH_3$ gas, one of the offensive odor. The removal efficiencies of $NH_3$ gas through zeolie column increased with the decreased percolation velocity. The effect of zeolite colum in removing $NH_3$ gas was influenced by the water content of zeolite and the added amount of zeolite, but was not influenced by the setting method of zeolite. The $NH_3$ gas removing sequence of saturated cation species on zeolite was in order of Ca->Na->$NH_4$ ->Natural->K-zeolite. Consequently the effect of zeolite on $NH_3$ gas removal efficiency is consided by the water content, added amount and saturated cation of the zeolite.

• Applied Biological Chemistry
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• v.29 no.3
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• pp.311-317
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• 1986

This experiment was conducted to find out the minimum size of pores through that Zeolite particles moved vertically out with percolated solution in the sand column and to estimate whether they were lost through the pores in the field sandy soil. The results were as follows. 1. The amount of Zeolite loss through sand columns was increased in the order of the columns filled with $2{\sim}1>1{\sim}0.5>0.5>0.25mm$ sand particles. 2. The Zeolite particles lost through columns filled with $1{\sim}0.5$ and $0.5{\sim}0.25mm$ sand were clay fraction. 3. The pore sire that clay fraction of Zeolite mineral could migrate through was determined to be above $150{\mu}m$ and Jangchon subsoil was presumed to have possibility of Zeolite loss in consideration of its pore size distribution. 4. The suitable particle size of Zeolite for application in sandy soil was presumed to be above $2{\mu}m$.

• Korean Journal of Soil Science and Fertilizer
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• v.18 no.4
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• pp.352-358
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• 1985

Loss of cationic zeolites saturated with different ions, sodium, potasium, ammonium, magnesium and calcium ions, and changes of hydraulic conductivity were investigated in labortory. The 0.5 to 1mm sands and the zeolite particles passed 0.1mm sieve were used in the column tests. The amount of zeolite particle loss was in order of Na- > K- > $NH_4-$ saturated zeolites, and little loss was observed from Mg and Ca saturated zeolites. The loss of zeolite particles was mainly due to dispersion in solution, which was prominant when 0.01N dilute mono ionic solution and distilled water were percolated. The results also showed that the changes in hydraulic conductivity were greater in the columns where the loss of dispersed zeolite particles was higher.

• Korean Journal of Soil Science and Fertilizer
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• v.18 no.3
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• pp.240-246
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• 1985

This study was conducted to estimate the proper particle size of Zeolite particle as the soil conditioner for sandy soil. On sand columns filled with different size of sand fractions, Zeolite particles of different size were applied. Tap water was percolated through those columns under the same water level as paddy soil during rice growth. The > 0.1mm fraction of Zeolite was not vertically moved although the water was percolated for 96 hours. The < 0.1mm fraction of Zeolite was moved out 85.7% in 2-1mm, 32.64% in 1-0.5mm, and 24.5% in 0.5-0.25mm sand column, respectively. The proper diameter of Zeolite particle for amelioration of sandy soils widely distributed around river side in Korea was estimated as 0.25-0.1mm fraction in consideration of its pore size.

• Korean Journal of Environmental Agriculture
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• v.15 no.2
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• pp.232-238
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• 1996

This study was conducted to find out the optimum condition for $NH_4-N$ removal from wastewater by a zeolite column. The removal efficiency of $NH_4-N$ by a glass column packed with decreased with the increase in initial concentration, percolation velocity and fraction number. The result of multiple stepwise regressions, $NH_4-N$ removal efficiency by the zeolite column showed a high correlationship with various parameters such as percolation velocity, initial concentration, adsorption amount and fraction number. Theoretical formula by parameter coefficients of multiple stepwise regression was found to be $NH_4-N$ removal $efficiency=0.620{\times}amount$ of zeolite $-0.456{\times}percolation$ velocity $-0.212{\times}initial$ concentration $-3.038{\times}fraction$ number+100.1 In the case of the $NH_4-N$ removal efficiency in cattle farming wastewater, the experimental data were nearly coincident with the theoretical formula.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2005.04a
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• pp.151-154
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• 2005

Laboratory column experiments for simultaneous removal of Cd and Cr(VI) are conducted using newly developed material, referred to as Fe-loaded zeolite, which has both reduction ability of iron and ion exchange ability of zeolite. Breakthrough curves were obtained from each column experiment, and described with advection-dispersion equation. Apparent parameters including $K_{app}\;and\;D_{app}$ were newly introduced for effectively describing the Cr(VI) breakthrough curve. $K_{app}$ decreased with increasing initial contaminant concentration and with decreasing flow rates. Whereas, $D_{app}$ were not significantly affected by initial contaminant concentration or flow rate.

• Journal of Wetlands Research
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• v.3 no.1
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• pp.75-89
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• 2001

Constructed wetlands were typically cost less to build and operate, and require less energy than standard mechanical treatment technology but they have similar performance to centralized wastewater treatment plants. Therefore, they were constructed especially many in rural areas, where are small villages but not industries. Accordingly, plantless column tests were performed to investigate the possibility on using zeolite as a filter medium of constructed wetland for the wastewater treatment. $COD_{cr}$ removal efficiency was 94.63% at hydraulic load $314L/m^2{\cdot}d$ and filtering hight 100cm filled with a zeolite mixture. This zeolite mixture consisted of 1 : 1 by volume of a zeolite in the diameter range of 0.5 to 1mm to a zeolite in the diameter range of 1 to 3mm. According, hydraulic load $314L/m^2{\cdot}d$ was considered as optimal. Three zeolite mixture were used to determine the optimal mixing ratio by volume of a zeolite(A) in the diameter range of 0.5 to 1mm to a zeolite(B) in the diameter range of 1 to 3mm diameter. 1 : 3, 1 : 1 and only B in A to B by volume were tested at hydraulic load $314L/m^2{\cdot}d$ and filtering hight 100cm. $COD_{cr}$ removal efficiency was more than 89% at mixing ratios of 1 : 3 and 1 : 1 in A to B. Removal efficiency was lower at the column filled with only B. Removal efficiency was better at filter medium filled with mixing ratio 1 : 1 in A to B than with the other mixing ratios. Thus, it was found that the mixture of mixing ratio 1 : 1 in A to B was appropriate for filter medium of constructed wetland. Removal efficiency was higher in down-flow than in up-flow, and $COD_{cr}$ and BOD were removed best in 20cm filter height near feeding area.

• The Journal of Natural Sciences
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• v.5 no.1
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• pp.67-75
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• 1992

In the our country, especially in Yeongil and Wolsung area, abundant authigenic zeolites are found from the tuffaceous sediments and volcanic rocks of Miocene age showing wide variation in their mineralogy and abundance from horizon to horizon. The principal zeolite species identified are clinopti-lolite. mordenite. heulandite. ferrierite, and erionite. etc. Zeolite minerals are widely used in many countries in the following applications; (a) in air separation adsorption processes; (b)as desiccants; (c)in inorganic building materials; (d)in papermaking; (e)in fertilizers; (f)as soilconditioners-this application is based upon the ability of the zeolite to ion exchange with soil nutrients; (g)in the treatment of radioactive wastes; and (h)as adsorbents for toxic gases, etc. In the present paper, using natural zeolite mordenite treated with IN hydrochloric acid or IN sodium chloride solution as column packings, separation characteristics of argon, nitrogen, carbon monoxide, and methane gases have been studied by gas chromatography. By the use of mordenite treated with hydrochloric acid solution, the tailing peak of methane showed from untreated mordenite was satisfactorily reduced, although it was difficult to separate it from carbon monoxide with a column activated at $300^{\circ}C$. Using a column activated at $350^{\circ}C$, methane could be separated from carbon monoxide easily but only carbon monoxide eluted as a bad defined peak. Mordenite treated with sodium chloride solution was generally similar to chromatograms obtained by using the untreated mordenite. Both the above chemical treatments of mordenite had little effect on the separations of argon and nitrogen. The separations and the HETP values obtained from natural zeolite mordenite treated with continuously hydrochloric acid and sodium chloride solutions were almost identical with those obtained with synthetic molecular sieve 5A zeolite. On the other hand, the efficiency of column was good in the range 20~3Oml/min of the carrier helium gas rate.

• Clean Technology
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• v.10 no.3
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• pp.159-168
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• 2004

Benzene adsorption experiment was carried out for activated carbon and zeolite 13X adsorbents. Single column and dual column packed with two adsorbents were used to investigate the dynamic adsorptive characteristics. Effect of feed flow rate on the breakthrough curve was not significant. Specific adsorption amount of benzene for activated carbon was larger than that for zeolite 13X. On the contrary, adsorption amount per column volume was larger for zeolite 13X column because the density of zeolite 13X was larger. In the dynamic experiment using dual adsorbents column, length of mass transfer zone was changed by the feed direction. Breakthrough time was longer and breakthrough curve was sharper when activated carbon was packed in feed inlet and zeolite 13X was packed in column outlet. Also breakthrough time and breakthrough curve slope were affected by the packing ratio of the two adsorbents.

• Proceedings of KOSOMES biannual meeting
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• 2004.05b
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• pp.81-84
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• 2004

Control of Sediment is very important in prawn farm due to the eruption of toxic material such as W1ionized H2S, NH3 and NO2-. In this study, column test study, column with filter media such as activated carbon, zeolite, oyster shell and iron chloride to evaluate the reduction of toxicity from sediment ammonia-N(NH3) was effectively removed by Zeolite and oyster shell. It was indicated that ammonium ion(NH4+) was removed by ion exchange of zeolite. And the ammonia in the column of oyster shell was existed as the form of NH4+, which is not toxic for prawn because oyster shell was stably kept around pH 8. Therefore, some of ammonia(NH3) was reduced by oyster shell. Hydrogen sulfide and COD were effectively removed by adsorption of activated carbon and a partial removal of hydrogen sulfide was accomplished by Oyster shell. Phosphorous was removed by activated carbon, oyster shell and iron chloride. In prawn farm, the concentration of ammonia was increased with increase of pH by algae photosynthesis in the column of activated carbon, zeolite and iron chloride, but it was revealed that pH was stably kept in the column of oyster shell.