• Title/Summary/Keyword: wetting resistance

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Characteristics of Ceramic Separator Impregnated by Molten Salt for Thermal Batteries (열전지용 세라믹 분리막의 용융염 전해질 함침 특성)

  • Kang, Seung-Ho;Im, Chae-Nam;Park, Byung-Jun;Cho, Sung-Baek;Cheong, Hae-Won;Yi, Junsin
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.28 no.7
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    • pp.467-472
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    • 2015
  • Thermal batteries are primary power sources for military applications requiring high reliability, robustness and long storage life. Conventional electrodes for thermal batteries are prepared by compacting powder mixtures into pellets. Separator is composed of halide mixture, such as LiCl-KCl eutectic salt, blended with MgO to immobilize the molten salt. In order to increase the power density and energy density, the resistance of electrolyte should be reduced because the resistance of electrolyte is predominant in thermal batteries. In this study, wetting behaviors and impregnation weight of molten salts as well as the micro structures of ceramic felt were investigated to be applicable to thin electrolyte. Discharge performances of single cell with the ceramic separator impregnated by molten salt were evaluated also. Zirconia felt with high porosity and large pore outperformed alumina felt in wetting characteristics and molten salt impregnation as well as discharge performances. Based on the results of this study, ceramic felt separator impregnated with molten salt have revealed as an alternative of conventional thick MgO based separator with no conspicuous sign of thermal runaway by short circuit.

Evaluation of Material Properties of Acetylated Medium Density Fiberboard (MDF) (아세틸화 처리 중밀도 섬유판(MDF)의 재질 평가)

  • LEE, Jong Shin;KIM, Soung Joon
    • Journal of the Korean Wood Science and Technology
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    • v.48 no.3
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    • pp.393-404
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    • 2020
  • This study examined the material properties of MDF manufactured using acetylated pinus radiata fibers against moisture and compared the properties with the fiberboard quality standards of KS F 3200. Since acetylated MDF shows very low moisture content, water absorption and thickness swelling than the quality standards, it is expected to have an excellent dimensional stability. The bending strength in wetting condition of the acetylated MDF reached approximately 70% of the bending strength in dry condition, making it suitable for the quality standards. The internal bond of the acetylated MDF in the wetting condition was higher than the minimum internal bond of the quality standards in the dry condition, showing a good water resistance. Since the water droplet contact angle of the acetylated MDF is larger than that of untreated MDF, it is determined that it contributes in improving the water resistance due to the low wettability.

An Experimental Study on the Salt Resistance Properties with Concrete Materials under Marine Environment (Exposure period : 5 years) (해양환경에 폭로한 콘크리트의 내염특성에 대한 실험적 연구 (폭로기간 : 5년))

  • Kim, Yong-Chul;Suk, Jun-Yeoll;Shin, Do-Chul
    • Proceedings of the Korea Concrete Institute Conference
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    • 2006.05b
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    • pp.169-172
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    • 2006
  • The IIA structures exposed to marine environment is subject to many different types of potential attack. The physical attack due to drying and wetting would increase the internal stress of concrete. The chemical attack resulting from the diffusion of ions$(Cl^-,SO_4^{2-},Mg^+)$ from seawater through the pores in concrete. Therefore the sea water resistance of concrete must be considered when it is used for structure in the ocean. The objective of this study is to evaluate chloride diffusion and corrosion characteristics of concrete when using the various concrete materials under marine environment. After 5 years of exposure, concrete incorporating 40% blast-furnace slag as replacement for type I cement with low w/c ratio of 0.42 and using the inhibitor shows excellent performance.

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Mechanical Properties & Ablation Mechanism of SiC Coated Carbon/Carbon Composite by Pack-cementation Method

  • Kim, J.I.;Oh, I.S.;Joo, H.J.
    • Carbon letters
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    • v.2 no.1
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    • pp.27-36
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    • 2001
  • The pack-cementation process is the method which is formed SiC coating layer to improve weak oxidation properties of CFRCs (carbon fiber-reinforced carbons). This method develops the anti-oxidation coating layer having no dimensional changes and good wetting properties. In this study to improve the oxidative resistance of the prepared 4D CFRCs, the surface of CFRCs is coated by SiC using pack cementation method. The mechanical properties of SiC-coated 4D CFRCs are measured by the 3-point bending test, and their ablation properties are investigated by the arc torch plasma test. From the results, it is found that both mechanical and ablation properties of SiC-coated 4D CFRCs are much better than bare CFRCs.

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2-Packaged Polyurethane Coatings(II);Preparation and Physical Properties of Polyurethane Coatings (2액형 폴리우레탄 도료에 관한 연구(II);폴리우레탄 도료의 제조와 도막물성)

  • Kim, Seon-Kil;Chung, Kyeng-Teak;Park, Hong-Soo
    • Journal of the Korean Applied Science and Technology
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    • v.12 no.1
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    • pp.19-27
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    • 1995
  • The 2-packaged polyurethane coatings were synthesized, blending pheylmodified polyesters(of which synthetic methods were reported in the previous paper), Desmodur L-75(polyisocyanate wide1y used for coatings), wetting-dispersing agent, white pigment. etc. A variety of coating properties were tested for the coating treatment polyurethane coationgs. Compared with conventional 2-packaged polyure-thane coating, abrasion resistance and lightness index difference of the ones synthesized in the present work were somewhat decreased, but the coating properties such as hardness, gloss specular, cross hatch adhesion. etc. were improved. Especially, resistance against chemical reagents and salt were strikingly improved. In addition. the coationgs had short drying time and long pot-life. This shows that the coationgs are appropriate for rapid drying coatings.

Influence of Electrolyte on the Shape and Characteristics of TiO2 during Anodic Oxidation of Titanium (Titanium 양극산화시 TiO2 의 형상 및 특성에 미치는 전해질의 영향)

  • Yeji Choi;Chanyoung Jeong
    • Corrosion Science and Technology
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    • v.22 no.3
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    • pp.193-200
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    • 2023
  • Titanium alloy (grade-4) is commonly used in industrial and medical applications. To improve its corrosion resistance and biocompatibility for medical use, it is necessary to form a titanium oxide film. In this study, the morphology of the oxide film formed by anodizing Ti-grade 4 using different electrolytes was analyzed. Wetting properties before and after surface modification with SAM coating were also observed. Electrolytes used were categorized as A, B, and C. Electrolyte A consisted of 0.3 M oxalic acid and ethylene glycol. Electrolyte B consisted of 0.1 M NH4F and 0.1 M H2O in ethylene glycol. Electrolyte C consisted of 0.07 M NH4F and 1 M H2O in ethylene glycol. Samples B and C exhibited a porous structure, while sample A formed a thickest oxide film with a droplet-like structure. AFM analysis and contact angle measurements showed that sample A with the highest roughness exhibited the best hydrophilicity. After surface modification with SAM coating, it displayed superior hydrophobicity. Despite having the thickest oxide film, sample A showed the lowest insulation resistance due to its irregular structure. On the other hand, sample C with a thick and regular porous oxide film demonstrated the highest insulation resistance.

Comparison of removal torque of dual-acid etched and single-acid etched implants in rabbit tibias (단일, 이중 산처리 임플란트의 회전제거력 비교)

  • Kim, Jong-Jin;Cho, Sung-Am
    • The Journal of Korean Academy of Prosthodontics
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    • v.57 no.4
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    • pp.335-341
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    • 2019
  • Purpose: Chemically strong-acids (HF and $HCl/H_2SO_4$) dual etching implant surfaces have higher strengths of osseointegration than machined implant surfaces. However, the dual acid treatment deteriorates the physical properties of the titanium by weakening the fatigue resistance of the implant and causing microcracks. The removal torque comparison between the dual-acid etched (hydrochloric acid, sulfuric acid, HS) and single-acid etched implants (hydrochloric acid, H) could reveal the efficiency of implant surface acid treatment. Materials and methods: Nine $3.75{\times}4mm$ dual-acid etched SLA implants and nine single-acid etched SLA implants were inserted into New Zealand rabbit tibias. After 10 days, removal torque, roughness, and wetting angle were measured. Results: Mean removal torque values were as follows: Mean removal torque were 9.94 Ncm for HS group and 9.96 Ncm for H group (P=.995). Mean surface roughness value were $0.93{\mu}m$ for HS group and $0.84{\mu}m$ for H group (P=.170). Root mean square roughness (RSq) values were $1.21{\mu}m$ for HS group and $1.08{\mu}m$ for H group (P=.294), and mean wetting angle values were $99^{\circ}$ for HS group and $98^{\circ}$ for H group (P=.829). Statistical analysis showed no significant difference between the removal torques, roughness, or wetting angles of the two groups. Conclusion: In this experiment, we found no significant difference in removal torque, roughness, or wetting angle between dual-acid etched and single-acid etched implants.

Development of the High-quality Coating System for the Steam Pipe of Ship (선박 스팀파이프용의 고내구성 도장 사양 개발 연구)

  • Lee, Sung-Kyun;Baek, Kwang-Ki;Hwang, Dong-Un;Song, Eun-Ha
    • Special Issue of the Society of Naval Architects of Korea
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    • 2006.09a
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    • pp.46-52
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    • 2006
  • For ships, heat resistant coating is applied on the aluminized steel pipe systems dealing with high temperature steam over $200^{\circ}C$. The coatings on these steam pipes should retain both heat resistance and anti-corrosion properties to provide long-term resistance against coating defects (rust, delamination and crack) under the harsh outdoor environment including repeated seawater wetting and condensation. Thus, it is important to improve the coating qualities and to reduce maintenance works for these steam pipe systems. In this study, five different commercial heat resistant coatings (A, B, C, D, E) were selected for evaluation. Various physical properties of these coatings were evaluated on the coatings applied on the aluminized steam pipes. FT-IR analysis was also employed to identify the factors contributing the degree of heat resistance and durability of each coating material. The results indicated that the heat resistance capacity of coatings increased with the increase of silicon content as well as the decrease of substituent content. Both products C and D showed the best coating qualifies, which can be standard coating systems for future steam pipe areas.

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Preparation and Curing Behavior of Polyurethane Coatings by Polyester/Lactone Polyol and HDI-biuret (폴리에스테르/락톤 폴리올과 HDI-Biuret에 의한 폴리우레탄 도료의 제조 및 경화거동)

  • 최용호;김대원;황규현;박홍수;김태옥
    • Polymer(Korea)
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    • v.24 no.1
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    • pp.72-81
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    • 2000
  • Benzoic acid polyester/lactone polyol were synthesized by polycaprolactone 0201 as diol, trimethylolpropane as triol, adipic acid as dibasic acid, and benzoic acid as monobasic acid. Polyisocyanate prepolymer Desmodur N-100 of HDI-biuret type was used in this study. Two-component polyurethane coatings were prepared by blending benzoic acid polyester/polycaprolactone, polyisocyanate, wetting/dispersing agent, white pigment, and flowing agent. Various properties were examined on the film coated with the prepared polyurethane. They showed excellent physical properties such as abrasion resistance, accelerated weathering resistance, and yellowness index. They also showed good physical properties such as flexibility, impact resistance, 60$^{\circ}$ specular gloss, cross hatch adhesion, hydrocarbon resistance, and lightness index difference. Hardness of coating showed a little poor character. The introduction of polycaprolactone 0201 as diol in the polyurethane coatings improved the hydrocarbon resistance, impact resistance, and flexibility of coatings. According to the drying and curing behavior with the contents of benzoic acid, they seem to have reasonable coating properties such as drying time of 2 to 4 hours and pot-life time of 20 to 37 hours.

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Analysis on the Rainfall Triggered Slope Failure with a Variation of Soil Layer Thickness: Flume Tests (강우로 인한 조립토 사면에서의 토층 두께 변화에 따른 사면의 활동 분석: 실내 모형실험)

  • SaGong, Myung;Yoo, Jea-Ho;Lee, Sung-Jin
    • Journal of the Korean Geotechnical Society
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    • v.25 no.4
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    • pp.91-103
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    • 2009
  • Slope failure depends upon the climatic features related to related rainfall, structural geology and geomorphological features as well as the variation of the mechanical behaviors of soil constituting a slope. In this paper, among many variables, effects of soil layer thickness on the slope failure process, and variations of matric suction and volumetric water content were observed. When the soil layer is relatively thick, the descending wetting front decreases matric suction and the observed matric suction reaches to "0" value. When the wetting front reaches to the impermeable boundary, the bottom surface of steel soil box, ascending wetting front was observed. This observation can be postulated to be the effects of various sizes of pores. When macro size pores exist, the capillary effects can be reduced and infilling of pore will be limited. The partially filled pores would be filled with water during the ascending of the wetting front, which bounces from the impermeable boundary. This assumption has been assured from the observation of variation of the volumetric water contents at different depth. When the soil layer is thick (thickness = 20 cm), for granular material, erosion is a cause triggering the slope failure. It has been found that the initiation of erosion occurs when the top soil is fully saturated. Meanwhile, when the soil layer is shallow (thickness = 10 cm), slope slides as en mass. The slope failure for this condition occurs when the wetting front reaches to the interface between the soil layer and steel soil box. As the wetting front approaches to the bottom of soil layer, reduction of shear resistance along the boundary and increase of the unit weight due to the infiltration occur and these produce complex effects on the slope failure processes.