• Title/Summary/Keyword: wetting effect

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Scouring Effect of PAPE(Polyoxyethylene Alkyl Phosphoric Ester) on Cotton Fibres (면섬유에 대한 폴리옥시에틸렌 알킬 인산에스테르의 정련효과)

  • Ha, Youn-Shick;Kwak, Gyeong-Do;Chang, Yoon-Ho
    • Applied Chemistry for Engineering
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    • v.10 no.7
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    • pp.974-978
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    • 1999
  • This study was concerned with the scouring effect of anionic surfactants, PAPE(sodium polyoxyethylene alkyl phosphoric ester) for cotton fibres. Sodium polyoxyethylene(7) nonylphenyl phosphoric ester(CPB-1) and the sodium polyoxyethylene(7) tridecyl phosphoric ester(CPB-2) were synthesized by the phosphoric esterification reaction from NP-7(polyoxyethylene(7) nonylphenyl ether) and TDA-7(polyoxyethylene(7) tridecyl ether) as scouring agents. Defoaming ability, fibre wetting time and absorbency rate of scouring agents were investigated. Being compared with the conventional scouring agent(Ultravon GP; Ciba-guyge Co.), CPB-1 and CPB-2 showed a higher defoaming ability in the cotton scouring process at room temperature. And CPB-1 has a higher wetting effect than the agents, CPB-2 or GP in distilled water bath but CPB-2 showed more scouring effect in 1.2 wt % NaOH solution bath.

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A Study on Wetting Behaviors of Al-Coated $SiC_f$ Composite (Al-$SiC_f$ 복합재료에서 보강재의 coating처리가 젖음성에 미치는 영향)

  • Kim, Kyun-Young;Lee, Kyung-Ku;Choi, Dap-Chun;Lee, Doh-Jae
    • Journal of Korea Foundry Society
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    • v.14 no.3
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    • pp.274-284
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    • 1994
  • SiC fibers were coated with Cu, Ag and Ni metallic thin films by magnetron sputtering in order to improve wetting properties between Al matrix and SiC fiber. The wetting behavior of metal coated SiC fiber by pure Al has been studied at $670^{\circ}C{\sim}900^{\circ}C$ range for $10{\sim}90min$. under vacuum atmosphere. Besides, the effect of coated film thickness on the wettability has been investigated. The wetting behavior and interfacial reaction between Al and SiC fibers were analysed with optical microscope and SEM (scanning electron microscope). The wetting behavior of the as-received SiC fiber with Al melt was not uniform, indicated by the contact angles from less than $90^{\circ} to more Al melt was appeared in the initial stage of reation. It was considered that the metallic thin film played an important role in reducing the interfacial free energy and breaking down the aluminum oxide film by eutectic reaction with Al melt. However the wettability of Ni coated SiC fiber was not improved as much as that of Cu or Ag coated SiC fiber. The improvement of wettability by coating thickness is clearly showed in $1{\mu}m$ coated SiC fiber compared with $0.25{\mu}m$ coated SiC.

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A Molecular Simulation on the Adhesion Control of Metal Thin Film-Carbon Nanotube Interface based on Thermal Wetting (Thermal wetting 현상이 탄소나노튜브-금속박막 계면의 응착력에 미치는 영향에 관한 분자 시뮬레이션 연구)

  • Sang-Hoon Lee;Hyun-Joon Kim
    • Tribology and Lubricants
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    • v.39 no.1
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    • pp.8-12
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    • 2023
  • This study presents a molecular simulation of adhesion control between carbon nanotube (CNT) and Ag thin film deposited on silicon substrate. Rough and flat Ag thin film models were prepared to investigate the effect of surface roughness on adhesion force. Heat treatment was applied to the models to modify the adhesion characteristics of the Ag/CNT interface based on thermal wetting. Simulation results showed that the heat treatment altered the Ag thin film morphology by thermal wetting, causing an increase in contact area of Ag/CNT interface and the adhesion force for both the flat and rough models changed. Despite the increase in contact area, the adhesion force of flat Ag/CNT interface decreased after the heat treatment because of plastic deformation of the Ag thin film. The result suggests that internal stress of the CNT induced by the substrate deformation contributes in reduction of adhesion. Contrarily, heat treatment to the rough model increases adhesion force because of the expanded contact area. The contact area is speculated to be more influential to the adhesion force rather than the internal stress of the CNT on the rough Ag thin film, because the CNT on the rough model contains internal stress regardless of the heat treatment. Therefore, as demonstrated by simulation results, the heat treatment can prevent delamination or wear of CNT coating on a rough metallic substrate by thermal wetting phenomena.

Long-term Compression Settlement of Granular (Rock/Soil Mixture) Fill Materials under Concrete Track (콘크리트궤도 하부 조립지반재료의 장기압축침하에 관한 연구)

  • Lee, Sung-Jin;Lee, Il-Wha;Lee, Jin-Wook;Lee, Jun-S.
    • Journal of the Korean Geotechnical Society
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    • v.25 no.8
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    • pp.95-106
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    • 2009
  • This study was intended to identify the effect of the wetting on a long-term compression settlement of the rock/soil mixture used as fill material, depending on compaction and grading conditions. The relatively large settlement happened under the fully-submerged condition, and a repeated settlement was monitored when moisture content increased over and over again like the rainfall infiltration. In case of the materials without fine fractions or compacted in wet condition, the settlement caused by wetting was relatively low. In conclusion, the long-term compression settlement of granular (rock/soil mixture) fill material is more affected by the increase of water content and temperature change (freezing and thawing) than creep.

Self-Healing Properties of Fiber-Reinforced Cement Composite (FRCC) Depending on Various Curing Conditions (양생조건에 따른 섬유보강 시멘트계 복합재료(FRCC)의 균열 자기치유 특성)

  • Choi, Heesup;Choi, Hyeonggil
    • Journal of the Korea Institute of Building Construction
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    • v.16 no.4
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    • pp.289-296
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    • 2016
  • In this study, the self-healing effect of a fiber-reinforced cement composite (FRCC) was examined using a drying-wetting test and an outdoor exposure test. The influence of various curing conditions on the self-healing effect of the FRCC was also investigated. The effect of self-healing was evaluated using a permeability coefficient and by investigating the cracks using a optical microscope. The results confirmed that the FRCC was capable of self-healing under a long wetting time and a low drying temperature. In addition, watertight performance by self-healing was shown to have a significant influence on wetting time. Meanwhile, this self-healing effect was enhanced by hydration as a result of rainfall when the FRCC was put under actual environmental conditions. Moreover, it was determined that cracking self-healing can be improved by using the appropriate admixture materials.

Effect of Slurry Property on Preparation of Zirconia Film in Electrophoretic Deposition (전착법에서 용액특성이 지르코니아 막형성에 미치는 영향)

  • 김상우;이병호;손용배;송휴섭
    • Journal of the Korean Ceramic Society
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    • v.36 no.9
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    • pp.991-996
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    • 1999
  • Effect of solution property on the weight varation and microstructural change of film was studied by electrophoretic deposition in order to obtain a homogeneous and dense zirconia film. As a result of weight kinetics of film which obtained in alcohol or aqueous solution having different polarity experimental data showed large deviation from theoretical ones calculated by Zhang's kinetic model. It had been shown that the weight affecting factors was largely dependent on properties other than dielectric constant and viscosity of solvent zeta potential appiled field and time. In initial stage a main factor of the drastic weight increase was the capillary drag of porous substrate. The cause of weight decrease with time in aqueous solution after 300 s was attributed to the defect of film by sagging and electrolytic reaction. The electrolyte film which prepared in alcohol solution with good wetting for substrate had better homogeneous and dense microstructure than one in aqueous solution with high surface tension.

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Analysis of Unsaturated Flow Considering Hysteresis in Porous Media under Antecedent Rainfall (선행강우가 존재하는 다공성 매질에서 이력현상을 고려한 비포화 흐름 해석)

  • Park, Chang Kun;Sonu, Jung Ho
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.14 no.5
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    • pp.1137-1143
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    • 1994
  • Through the numerical analysis of the capillary pressure-based Richards equation with and without the effect of the capillary hysteresis under the boundary condition having an antecedent rainfall. the moving tendency of the wetting front, the redistribution of the moisture content, infiltration rate, cumulative infiltration etc, were computed. The effect of the capillary hysteresis cannot be neglected in analyzing an unsaturated flow, and the more accurate results may be obtained by the consideration of the hysteresis effect. If the effect of the hysteresis cannot be considered, the analysis by the use of the main wetting curve may give more reliable result than that of the main drying curve.

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Synthesis of Fluorinated Polymer Gate Dielectric with Improved Wetting Property and Its Application to Organic Field-Effect Transistors

  • Kim, Jae-Wook;Jung, Hee-Tae;Ha, Sun-Young;Yi, Mi-Hye;Park, Jae-Eun;Kim, Hyo-Joong;Choi, Young-Ill;Pyo, Seung-Moon
    • Macromolecular Research
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    • v.17 no.9
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    • pp.646-650
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    • 2009
  • We report the fabrication of pentacene organic field-effect transistors (OFETs) using a fluorinated styrene-alt-maleic anhydride copolymer gate dielectric, which was prepared from styrene derivatives with a fluorinated side chain [$-CH_2-O-(CH_2)_2-(CF_2)_5CF_3$] and maleic anhydride through a solution polymerization technique. The fluorinated side chain was used to impart hydrophobicity to the surface of the gate dielectric and maleic anhydride was employed to improve its wetting properties. A field-effect mobility of 0.12 cm$^2$/Vs was obtained from the as-prepared top-contact pentacene FETs. Since various functional groups can be introduced into the copolymer due to the nature of maleic anhydride, its physical properties can be manipulated easily. Using this type of copolymer, the performance of organic FETs can be enhanced through optimization of the interfacial properties between the gate dielectric and organic semiconductor.

Effects of Port Fuel Injection Characteristics upon HC Emission in SI Engines (연료 분사 특성이 가솔린 엔진 HC 배출특성에 미치는 영향)

  • Woo, Young-Min;Bae, Choong-Sik;Lee, Yong-Pyo
    • Proceedings of the KSME Conference
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    • 2001.06d
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    • pp.796-801
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    • 2001
  • During cold operation period, fuel injection system directly contributes the unburned hydrocarbon formation in spark ignition engines. The relationship between injection parameters and HC emission behavior was investigated through a series of experiments. Spray behavior of port fuel injectors was characterized through a quantitative evaluation of mass concentration of liquid fuel by a patternator and PDA. 6-hole injector was found to produce finer spray than single hole one. Using a purpose-built test rig, the wall wetting fuel was measured, which was mostly affected by wall temperature. Varying coolant temperature($20{\sim}80^{\circ}C$), HC emissions were measured in a production engine. With respect to the different types of injectors, HC emission was also measured. In the 6-hole injector application, the engine produced less HC emission in low coolant temperature region. Though it produces much more amount of wetting fuel, it has the advantages of finer atomization quality. In high coolant temperature region, there was little effect between different types of injectors. The control schemes to reduce HC emissions during cold start could be suggested from the findings that the amount of fuel supply and HC emission could be reduced by utilizing fine spray and high intake wall temperature.

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