• Title/Summary/Keyword: wide light absorption

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Structural and optical properties of $TiO_2$ thin film fabricated by reactive sputtering (반응성 스퍼터링법에 의한 $TiO_2$ 박막의 구조적 및 광학적 특성)

  • Jeong, Woon-Jo;Yang, Hyeon-Hun;Park, Gye-Choon
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.06a
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    • pp.393-394
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    • 2008
  • $TiO_2$ is a wide band-gap semiconductor (3.4 eV) and can only absorb about 5% of sun light in the ultraviolet light region, which largely limits its practical applications because of the lower utility of sun light and quantum yield. In order to move the absorption edge of $TiO_2$ films to visible spectrum range, we have made the impurity level within a band-gap of $TiO_2$ thin film by introduction of oxygen vacancy. Oxygen-defected $TiO_2$ thin film have prepared by reactive sputtering with the partial pressure of Ar:$O_2$=10:90~99.33:0.66 ratio. As a result, we could have the impurity level of about 2.75 eV on condition that oxygen partial pressure is below 7%.

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Structural and optical properties of $TiO_2$ thin film fabricated by reactive sputtering (반응성 스퍼터링법으로 제조된 $TiO_2$ 박막의 구조적 및 광학적 특성)

  • Jeong, Woon-Jo;Yang, Sung-Eun;Yang, Hyeon-Hun;Kim, Young-Jun;Park, Gye-Choon
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.06a
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    • pp.398-399
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    • 2006
  • $TiO_2$ is a wide band-gap semiconductor (3.4 eV) and can only absorb about 5% of sun light. in the ultraviolet light region, which largely limits its practical applications because of the lower utility of sun light and quantum yield. In order to move the absorption edge of $TiO_2$ films to visible spectrum range, we have made the impurity level within a band-gap of $TiO_2$ thin film by introduction of oxygen vacancy. Oxygen-defected $TiO_2$ thin film have prepared by reactive sputtering with the partial pressure of Ar:$O_2$=10:90~99.33:0.66 ratio. As a result, we could have the impurity level of about 2.75 eV on condition that oxygen partial pressure is below 7%.

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Analysis of Wide-gap Semiconductors with Superconducting XAFS Apparatus

  • Shiki, S.;Zen, N.;Matsubayashi, N.;Koike, M.;Ukibe, M.;Kitajima, Y.;Nagamachi, S.;Ohkubo, M.
    • Progress in Superconductivity
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    • v.14 no.2
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    • pp.99-101
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    • 2012
  • Fluorescent yield X-ray absorption fine structure (XAFS) spectroscopy is useful for analyzing local structure of specific elements in matrices. We developed an XAFS apparatus with a 100-pixel superconducting tunnel junction (STJ) detector array with a high sensitivity and a high resolution for light-element dopants in wide-gap semiconductors. An STJ detector has a pixel size of $100{\mu}m$ square, and an asymmetric layer structure of Nb(300 nm)-Al(70 nm)/AlOx/Al(70 nm)-Nb(50 nm). The 100-pixel STJ array has an effective area of $1mm^2$. The XAFS apparatus with the STJ array detector was installed in BL-11A of High Energy Accelerator Research Organization, Photon Factory (KEK PF). Fluorescent X-ray spectrum for boron nitride showed that the average energy resolution of the 100-pixels is 12 eV in full width half maximum for the N-K line, and The C-K and N-K lines are separated without peak tail overlap. We analyzed the N dopant atoms implanted into 4H-SiC substrates at a dose of 300 ppm in a 200 nm-thick surface layer. From a comparison between measured X-ray Absorption Near Edge Structure (XANES) spectra and ab initio FEFF calculations, it has been revealed that the N atoms substitute for the C site of the SiC lattice.

Development of Concurrent Multi Path (CMP)-Differential Optical Absorption Spectroscopy (DOAS) for Remote Sensing of Surface Atmospheric Gases (지표면 대기중 가스상오염물질 다경로 동시 원격 모니터링을 위한 CMP-DOAS 개발: 첫 개발 사례 및 이산화질소 측정 연구)

  • Lee, Han-Lim;Hwang, Jung-Bae;Kim, Jhoon;Noh, Young-Min;Won, Yong-Kwan
    • Journal of Korean Society for Atmospheric Environment
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    • v.26 no.4
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    • pp.412-419
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    • 2010
  • Concurrent Multi Path-Differential Optical Absorption Spectroscopy (CMP-DOAS) is a novel active optical system to measure simultaneously ambient trace gases (such as $NO_2$, $SO_2$, $O_3$, and HCHO) present on several light paths. The CMP-DOAS system consists of a 2D CCD camera, spectrometer, receiving telescopes, and artificial light sources. The system receives spectra, which have been transported through several paths. It also covers wavelength ranges of which trace gases of interest share at the same time. This study presents the instrumental setup of a CMP-DOAS in detail. A field campaign for a comparative measurement was carried out at an urban site in Gwangju for a month on January 2009. $NO_2$ mixing ratios measured by the CMP-DOAS system and in-situ $NO_2$ analyzers were in good agreement by 83%. It demonstrates the high capacities of the CMP-DOAS technique to cover atmospheric trace gases dispersed across wide light paths.

A Wireless Optical Identification System Using Solar Cells (솔라 셀을 이용한 무선광 인식 장치)

  • Lee, Seong-Ho
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.21 no.5
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    • pp.494-500
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    • 2010
  • In this paper, we newly propose a wireless optical identification system and carried out experiments. A wireless optical identification system consists of a reader and a transponder. The configuration of a reader is the same as that of a transponder, which uses LED light as transmission media and detects the signal light with a solar cell. Optical alignment with a lens is not required because the absorption area of a solar cell is wide and flat, and it is very easy to attach a solar cell on the surface of an object. As the light wavelength does not interfere with radio frequency, a wireless optical identification system shows stable operation. In experiments, we realized a wireless optical identification system that automatically identifies the transponder data at a distance of 1 m using solar cells.

Fabrication of Transient Absorption Spectroscopic System and Measurement of Transient Absorption Changes of DDI (순간흡수 분광학 측정장치 구성 및 DDI의 순간흡수율 변화 측정)

  • Seo, Jung-Chul;Lee, Min-Yung;Kim, Dong-Ho;Jeong, Hong-Sik;Park, Seung-Han;Kim, Ung
    • Korean Journal of Optics and Photonics
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    • v.2 no.4
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    • pp.209-213
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    • 1991
  • Recently, the developments in generating and amplifying ultrashort optical pulses $(ps=10^{-12}s or fs=10^{-15}s)$ have imposed on great advances in the time-resolved laser spectroscopy. Especially, the transient absorption spectroscopy has a wide application range and the main idea of this technique is pump & probe method. After the pump pulse makes the material an excited or a transient states, the probe pulse is sent through the material to measure the absorbance change due to the transient states. Here, if the absorbance change was measured by the time delay between pump & probe pulses, the dynamic information of the excited or the transient states (the transient abnsorption changes by time & wavelength) can be obtained. At our laboratory, the ultrashort optic1 pulse (

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Disk-averaged Spectra Simulation of Earth-like Exoplanets with Ray-tracing Method

  • Ryu, Dong-Ok;Kim, Sug-Whan
    • The Bulletin of The Korean Astronomical Society
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    • v.37 no.1
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    • pp.76.2-76.2
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    • 2012
  • The understanding spectral characterization of possible earth-like extra solar planets has generated wide interested in astronomy and space science. The technical central issue in observation of exoplanet is deconvolution of the temporally and disk-averaged spectra of the exoplanets. The earth model based on atmospheric radiative transfer method has been studied in recent years for solutions of characterization of earthlike exoplanet. In this study, we report on the current progress of the new method of 3D earth model as a habitable exoplanet. The computational model has 3 components 1) the sun model, 2) an integrated earth BRDF (Bi-directional Reflectance Distribution Function) model (Atmosphere, Land and Ocean) and 3) instrument model combined in ray tracing computation. The ray characteristics such as radiative power and direction are altered as they experience reflection, refraction, transmission, absorption and scattering from encountering with each all of optical surfaces. The Land BRDF characteristics are defined by the semi-empirical "parametric-kernel-method" from POLDER missions from CNES. The ocean BRDF is defined for sea-ice cap structure and for the sea water optical model, considering sun-glint scattering. The input cloud-free atmosphere model consists of 1 layers with vertical profiles of absorption and aerosol scattering combined Rayleigh scattering and its input characteristics using the NEWS product in NASA data and spectral SMARTS from NREL and 6SV from Vermote E. The trial simulation runs result in phase dependent disk-averaged spectra and light-curves of a virtual exoplanet using 3D earth model.

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Extraction of Material Parameters and Design of Schottky Diode UV Detectors Using a Transfer Matrix Method (전달 행렬 방법을 이용한 Schottky 다이오드 자외선 광검출기의 물질특성 추출과 설계)

  • Kim Jin-Hyung;Kim Sang-Bae
    • Journal of the Institute of Electronics Engineers of Korea SD
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    • v.43 no.5 s.347
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    • pp.25-33
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    • 2006
  • We have extracted the material parameters such as absorption coefficients of GaN, $Al_{0.2}Ga_{0.8}N$, and Schottky contact metal Ni of Schottky Diode UV-A and B detectors using a transfer matrix method (TMM). The ratios of the absorbed light to the total incident amount at the depletion regions of GaN and $Al_{0.2}Ga_{0.8}N$ have been calculated in order to obtain the spectral responsivity. Absorption coefficients of the materials have been obtained by fitting the simulated data with measured data. The depletion layer thickness has been obtanied by capacitance-voltage measurement. The results pave the way for the optimum design of UV Schottky detectors. Since the absorption coefficient of the Ni electrode is very high, its thickness is a major factor that determines the responsivity. It is possible to attain improved UV detectors using thinnest possible Ni electrodes and wide depletion regions of GaN and $Al_{0.2}Ga_{0.8}N$.

Agricultural Application of Ground Remote Sensing (지상 원격탐사의 농업적 활용)

  • Hong, Soon-Dal;Kim, Jai-Joung
    • Korean Journal of Soil Science and Fertilizer
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    • v.36 no.2
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    • pp.92-103
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    • 2003
  • Research and technological advances in the field of remote sensing have greatly enhanced the ability to detect and quantify physical and biological stresses that affect the productivity of agricultural crops. Reflectance in specific visible and near-infrared regions of the electromagnetic spectrum have proved useful in detection of nutrient deficiencies. Especially crop canopy sensors as a ground remote sensing measure the amount of light reflected from nearby surfaces such as leaf tissue or soil and is in contrast to aircraft or satellite platforms that generate photographs or various types of digital images. Multi-spectral vegetation indices derived from crop canopy reflectance in relatively wide wave band can be used to monitor the growth response of plants in relation to environmental factors. The normalized difference vegetation index (NDVI), where NDVI = (NIR-Red)/(NIR+Red), was originally proposed as a means of estimating green biomass. The basis of this relationship is the strong absorption (low reflectance) of red light by chlorophyll and low absorption (high reflectance and transmittance) in the near infrared (NIR) by green leaves. Thereafter many researchers have proposed the other indices for assessing crop vegetation due to confounding soil background effects in the measurement. The green normalized difference vegetation index (GNDVI), where the green band is substituted for the red band in the NDVI equation, was proved to be more useful for assessing canopy variation in green crop biomass related to nitrogen fertility in soils. Consequently ground remote sensing as a non destructive real-time assessment of nitrogen status in plant was thought to be useful tool for site specific crop nitrogen management providing both spatial and temporal information.

Synthesis of Ag-doped black ZnO nano-catalysts for the utilization of visible-light (가시광선 활용을 위한 Ag 도핑 흑색 ZnO 나노 광촉매 합성)

  • Ui-Jun Kim;Hye-Min Kim;Seung-Hyo Lee
    • Journal of the Korean institute of surface engineering
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    • v.56 no.3
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    • pp.208-218
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    • 2023
  • Photocatalysts are advanced materials which accelerate the photoreaction by providing ordinary reactions with other pathways. The catalysts have various advantages, such as low-cost, low operating temperature and pressure, and long-term use. They are applied to environmental and energy field, including the air and water purification, water splitting for hydrogen production, sterilization and self-cleaning surfaces. However, commercial photocatalysts only absorb ultraviolet light between 100 and 400 nm of wavelength which comprises only 5% in sunlight due to the wide band gap. In addition, rapid recombination of electron-hole pairs reduces the photocatalytic performance. Recently, studies on blackening photocatalysts by laser, thermal, and plasma treatments have been conducted to enhance the absorption of visible light and photocatalytic activity. The disordered structures could yield mid-gap states and vacancies could cause charge carrier trapping. Herein, liquid phase plasma (LPP) is adopted to synthesize Ag-doped black ZnO for the utilization of visible-light. The physical and chemical characteristics of the synthesized photocatalysts are analyzed by SEM/EDS, XRD, XPS and the optical properties of them are investigated using UV/Vis DRS and PL analyses. Lastly, the photocatalytic activity was evaluated using methylene blue as a pollutant.