• Journal of Environmental Health Sciences
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• v.22 no.2
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• pp.83-89
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• 1996

In order to evaluate the air quality, dry and wet deposition samples were collected by deposit containers during four months in Inchon area. The samples were analyzed for its solid composition and trace elements(Ca, Cd, Cu, Fe, Mn, Ni, Pb, Zn). The main results are summarized below 1. The amounts of dry and wet deposition in Inchon area were 1.06~3.14 ton/$km^2$/month, and affected by the rainfall and suspended yellow sand. 2. Through the analysis of solid balance, we found that 50% of total solids(TS) was fixed suspend ed solids(FSS), 25% was fixed dissolved solids(FDS), and each of volatile suspended solids(VSS) and volatile dissolved solids(VDS) accounted for 12.5%. 3. The amounts collected by sampler for trace elements were 938 ~ 2,765 $\mu g$ calcium/10days sampler, 0.2 ~ 90.4 $\mu g$ cadmium/10days/sampler, 26 ~ 298 $\mu g$ copper/10days/sampler, 928 ~ 3,939 $\mu g$ iron/10days/sampler, 50 ~ 202 $\mu g$ manganese/10days/sampler, 4 ~ 37 $\mu g$ nickel/10days/sampler, 52 ~ 406 $\mu g$ lead/10days/sampler, and 97 ~ 1,317 $\mu g$ zinc/10days/sampler, respectively. 4. Using the manganese analysis, it was found that 76.1% of TS was from soil.

• Journal of Korean Society for Atmospheric Environment
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• v.20 no.4
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• pp.483-491
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• 2004

The purpose of this study is to develop an ozone passive sampler and to evaluate its performance p-Acetamidophenol using as the reagent for ozone reacts specifically with the ambient ozone to produce a fluorescence material (p-acetamidopheonl dimer). The volume of absorbent solution and the extraction time determined at suitable conditions for measuring ozone were 100$\mu$L and 60 min, respectively. The changes of fluorescence were observed with incresing the storage period of passive samplers in ambient air. but the cool storage in a refrigerator did not remarkably influence the increase of fluorescence. The measurement for the precision oi the passive sampling was carried out with duplicate measurement of passive samplers. The intra-class correlation coefficients of passive samplers using dry and wet filters were 0.992 and 0.962, respectively The results from field validation tests indicated practical agreement (dry filter: r=0.963, wet filter: r=0.995) between the passive sampler and an UV photometric $O_3$ analyzer. The limit of quantification of ozone passive samplers with sampling time of 8 hr (wet filter) and 24 hr (dry filter) were 8.0 ppb and 2.7 ppb, respectively.

• Journal of Korean Society for Atmospheric Environment
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• v.20 no.3
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• pp.381-396
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• 2004

In order to understand the precipitation acidity and chemical composition of ion species in Iksan area as well as to know the difference of chemical characteristics in precipitation samples from the viewpoint of precipitation sampling method, precipitation samples were collected by wet-only automatic precipitation sampler and bulk manual precipitation sampler in Iksan, from March 2003 to August 2003. The mean pH of precipitation was 5.0. There was a little significant difference in the mean value of pH between automatic and manual sampler. However, pH values of some precipitation samples were lower in automatic sampler than in manual sampler, especially in case of precipitation samples with small rainfall for March 2003. The mean concentrations of each ions in precipitation were generally a little higher in precipitation samples collected by the manual sampler than in those collected by the automatic sampler because of accumulation of dry deposition on the surface of glass funnel installed at the manual sampler during the sampling period or no rainfall. Dominant species determining the acidity of precipitation, were N $H_4$$^{[-10]}$ and nss-C $a^{2+}$ for cations and nss-S $O_4$$^{2-}$ and N $O_3$$^{[-10]}$ for anions. The mean concentration of N $H_4$$^{+}$ and nss-C $a^{2+}$ were 31 $\mu$eq/L and 9 $\mu$eq/L for the automatic sampler and 40 ueq/L and 16 ueq/L for the manual sampler, respectively. In addition, nss-S $O_4$$^{2-}$ and N $O_3$$^{[-10]}$ were 27 $\mu$eq/L and 13 $\mu$eq/L for the automatic sampler and 32 $\mu$eq/L and 17 $\mu$eq/L for the manual sampler, respectively. Although the concentrations of the acidifying ions of nss-S $O_4$$^{2-}$ and N $O_3$$^{[-10]}$ were about 3 times higher than those for foreign pristine sites, precipitation acidity were estimated to be natural due to the neutralization reaction of the alkaline species of N $H_4$$^{+}$ and nss-C $a^{2+}$ with its higher concentrations. Considering the ratios of nss-S $O_4$$^{2-}$/N $O_4$$^{[-10]}$ nss-S $O_4$$^{2-}$, it was found that ammonium sulphate was dominant in Iksan precipitation. The major non-sea salt ions were maximum concentrations for March, but decreased with increasing of precipitation amount.on amount.

• Analytical Science and Technology
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• v.24 no.6
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• pp.429-434
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• 2011

In this study, a wet-sampler was developed for collection in water and simultaneous fractionation of micron-sized particles (e.g., pigment, airborne, etc.). In this new device, three cylinders (partially filled with water) through which air was forced to pass for sample collection are connected in a series. Particles of different sizes are collected in different cylinders, allowing simultaneous fractionation. An uniqueness of this new device is that it does not use any membrane filter. Microparticles are collected directly in cylinders filled partially with water. Also the particles are simultaneously fractionated within this device while they are being collected. The new device was employed for collection of airborne particles. The collected airborne particles were fractionated by using sedimentation field-flow fractionation, SdFFF), and observed with an optical microscopy (OM) for size and shape analysis. Also AAS and ICP-AES were used for composition analysis of the airborne particles. It is expected that the new device is applicable to collection and analysis of size distribution of various types of microparticles.

• Journal of Korean Society for Atmospheric Environment
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• v.14 no.6
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• pp.589-598
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• 1998

This study was conducted to investigate the chemical characteristics of Precipitation at Seoul, Yangpyong, Hongchon and Inje in the central part of Korean peninsula during the period from March 1994 to November 1997. The precipitation samples were collected by automatic wet-only sampler. The samples were analyzed for major anions (SO42-, NO3-, Cl-, F-) and cations(NH4+, Ca2+, Mg+, Na+, K+), in addition to acidity and electrical conductivity. The analytical instrument for water soluble ionic components was ion chromatography. The volume - weighted mean PH were 4.73, 4.87, 4.89 and 4.81 at Seoul, Yangpyong, Hongchon and Inje, respectively. The sums of cation concentrations was slightly greater than the sums of anion concentrations. Also, the highest ion component was SO42- in anions and NH4+ in cations. The mean equivalent ratios of SO42- to NO3- were found by 2.96, 2.71, 2.43 and 2.25 at Seoul, Yangpyong, Hongchon and Inje, respectively. The factor analysis was conducted in order to make the large and diverse data set as manageable levels and to qualitatively examine the relationship between the variables. It showed that major sources of pollutants in precipitation were from the anthropogenic in Seoul, the natural in Hongchon, and the anthropogenic and natural in Yangpyong and Inje.

• Journal of Korean Society of Occupational and Environmental Hygiene
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• v.25 no.2
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• pp.166-173
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• 2015

Objectives: The purpose of this study was to evaluate cobalt concentrations in airborne inhalable, total and respirable dust from manufacturing industries using cobalt. Methods: To compare cobalt concentrations, three types of dust samplers(a 37mm closed cassette sampler, Institute of Occupational Medicine(IOM) sampler, and Aluminum cyclone sampler) were used. The analysis of cobalt concentrations was conducted using AAs based on the NIOSH 7300 method. Results: The geometric mean of cobalt concentration in total dust was $1.47{\mu}g/m^3$, and the rate of excess of the Korean Occupational Exposure Limit(KOEL) was 10.0%. The geometric mean concentrations of cobalt in super alloy manufacturing industries were higher than those in plating industries, and molding operations showed higher exposure levels to cobalt than did other operations. Conclusions: The rate of cobalt concentration in inhalable dust from super alloy manufacturing industries exceeding the Workplace Exposure Limit(WEL) as recommended by the Health & Safety Executive(HSE) was 7.1%, which means proper work environmental management is required through wet work environments. Given that molding operations had higher cobalt concentrations, it is necessary to apply measures such as local exhaust for reducing airborne dust in cobalt manufacture industries.

• Journal of Korean Society for Atmospheric Environment
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• v.21 no.1
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• pp.39-48
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• 2005

Nitrogen and sulfur deposition was measured on Lake Pal dang from March 2002 to October 2003. Wet and dry depositions were separately measured using wet- and dry-only samplers, respectively. In order to measure the dry deposition to the water body, a dry deposition sampler composed of three pans filled with pure water, called the deposition water, was used. Since ammonium was generally in excess in ambient air, more than half of ammonium was present in the gaseous form. Ammonium concentration was also generally higher than the sum of major anion concentrations in the deposition water because gaseous species were much easily deposited than the species in fine particles. Nevertheless, the contribution of gaseous ammonia to the deposition of ammonium was not high as well as that of particulate ammonium while the contribution of gaseous nitric acid was much higher than that of particulate nitrate. Annual wet deposition fluxes of nitrogen and sulfur were five and six times higher than their dry deposition fluxes, respectively. Except for ammonium, the dry deposition flux estimated in the present work was a half of the previous results. This was mainly caused by much smaller dry deposition velocities over the water than over the ground.

• Analytical Science and Technology
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• v.29 no.5
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• pp.242-247
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• 2016

This research aims to set up and validate methods of analyzing the methanol in wet wipes and verifies the analysis methods that applied to the wet wipes. We used Headspace (HS) Gas Chromatography (GC) - Flame Ionization Detector (FID) to the establish analysis method of methanol in wet wipes and optimized heating temperature, heating time, GC conditions with column. The result indicated that 3 mL of sample in 20 mL headspace vial can be equilibrated efficiently in headspace sampler at 70 ℃ for 10 min and sample was measured by GC with spli injection mode(10:1). The results show that linearity from 1 to 100 ppm was over R2 0.9995, precision was RSD 1.83 % and accuracy(recovery rate) was 105.44 (±1.05 %) on water matrix and wet wipes matrix removed non-woven fabric. Also, monitoring results of total 20 cosmetics on the market, from 0.00017 to 0.00156 % of methanol was detected from wet wipes.

• Korean Journal of Environmental Agriculture
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• v.18 no.2
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• pp.116-121
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• 1999

Tree leaves have been used as the passive sampler to measure lipophilic PAHs in the atmosphere. This is a convenient and economical method in case of sampling at many regions including the remote places that are not supplied with electric power. But poor results can be obtained if samples are collected carelessly or PAHs concentrations are calculated on the basis of wrong natures of tree leaves. This study was performed to avoid the errors of interpretation that can be induced by these problems when tree leaves are used as a passive sampler of PAHs. Conclusions have been reached as follows: 1) The correlativity was low among the water content, the lipid content, the dry weight and the area of four kinds of tree leaves. According to this, PAHs concentrations calculated per wet weight, dry weight, lipid content and area of tree leaves differed. Therefore, same unit shoud be used to describe concentrations of the pollutants when PAHs concentrations deposited on leaves from atmosphere in the different regions are compared. It is better to decribe the unit as PAHs concentrations per dry weight of leaves for comparison with other data because almost researcher make use of this unit, and the range of fluctuation of the dry weights in several natures of tree leaves was relatively little during growing seasons. 2) Although four kinds of trees(Pinus Koraiensis, Ginkgo biloba, Evodia daniellii, Kalopanax pictus) had been grown at the same place, PAHs concentrtions deposited on leaves differed respectively. Therefore PAHs concentrations deposited on different kinds of tree leaves should not be compared. It is better to make use of pine needles as the sample because pine trees grow almost over the world, and it is able to collect their samples in winter.

• Journal of Korean Society for Atmospheric Environment
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• v.19 no.6
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• pp.647-661
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• 2003

For continuous monitoring of atmospheric visibility in the city of Kwanaju, Korea, a transmissometer system consisting of a transmitter and a receiver was installed at a distance of 1.91 km across the downtown Kwanaju. At the transmitter site an integrating nephelometer and an aethalometer were also installed to measure the scattering and absorption coefficients of the atmosphere, respectively. At the receiver site. an URG PM$_{2.5}$ cyclone sampler and an URG-VAPS (Versatile Air Pollutant Sampler) with three filter packs and two denuders were used to collect both PM$_{2.5}$ and PM$_{10}$ samples at a 2-hour or 12-hour sampling interval for aerosol chemical analysis. Sulfate, organic mass by carbon (OMC), nitrate, elemental carbon (EC) components of fine aerosol were the major contributors to visibility impairment. Diurnal variation of visibility during best-case days showed rapid improvement in the morning hours, while it was delayed until afternoon during the worst-case days. Aerosol mass concentration of each aerosol component for the worst-case was calculated to be 11.2 times larger than the best-case for (NH$_4$)$_2$SO$_4$(NHSO), 19.0 times for NH$_4$NO$_3$ (NHNO), 2.2 times for OMC, respectively. Also result shows that elemental carbon and fine soil (FS) were 3.7 and 2.2 times more than those of best-case. respectively- Sum of total contributions of wet NHSO and NHNO to light extinction was calculated to be 301 Mm$^{-1}$ for the worst-case. However, sum of contributions by dry NHSO and NHNO was calculated to be 123 Mm$^{-1}$ for the best case. Mass extinction efficiencies of fine and coarse particles were calculated to be 5.8$\pm$0.3 $m^2$/g and 1.8$\pm$0.1 $m^2$/g, respectively.ely.