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Formation Rate of DNA Nanowires According to the APTES Concentration

  • Kim, Taek-Woon;Kim, Nam-Hoon;Roh, Yong-Han
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.06a
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    • pp.143-143
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    • 2008
  • Nanowires are promising options for building nanoscale electronic structures coming from high conductivity of nanowires. In particular, Deoxyribonucleic acid (DNA), which is structurally nanowire, can obtain highly ordered electronic components for nanocircuitry and/or nanodevices because of its very flexible length controllability, nanometer-size diameter, about 2 nm, and self-assembling properties. In this work, we used the method to form DNA-Nanowires (NWs) by using chemical treatment on Silicon (Si) surface, and Aminopropyl-triethoxysilane (APTES) was used as inducer of DNA sequence to modify the characteristics of Si surface. Moreover, we performed tilting technique to align DNA by the direction of flow of DNA solution. We investigated the assembly process between DNA molecules and APTES - coated Si surface according to the APTES concentration, from $1.2{\mu}\ell$ to $120{\mu}\ell$. Atomic Force Microscopy (AFM) images showed the combination rate of DNA molecules by the change of APTES concentration. As APTES concentration becomes thicker, aggregation of DNA molecules occurs, and this makes a kind of DNA networks. In this respect, we confirmed that there's a positive relationship between the concentration of APTES and the formation rate of DNA nanowires. Since there have been lots of research preceded to utilize DNA nanowires as template, so by using this positive relationship with proper alignment technique, realization of nano electronic devices with DNA nanowires might be feasible.

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Synthesis of CoO/Co(OH)2 Nanosheets Depending on Reaction Temperatures (반응 온도에 따른 CoO/Co(OH)2 나노시트의 합성)

  • Minjeong Lee;Gayoung Yoon;Gyeong Hee Ryu
    • Korean Journal of Materials Research
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    • v.33 no.5
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    • pp.222-228
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    • 2023
  • Transition metal oxides formed by a single or heterogeneous combination of transition metal ions and oxygen ions have various types of crystal structures, which can be classified as layered structures and non-layered structures. With non-layered structures, it is difficult to realize a two-dimensional structure using conventional synthesis methods. In this study, we report the synthesis of cobalt oxide into wafer-scale nanosheets using a surfactant-assisted method. A monolayer of ionized surfactant at the water-air interface acts as a flexible template for direct cobalt oxide crystallization below. The nanosheets synthesized on the water surface can be easily transferred to an arbitrary substrate. In addition, the synthesizing morphological and crystal structures of the nanosheets were analyzed according to the reaction temperatures. The electrochemical properties of the synthesized nanosheets were also measured at each temperature. The nanosheets synthesized at 70 ℃ exhibited higher catalytic properties for the oxygen evolution reaction than those synthesized at other temperatures. This work suggests the possibility of changing material performance by adjusting synthesis temperature when synthesizing 2D nanomaterials using a wide range of functional oxides, resulting in improved physical properties.

Be it unresolved: Measuring time delays from unresolved light curves

  • Bag, Satadru;Kim, Alex G.;Linder, Eric V.;Shafieloo, Arman
    • The Bulletin of The Korean Astronomical Society
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    • v.46 no.1
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    • pp.47.4-48
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    • 2021
  • Gravitationally lensed Type Ia supernovae may be the next frontier in cosmic probes, able to deliver independent constraints on dark energy, spatial curvature, and the Hubble constant. Measurements of time delays between the multiple images become more incisive due to the standardized candle nature of the source, monitoring for months rather than years, and partial immunity to microlensing. While currently extremely rare, hundreds of such systems should be detected by upcoming time-domain surveys. Others will have the images spatially unresolved, with the observed lightcurve a superposition of time delayed image fluxes. We investigate whether unresolved images can be recognized as lensed sources given only lightcurve information and whether time delays can be extracted robustly. We develop a method that we show can identify these systems for the case of lensed Type Ia supernovae with two images and time delays exceeding ten days. When tested on such an ensemble the method achieves a false positive rate of ≲5%, and measures the time delays with the completeness of ≳93% and with a bias of ≲0.5% for time delay ≳10 days. Since the method does not assume a template of any particular type of SN, the method has the potential to work on other types of lensed SNe systems and possibly on other transients.

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Target Recognition Triggered Split DNAzyme based Colorimetric Assay for Direct and Sensitive Methicillin-Resistance Analysis of Staphylococcus aureus

  • Jin Xu;Dandan Jin;Zhengwei Wang
    • Journal of Microbiology and Biotechnology
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    • v.34 no.6
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    • pp.1322-1327
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    • 2024
  • The accurate and rapid detection of methicillin-resistant Staphylococcus aureus (MRSA) holds significant clinical importance. This work presents a new method for detecting methicillin-resistant Staphylococcus aureus (S. aureus) in clinical samples. The method uses an aptamer-based colorimetric assay that combines a recognizing probe to identify the target and split DNAzyme to amplify the signal, resulting in a highly sensitive and direct analysis of methicillin-resistance. The identification of the PBP2a protein on the membrane of S. aureus in clinical samples leads to the allosterism of the recognizing probe, and thus provides a template for the proximity ligation of split DNAzyme. The proximity ligation of split DNAzyme forms an intact DNAzyme to identify the loop section in the L probe and generates a nicking site to release the loop sequence ("3" and "4" fragments). The "3" and "4" fragments forms an intact sequence to induce the catalytic hairpin assembly, exposing the G-rich section. The released the G-rich sequence of LR probe induces the formation of G-quadruplex-hemin DNAzyme as a colorimetric signal readout. The absorption intensity demonstrated a strong linear association with the logarithm of the S. aureus concentration across a wide range of 5 orders of magnitude dynamic range under the optimized experimental parameters. The limit of detection was calculated to be 23 CFU/ml and the method showed high selectivity for MRSA.

A Decision Making Support Model of Work Item-based Adaptation Strategy for RFID-based Construction Logistics and Progress Management (RFID 기반의 건설 물류 및 진도관리 통합체계를 위한 공종별 적용전략 의사결정모델)

  • Koo, Do-Hyung;Yoon, Su-Won;Chin, Sang-Yoon
    • Korean Journal of Construction Engineering and Management
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    • v.10 no.1
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    • pp.3-15
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    • 2009
  • As building construction projects have been more higher and bigger in scale, the needs for cost reduction, productivity improvement, and reducing of work terms have rapidly increased in recent years. There has been, accordingly, a great emphasis on the necessity of logistics and progress management by well-organized system developed based on the appliance of different management theories. Although highly developed IT technology has contributed to the efficiency and effectiveness in information research and project management, RFID has been merely applied to a single progress or a few types of materials in current management studies, not to the overall process of the projects. This research proposes a consistent and systemized approach for decision making in adopting RFID technology in a construction project to support construction logistics and progress management. With a decision making model that consists of process model and template developed in this research, risks in cost, time, and error in building RFID-based construction logistics and progress management could be minimized.

A Study on RFID System Design and Expanded EPCIS Model for Manufacturing Systems (제조 시스템의 RFID System 설계 및 EPCIS 확장모형 연구)

  • Choi, Weon-Yong;Lee, Jong-Tae
    • Journal of the Korea Safety Management & Science
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    • v.9 no.6
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    • pp.123-135
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    • 2007
  • In the recent years, the companies have manually recorded a production status in a work diary or have mainly used a bar code in order to collect each process's progress status, production performance and quality information in the production and logistics process in real time. But, it requires an additional work because the worker's record must be daily checked or the worker must read it with the bar code scanner. At this time, data's accuracy is decreased owing to the worker's intention or mistake, and it causes the problem of the system's reliability. Accordingly, in order to solve such problem, the companies have introduced RFID which comes into the spotlight in the latest automatic identification field. In order to introduce the RFID technology, the process flow must be analyzed, but the ASME sign used by most manufacturing companies has the difficult problem when the aggregation event occurs. Hence, in this study, the RFID logistic flow analysis Modeling Notation was proposed as the signature which can analyze the manufacturing logistic flow amicably, and the manufacturing logistic flow by industry type was analyzed by using the proposed RFID logistic flow analysis signature. Also, to monitor real-time information through EPCglobal network, EPCISEvent template by industry was proposed, and it was utilized as the benchmarking case of companies for RFID introduction. This study suggested to ensure the decision-making on real-time information through EPCglobal network. This study is intended to suggest the Modeling Notation suitable for RFID characteristics, and the study is intended to establish the business step and to present the vocabulary.

Development of Parametric Design Tool for Offshore Plant Cable Tray Using PML (프로그램 매크로언어를 이용한 해양 플랜트 케이블 트레이의 파라메트릭 설계 도구 개발)

  • Kim, Hyun-Cheol
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.20 no.2
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    • pp.632-637
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    • 2019
  • The cable tray design of an offshore plant production design is to optimally arrange the 3D modeling so that the cable can be installed without interfering with the structural members and various outfit equipment, and it is performed using a PDMS (Plant design management system), which is a 3D CAD system for an offshore plant layout. This study reviewed the development of PML (Programmable macro language) for a PDMS supporting offshore plant cable tray design and examined the efficiency compared to the existing method. Cable tray design PML developed in this paper enables fully parametric design using electrical outfit template library, allowing a rapid response to frequent modifications due to design changes and minimizing repetitive work fatigue by reflecting the accumulated design experience. In addition, the developed system was applied to the offshore plant structure module and it improved the work efficiency by more than 50% compared to the existing method.

Synthesis of Organized $TiO_2$ Electrodes Using Graft Copolymer and Their Applications to Dye-Sensitized Solar Cells (가지형 공중합체를 이용한 나노구조 $TiO_2$ 제조 및 염료감응 태양전지 응용)

  • Ahn, Sung Hoon;Koh, Joo Hwan;Park, Jung Tae;Kim, Jong Hak
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.06a
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    • pp.64.1-64.1
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    • 2010
  • The morphology of mesoporous $TiO_2$ films plays an important role in the operation of a DSSC. For example, the energy conversion efficiency of DSSCs with well-organized mesoporous $TiO_2$ films is much higher than those with traditional films possessing a random morphology. In previous research, well-organized mesoporous $TiO_2$ films have mainly been synthesized using an amphiphilic block copolymer, e.g., a poly(ethylene oxide) (PEO)-based template. A graft copolymer is more attractive than a block copolymer due to its low cost and the ease with which it can be synthesized. In this work, we provide the first report on the successful synthesis of well-organized mesoporous $TiO_2$ films templated by an organized graft copolymer as a structure directing agent. Well-organized mesoporous $TiO_2$ films with excellent channel connectivities were developed via the sol gel processusing an organized PVC-g-POEM graft copolymer synthesized by one-pot ATRP. The careful adjustment of copolymer composition and solvent affinity using a THF/$H_2O$/HCl mixture was used to systematically vary the material structure. The influence of the material structure on solar cell performance was then investigated. A solid-state DSSC employing both the graft copolymer templated organized 700 nm-thick $TiO_2$ films and graft copolymer electrolytes exhibited a solar conversion efficiency of 2.2% at 100 $mW/cm^2$. This value was approximately two-fold higher than that attained from a DSSC employing a random mesoporous $TiO_2$ film. The solar cell performance was maximized at 4.6% when the film thickness was increased to $2.5{\mu}m$. We believe that this graft copolymer-directed approach introduces a new and simple route toward the synthesis of well-organized metal oxide films as an alternative to a conventional block copolymer-based template.

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Phosphate Adsorption Characteristics of Zirconium Mesostructure Synthesized under Different Conditions (지르코늄 메조구조체의 합성조건 변화에 따른 인 흡착 특성)

  • Lee, Seung-Hak;Lee, Kwan-Yong;Lee, Sang-Hyup;Choi, Yong-Su
    • Journal of Korean Society of Environmental Engineers
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    • v.28 no.6
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    • pp.583-587
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    • 2006
  • In this study, the phosphate adsorption characteristics of zirconium mesostructures synthesized under different conditions were estimated. X-ray diffraction analysis, phosphate adsorption isotherm test and kinetic test was performed for the zirconium mesostructures synthesized at different inorganic/surfactant molar ratio and with different surfactant templates. The test results were analyzed with adsorption models. From this work, it was found that at the inorganic/surfactant molar ratio of 1/0.50($0.013{\cdot}Zr(SO_4){_2}:0.068{\cdot}surfactant:5.55{\cdot}H_2O$), the meso-pores in the material could be most uniformly and clearly formed and thus the adsorption capacity and reaction rate of material could be maximized. And the pore size in the mesostructure increased with the chain length of surfactant template used, and maximum phosphate adsorption amount and reaction rate could be achieved with the zirconium mesostructure synthesized with the surfactant template of dodecyltrimethylammonium bromide.

Polymeric Material Application for The Production of Ceramic Foam Catalyst

  • Sangsuriyan, Anucha;Yeetsorn, Rungsima;Tungkamani, Sabaithip;Sornchamni, Thana
    • International Journal of Advanced Culture Technology
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    • v.3 no.1
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    • pp.21-30
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    • 2015
  • Ceramic foams are prepared as positive images corresponding to a plastic foam structure which exhibits high porosities (85-90%). This structure makes the ceramic foams attractive as a catalyst in a dry reforming process, because it could reduce a high pressure drop problem. This problem causes low mass and heat transfers in the process. Furthermore, the reactants would shortly contact to catalyst surface, thus low conversion could occur. Therefore, this research addressed the preparation of dry reforming catalysts using a sol-gel catalyst preparation via a polymeric sponge method. The specific objectives of this work are to investigate the effects of polymer foam structure (such as porosity, pore sizes, and cell characteristics) on a catalyst performance and to observe the influences of catalyst preparation parameters to yield a replica of the original structure of polymeric foam. To accomplish these objectives industrial waste foams, polyurethane (PU) and polyvinyl alcohol (PVA) foams, were used as a polymeric template. Results indicated that the porosity of the polyurethane and polyvinyl alcohol foams were about 99% and 97%. Their average cell sizes were approximate 200 and 50 micrometres, respectively. The cell characteristics of polymer foams exhibited the character of a high permeability material that can be able to dip with ceramic slurry, which was synthesized with various viscosities, during a catalyst preparation step. Next, morphology of ceramic foams was explored using scanning electron microscopy (SEM), and catalyst properties, such as; temperature profile of catalyst reduction, metal dispersion, and surface area, were also characterized by $H_2-TPR$ and $H_2-TPD$ techniques, and BET, respectively. From the results, it was found that metal-particle dispersion was relatively high about 5.89%, whereas the surface area of ceramic foam catalysts was $64.52m^2/g$. Finally, the catalytic behaviour toward hydrogen production through the dry reforming of methane using a fixed-bed reactor was evaluated under certain operating conditions. The approaches from this research provide a direction for further improvement of marketable environmental friendly catalyst production.