• 한국전기전자재료학회논문지
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• 제23권12호
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• pp.983-987
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• 2010

In order to investigate the emission characteristics of the phosphorescent white organic light-emitting diodes (PHWOLEDs) according to various hole transport layers (HTLs), PHWOLEDs composed of HTLs whose structure are NPB/TCTA, NPB/mCP and NPB/TCTA/mCP, two emissive layers (EMLs) which emit two-wavelengths of light (blue and red), and electron transport layer were fabricated. The applied voltage, power efficiency, and external quantum efficiency at a current density of $1 mA/cm^2$ for the fabricated PHWOLEDs were 7.5 V, 11.5 lm/W, and 15%, in case of NPB/mCP, 5 V, 14.8 lm/W, and 13.7%, in case of NPB/TCTA, and 5.5 V, 14.6 lm/W, and 15%, in case of NPB/TCTA/mCP in the hole transport layer, respectively. High emission efficiency can be obtained when the amount of hole injection from anode is balanced out by the amount of electron injection from the cathode to EML by using NPB/TCTA/mCP structured HTL.

• Transactions on Electrical and Electronic Materials
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• 제14권1호
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• pp.24-27
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• 2013

In this paper, we investigated the effect of luminescence properties of various concentrations of magnesium-doped ZnS:Mn phosphor excited by plasma luminescence device. The PL intensity was evaluated in the range of 300~500 nm excitation wavelengths. We found the highest PL intensity of the phosphors excited by 365 nm and 450 nm was observed at Mg concentrations of 1.4 wt% and 0.8 wt%, respectively. In addition, an emission peak was distinguished at 580 nm wavelength. With increasing Mg dopant level, enhanced PL intensity was observed, which is possibly applicable to color converting materials by blue emission for white light sources. Finally, we evaluated the luminance properties of color converting ZnS:Mn,Mg phosphors with plasma blue light source. the white luminance of plasma light source with CIE(0.36,0.26) was established by color converting phosphors of ZnS:Mn with 0.8 wt% Mg.

• 한국세라믹학회지
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• 제49권1호
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• pp.105-110
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• 2012

In this paper, a yellow phosphor $Sr_3SiO_5:Eu^{2+}$ that emits efficiently at the 450 nm excitation for warm white LED is studied. In addition, the effects of various flux $BaF_2$, $NH_4Cl$ on the emission spectra were investigated. The samples were synthesized through conventional solid state reaction under reducing atmosphere of 95% $N_2$-5% $H_2$ mixture at the high temperature. All phosphors showed a excitation band from 450 nm and broad band emission peaking at region of 580 nm. The optimal concentration of $BaF_2$ flux is 3 wt% for $Sr_3SiO_5$ with doping 0.05mol Eu phosphors fired in a reductive atmosphere. The phosphor showed highest emission peaking at 582 nm.

• 한국전기전자재료학회논문지
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• 제22권2호
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• pp.163-168
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• 2009

Hyperbranched conjugated polymers (p-HPPV and m-HPPV) with para and meta linkages were synthesized from $A_2$ and $B_4$ type monomers through Wittig polycondensation. The synthesized p-HPPV and m-HPPV were completely soluble in common organic solvents such as chloroform, tetrahydrofuran, 1,2-dichloroethane, etc. and thermal gravimetric analyses showed that p-HPPV and m-HPPV are stable up to $350^{\circ}C$. The molecular weights (from GPC), UV-visible, and photoluminescence maximum peaks of p-HPPV and m-HPPV are characterized in detail. The fabricated EL devices using the synthesized hyperbranched polymers, (ITO/(p-HPPV or m-HPPV)/Al), showed EL emission at about 507 nm and 481 nm (681 nm), respectively. Especially, EL device from m-HPPV were found to exhibit nearly white emission with approximate CIE coordinates of (0.31, 0.34) compared with (0.310, 0.316) of NTSC white color at $100\;cd/m^2$. The good photophysical properties combine with good film-form ability could make these hyperbranched polymers to be a potential candidate for the EL materials.

• 한국정보디스플레이학회:학술대회논문집
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• 한국정보디스플레이학회 2004년도 Asia Display / IMID 04
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• pp.676-678
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• 2004

In order to develop new yellow phosphor that emit efficiently under the 450 - 470 nm excitation range, we have synthesized a $Eu^{2+}$-activated $Sr_3SiO_5$ yellow phosphor and investigated an attempt to develop white LEDs by combining it with a InGaN blue LED chip (460 nm). Two distinct emission bands from the InGaN-based LED and the $Sr_3SiO_5$:Eu phosphor are clearly observed at 460 nm and at 570 nm, respectively. These two emission bands combine to give a spectrum that appears white to the naked eye. Our results showed that InGaN (460 nm chip)-based $Sr_3SiO_5$:Eu exhibits a better luminous efficiency than that of the industrially available product InGaN (460 nm chip)-based YAG:Ce.

• 한국정보디스플레이학회:학술대회논문집
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• 한국정보디스플레이학회 2008년도 International Meeting on Information Display
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• pp.1350-1352
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• 2008

Research on down conversion phosphor materials is the key for the development of solid state lighting (SSL). Especially finding alternative red phosphor for white LEDs based on blue or NUV LEDs are important research task. Under this view, we have synthesized a series of $Eu^{3+}$ substituted $La_2W_{2-x}Mo_xO_9$ (x = 0 ~ 2, insteps of 0.1) red phosphor and characterized by X-ray diffraction (XRD) and photoluminescence. XRD results reveal a phase transition from triclinic to cubic structure for $x\;{\geq}\;0$. All the compositions show broad charge transfer band due to charge transfer from oxygen to tungsten/molybdenum and red emission due to $Eu^{3+}$ ions. Select compositions show high red emission intensity compared to the commercial red phosphor under NUV/blue ray excitation. Hence, this candidate can be possible red emitting phosphors for white LEDs.

• 한국정보디스플레이학회:학술대회논문집
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• 한국정보디스플레이학회 2006년도 6th International Meeting on Information Display
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• pp.1002-1005
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• 2006

In this study, we fabricated white organic light emitting devices (WOLEDs) to use single emission layer, DPVBi with partially doped Rubrene. To realize white color, rubrene with 3.6% was partially doped with the gap from interface between DPVBi and hole transport layer NPD in a definite DPVBi layer. As the gap was increased, the intensity of orange peak grows less and less. The WOLED with gap of $5\;{\AA}$ has the best color stability and its color coordination is (0.345, 0.321) at 6V.

• Bulletin of the Korean Chemical Society
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• 제23권10호
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• pp.1435-1454
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• 2002

Bright yellow ${(Y_{1-x}Gd_x)}_{3-z}{(Al_{1-y}Ga_y)}_5O_{12}:Ce_z$ phosphors were synthesized. White LED was obtained by the combination of non-absorbed blue emission from a blue L ED itself and yellow emission from ${(Y_{1-x}Gd_x)}_{3-z}{(Al_{1-y}Ga_y)}_5O_{12}:Ce_z$ phosphors. The crystal structures and optical properties of ${(Y_{1-x}Gd_x)}_{3-z}{(Al_{1-y}Ga_y)}_5O_{12}:Ce_z$ phosphors were investigated.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2013년도 제45회 하계 정기학술대회 초록집
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• pp.286.1-286.1
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• 2013

Nowadays, the glare towards the light-emitting diode (LED) lighting source has much attention due to its eco-friendly nature, reduced energy consumption, and low CO2 emission. LEDs can show versatile colors by changing the composition ratio of semiconductors. Phosphors re-emit light by absorbing light from LED, which is the key factor for emission. The endeavor to make replica of natural white light is increasing day by day. Industrially, blue LED chip crowned with a yellow phosphor coated lens gives low quality white light. Newly, many researchers are introducing modern approaches, adding red phosphor to the yellow phosphor to increase the quality of white light. Here, we synthesized structurally and chemically stable europium doped oxyapatite Ca8Gd2(PO4)6O2 nano-crystalline structures by a hydrothermal method. The ultrafine structures were formed due to the effect of ethylenediaminetetraacetic acid, which is confirmed by the transmission electron microscope images. The structural properties were analyzed using the X-ray diffraction patterns.

• 반도체디스플레이기술학회지
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• 제5권3호
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• pp.1-4
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• 2006

White-light-emitting ZnS:Mn, Cu, Cl phosphors with spherical shape and the size of $20\;{\mu}m$ are successfully synthesized. They have the double phases of cubic and hexagonal structures. They are applied to electroluminescent (EL) devices by silk screen method with the following structure: $electrode/BaTiO_3$ insulator layer ($50{\sim}60\;{\mu}m$)/ ZnS:Mn, Cu, Cl phosphor layer ($30{\sim}50\;{\mu}m$)/ITO glass. The EL devices are driven with the voltage of 100 V and the frequency of 400 Hz. The EL devices show the three emission peaks. The blue and green emission bands are originated from $CICu^{2+}$ transition and $ClCu^+$ transition, respectively. The yellow emission band results from $^4T^6A$ transition of $Mn^{2+}$ ion. As an increase of Cu concentrations, the blue and green emission intensities decrease whereas the yellow emission intensity increases; the quality becomes warm white. It is due to the energy transfer from the blue and green bands to the yellow band.