• Title/Summary/Keyword: wire electrode

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Electrochemical Properties of Ultrathin Film Prepared Functional Polyimide by Langmuir-Blodgett Method (Langmuir-Blodgett법으로 제조한 기능성 폴리이미드 초박막의 전기화학적 특성)

  • Park, Keun-Ho;Min, Chang-Hun;Son, Tae-Chul
    • Journal of the Korean Applied Science and Technology
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    • v.26 no.4
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    • pp.400-406
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    • 2009
  • We investigated the electrochemical properties for Langmuir-Blodgett (LB) films of functionalized polyimide. LB films of polyimide monolayer were deposited by the Langmuir-Blodgett method on the indium tin oxide(ITO) glass. The electrochemical properties measured by cyclic voltammetry with a three-electrode system(an Ag/AgCl reference electrode, a platinum wire counter electrode and LB film-coated ITO working electrode) at various concentrations(0.5, 1.0, and 1.5 N) of $NaClO_4$ solution. The current of reduction and oxidation range was measured from 1650 mV to -1350 mV, continuously. The scan rates were 50, 100 and 150 mV/s, respectively. As a result, monolayer and multilayer LB films of polyimide are appeared on irreversible process caused by the oxidation current from the cyclic voltammogram.

A Study on the Interface Properties of Metal/Organic Films/Metal (Metal/Organic Films/Metal에서 계면특성에 관한 연구)

  • Song, Jin-Won;Cho, Su-Young;Choi, Young-Il;Lee, Kyung-Sup
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.07b
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    • pp.723-726
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    • 2002
  • We give pressure stimulation into organic thin films and then manufacture a device under the accumulation condition that the state surface pressure is 10[mN/m]. In processing of a device manufacture, we can see the process is good from the change of a surface pressure for organic thin films and transfer ratio of area per molecule. The structure of manufactured device is Au/Poly-$\gamma$ Benzyl $_D$-Glutamate/Al; the number of accumulated layers is 1, 3, 5 and 7. Also, we then examined of the MIM device by means of I-V. The I-V characteristic of the device is measured from 0 to +2[V]. We determined electrochemical measurement by using cyclic voltammetry with a three-electrode system. LB film accumulated by monolayer on an ITO. In the cyclicvoltammetry, An Ag/AgCl reference electrode, a platinum wire counter electrode and LB film-coated ITO working electrode measured in $LiBF_4$ solution, stable up to 0.9V vs. Ag/AgCl.

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Electrochemical Properties and Photoisomerization of DOPC-8A5H Mixture Langmuir-Blogett Films (인지질(DOPC)과 지방산(8A5H)의 혼합 LB막의 광이성질화 현상과 전기화학적 특성)

  • Park, Keun-Ho;Choi, Sung-Hyun;Kim, Nam-Seok;Kim, Duck-Sool
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.07b
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    • pp.874-877
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    • 2004
  • We carried out this subject to observe electrochemical properties of 1,2-dioleoyl-sn- glycero-3-phosphocholine(DOPC) mixed with fatty acid containing azobenzene group by using cyclic voltammetry with a three-electrode system, An Ag/AgCl reference electrode, a platinum wire counter electrode and LB film-coated ITO working electrode in $NaClO_4$ solution. We investigated the photoisomerization and electrochemical property of the organic ultra thin film of fatty acid containing azobenzene was prepared on the hydrophilic ITO(idium tin oxide) glass plate by LB method. As a result, the absorption spectra of BASH and DOPC of mixture LB films was induced to photoisomerization by alternating irradiation of ultraviolet and visible light. A measuring range was reduced from initial potential to -1350mV, continuously oxidized to 1650 mV and measured to the initial point. The scan rate were 50, 100, 150 and 200 mV/s. As a results, LB films of BASH-DMPC appeared reversible process caused by the reduction-oxidation current from the cyclic voltammogram.

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Electrochemical Properties of Langmuir-Blodgett(LB) Monolayer Films of Alkyl Bromides Mixture (브롬화 알킬혼합물 단분자 LB막의 전기화학적 특징)

  • Son, Tae-Chul;Kim, Duck-Sool;Park, Keun-Ho
    • Journal of the Korean Applied Science and Technology
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    • v.27 no.2
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    • pp.202-207
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    • 2010
  • We investigated the electrochemical properties for Langmuir-Blodgett(LB) films mixed with l-bromotetradecane(Cl4), l-bromohexadecane(Cl6), and l-bromooctadecane(Cl8). The alkyl bromides mixture was deposited by using the Langmuir-Blodgett method on the ITO glass. The electrochemical properties measured by using cyclic voltammetry with a three-electrode system(an Ag/AgCl reference electrode, a platinum wire counter electrode and LB film-coated ITO working electrode) at various concentrations(0.5, 1.0, 1.5 and 2.0 N) of $NaClO_4$ solution. A measuring range was reduced from initial potential to -1350 m V, continuously oxidized to 1650 mV. The scan rate was 100 mV/s. As a result, LB films of Cl4, Cl6, and Cl8 mixture monolayers appeared irreversible process caused by only the oxidation current from the cyclic voltammogram. The diffusivity(D) effect of LB films decreased with increasing of alkyl bromides amount.

A Study on the Oxidation-reduction Reaction of Organic Thin Films (유기초박막의 산화-환원 반응에 관한 연구)

  • Park Keun-Ho;Song Ju-Yeong
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.19 no.8
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    • pp.724-731
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    • 2006
  • We investigated the electrochemical properties for Langmuir-Blodgett (LB) films mixed with 4-octyl-4'-(5-carboxylpentamethyleneoxy)azobenzene (denoted as 8A5H) and phospholipid(L-a-dimyristoylphosphatidylcholine, denoted as DMPC and L-a-dilauroylphosphayidylcholine, denoted as DLPC). The LB films of 8A5H, 8A5H-DMPC and 8A5H-DLPC mixture monolayers were deposited by using the LB method on the indium tin oxide(ITO) glass. The electrochemical properties measured by using cyclic voltammetry with a three-electrode system, an Ag/AgCl reference electrode, a platinum wire counter electrode and LB film-coated ITO working electrode at various concentrations(0.1, 0.5, and 1.0 mol/L) of $NaClO_4$ solution. A measuring range was reduced from initial potential to -1350 mV, continuously oxidized to 1650 mV and measured to the initial point. The scan rates were 50, 100, 150 and 200 mV/s, respectively. As a result, LB films of 8A5H and 8A5H-DLPC mixture monolayers appeared irreversible process caused by only the oxidation current from the cyclic voltammogram and LB films of 8A5H-DMPC monolayer mixture was found to be caused by a reversible oxidation-reduction process.

A Study on the Electronic Properties of LB Thin Films (LB박막의 전자이동 특성에 관한 연구)

  • Song, Jin-Won;Choi, Young-Il;Lee, Kyung-Sup
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.08a
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    • pp.101-104
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    • 2002
  • Abstract We give pressure stimulation into organic thin films and then manufacture a device under the accumulation condition that the state surface pressure is 10[mN/m]. In processing of a device manufacture, we can see the process is good from the change of a surface pressure for organic thin films and transfer ratio of area per molecule. The structure of manufactured device is Au/Poly-${\gamma}$ Benzyl $_D$-Glutamate/Al; the number of accumulated layers is 1, 3, 5 and 7. Also, we then examined of the MIM device by means of I-V. The I-V characteristic of the device is measured from 0 to +2[V]. We determined electrochemical measurement by using cyclic voltammetry with a three-electrode system. LB film accumulated by monolayer on an ITO. In the cyclicvoltammetry, An Ag/AgCl reference electrode, a platinum wire counter electrode and LB film-coated ITO working electrode measured in $LiBF_4$ solution, stable up to 0.9V vs. Ag/AgCl.

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Dynamic behavior of GMA considering metal transfer (금속이행을 고려한 GMA 용접 시스템의 동특성 해석)

  • 박세홍;김면희;강세령;최상균;이상룡
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2002.05a
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    • pp.565-568
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    • 2002
  • Welding variables and conditions in gas metal arc welding (GMAW) effect on the weld quality and productivity, extensive research efforts have been made to analyze the welding variables and conditions. In this study dynamic behavior of GMAW system is investigated using the characteristic equations of the power supply, wire and welding arc. Characteristic equation of wire is modified to include the effect of droplets attached at the electrode tip. The dynamic characteristics of arc length, current, voltage with respect to the step, ramp inputs of CTWD was simulated, seam tracking procedure using arc sensor was simulated with variable V-Groove geometries and weaving frequencies. From results of simulation, some predictions about dynamic characteristics of GMAW and welding process are available. The proposed simulator and results appear to be utilized to determine the proper welding conditions, to be improved by considering power supply dynamic characteristics.

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Development of a Dipstick Gage Type Small Engine oil Deterioration Detection Sensor (딥스틱게이지형 소형 엔진열화감지센서 개발)

  • Chun, Sang Myung
    • Tribology and Lubricants
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    • v.29 no.2
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    • pp.77-84
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    • 2013
  • A small engine-oil-deterioration detection sensor was developed and installed at the tip of a dipstick gage. The sensor part was manufactured using printed circuit board (PCB) manufacturing technology. A set of sensor covers was installed in order to protect the sensor and realize good signal stability. The small engine-oil-deterioration detection sensor system comprised a dual sensor having etched copper electrodes coated with gold and ceramic, a flexible PCB (FPCB) acting as electric wire, and a dummy PCB with only a lock connector. The sensor can easily be installed by insertion through the guide tube of a dipstick gage. Thus, a driver can easily handle it without further installation equipment. The sensor can determine the level of deterioration in the engine oil by estimating the corresponding dielectric constant of the engine oil.

A Study on Dynamic Characteristics of Welding Current and Arc Length At GMAW (GMA용접에서 용접전류와 아크 길이의 동특성에 관한 연구)

  • Lee, Tae-Young
    • Journal of the Korean Society of Industry Convergence
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    • v.14 no.1
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    • pp.15-21
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    • 2011
  • Welding variables and conditions in gas metal arc welding (GMAW) effect on the quality and productivity of the weld, extensive research efforts have been made to analyze the effect of the welding variables and conditions. In this study dynamic behavior of GMAW system is investigated using the characteristics of the power supply, wire and welding arc. Characteristic equation of wire is modified to include the effect of droplets attached at the electrode tip. The dynamic characteristics of arc length, current, voltage with respect to the step, ramp inputs of CTWD was simulated. From results of simulation, some predictions about dynamic characteristics of GMAW and welding process are available. The proposed simulator and results appear to be utilized to determine the proper welding conditions, to be improved by considering power supply dynamic characteristics.

Non-cracking YBCO Films on Silver Wire

  • Soh, Dea-Wha;Korobova, N.;Li, Young-Mae
    • Journal of the Speleological Society of Korea
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    • no.76
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    • pp.1-13
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    • 2006
  • Electrophoretic deposition (EPD) of alcohol YBCO suspensions on the Ag wire electrode is studied. Poly(ethylene glycol) was coordinated to a structure formed by the EPD process with YBCO particles. The suspension is characterized in terms of zeta potential and conductivity. The d.c electric fields of 200-300 V/cm are applied for 1-10 min. The optimal condition for the EPD allows modifying the properties and microstructure of the deposited films. Superconducting coatings with nanometer-sized pores and a preferred orientation along the c-axis were prepared from the result with chemically modified precursor solution. In contrast, YBCO coatings of submicrometer-sized pores and randomly orientated grains were prepared from the solution without PEG.