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X-Ray Diffraction Studies of Uranyl Hydrolysis Precipitates Synthesized in Neutral to Alkaline Aqueous Solutions

  • 박용준;표형렬;김원호;전관식
    • Bulletin of the Korean Chemical Society
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    • v.17 no.10
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    • pp.925-929
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    • 1996
  • Uranyl hydrolysis precipitates were obtained by increasing pH value of aqueous uranyl solution in the range of neutral to alkaline pH value and their phase transformation during the solubility experiment under various conditions has been examined. The precipitates formed in the hydrolysis reaction of uranyl ion had a layered structure such as a meta-schoepite phase, a schoepite structure, or a mixed phase of meta-schoepite and schoepite. Phase transformation between them was strongly dependent on the pH value at which the precipitate was formed. The distance between the layers in meta-schoepite or schoepite phase was ∼7.35 Å, and it was increased with the pH value at which the precipitate was synthesized as well as the pH values of the aqueous solution. The phase transformation from a meta-schoepite to schoepite was fast for the precipitates formed at low pH values, however, it was not the case for the precipitates formed at high pH values. A small difference of pH value in aqueous solution gave a great change on its solubilities near pH 9.7, because a layered structure of the precipitates became amorphous above that pH value. Greater solubility for the precipitate formed at higher pH value can be explained from the fact that the precipitates formed at low pH value had a better crystallinity and also that the precipitates formed at higher pH value has a slower rate of crystallization.

Simulation-based P-well design for improvement of ESD protection performance of P-type embedded SCR device

  • Seo, Yong-Jin
    • Journal of IKEEE
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    • v.26 no.2
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    • pp.196-204
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    • 2022
  • Electrostatic discharge (ESD) protection devices of P-type embedded silicon-controlled rectifier (PESCR) structure were analyzed for high-voltage operating input/output (I/O) applications. Conventional PESCR standard device exhibits typical SCR characteristics with very low-snapback holding voltages, resulting in latch-up problems during normal operation. However, the modified device with the counter pocket source (CPS) surrounding N+ source region and partially formed P-well (PPW) structures proposed in this study could improve latch-up immunity by indicating high on-resistance and snapback holding voltage.

A STUDY ON THE ACTUAL CONDITIONS OF CHILDREN′S REHABILITATION CENTERS IN SEOUL (서울지구 소아재활원 실태조사)

  • 김계숙
    • Journal of Korean Academy of Nursing
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    • v.4 no.1
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    • pp.64-80
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    • 1974
  • The social understanding of the rehabilitation and welfare work for the handicapped children is nearly devoid in Korea. Especially the medical rehabilitation or nursing for them is left ign. ored as well as the literature preferential to this study is wanted. For the purpose of conducting the study of this thesis Sam Yook Children's Rehabilitation Center, Inc. and Crippled Children's Center, Yonsei University Medical center sampled out; covering three months from Aug. 1 to Oct. 30, 1973, the problems of children's rehabilitation, the characteristics of the children, the medical rehabilitation, nursing, education, and vocational rehabilitation were interviewed and widely grasped. This thesis aimed at developing the rehabilitation, the professional nursing and especially aimed at contributing to the improvement of welfare for the handicapped by analysing, observing the result of this study. The result is as follows: 1. Sam Yook Children's Rehabilitation Center, Inc. has, since its establishment, contributed to the advancement of the crippled children and its purpose consists in implementing services, medical rehabilitation, nursing, education and vocational training. Crippled Children's Center, Yonsei University Medical Center is, being based on Christianity, aiming at the medical treatment and education for the crippled children. 2. All of the children admitted in the children's rehabilitation centers are the crippled children. The ratio of boys io girls is three to two. Boys are more than girls. Orphan formed 55.2 per sent of them. About 60 per cent of them is receiving medical attention free of charge. But there is no orphan in Crippled Children's Center, Yonsei University Medical Center. 3. 15.7 per cent of them have received the previous medical attention before their admitting in the centers; in Sam Yook Children's Rehabilitation Center 8.6 percent, Crippled Children's Center, Yonsei University Medical Center 50 percent; there is remarkable difference between the two. 4. On the standpoint of period of being in the centers, the children who have been over three years in Sam Yook Children's Rehabilitation Center formed 48.7 per cent; in Crippled Children's Center, Yonsei University Medical Center 2.6 percent; there is also considerable difference between the two; they couldn't discharge from the centers owing to the economic conditions and being orphan. 5. Among the diagnosis of the crippled children, poliomyelitis formed highest 51.7 percent of them ; cerebral palsy formed 30 percent secondly in order. Environmental factors (67.8 percent formed about three times of congenital factors (23.7 percent). 6. The children who are capable of doing independently activity of daily living formed 87.9 percent; 73.2 percent can walk about 300 m by wearing brace and so on. The ratio of wearing brace or leg prosthesis formed 47.4 per cent: crutch 44.3 per cent. The medical rehabilitation service and education for the crippled, are comparatively well carried out. But it is desired to improve and cultivate the vocational training, vocational guidance and special nursing to the insufficiency of their implementation. In the tendency that the rehabilitation and welfare for the handicapped are today emphasized, International Handicapped Rehabilitation Association, declaring that 1970s are the decade of rehabilitation, urged to improve positively the policy of rehabilitation and welfare for the handicapped. But here in korea the handicapped, being the object of social prejudice, ignorance, disdain lives in obscurity. Therefore the government or the community should draw up countermeasure on social under-standing, financial support, and rehabilitation services for the handicapped as well as should endeavor to make them participate in social activities as the productive total- person though they are physically imperfect.

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The Synthesis of Kaolinitic Clay Minerals from Domestic Diatomite by Hydrothermal Process (국내산 규조토의 수열반응에 의한 Kaolinite질 인공점토의 합성에 관한 연구)

  • 김남일;박계혁;정창주
    • Journal of the Korean Ceramic Society
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    • v.31 no.11
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    • pp.1401-1413
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    • 1994
  • The synthesis of kaolinite mineral from domestic diatomite for silica resource, commercial vailable gibbsite or alumina for alumina resource were made under various hydrothermal treatment, and the sythetic effect of acidic mineralizers, temperature treatment with time duration, particle size of alumina on formation of kaolinite mineral and the plastic properties of synthesized kaolinite were investigated. The various acidic mineralizers which are HCl, HNO3, H2SO4 and Oxalic acid were employed for hydrothermal reaction in the range of 0.01 mol/ι to 2 mol/ι concentration of each mineralizers. It was found that HCl in the level of 1 mol/ι solution produced highly yields of well-crystallized and platy form kaolinite mineral and gave the most effective extraction of iron oxide, compared to that of others, that HNO3 produced highly yield of kaolinite but lower extraction of iron oxide, that H2SO4 produced low yield of kaolinite and formed alunite mineral, and that oxialic acid formed spherical crystalline kaolinite and gave low extraction of iron oxide. Moreover, it showed that kaolinite minerals were well synthesized in a wide range of less than 2 mol/ι acids, but were poorly synthesized at more than 2 mol/ι acids. However, boehmite and kaolinite were coexistently formed in the temperature range of 18$0^{\circ}C$ and 20$0^{\circ}C$ when the calcined diatomite and gibbsite were involved. The well-ordered kaolinite mineral as a platy form was highly synthesized in the temperature range of 220 and 24$0^{\circ}C$, when the same marterials as above were used with treatment of 1 mol/ι HCl solution. The results also revealed that the size of crystalline platy form kaolinite, synthesized from alumina and calcined diatomite with treatment in 1 mol/ιHCl solution at 24$0^{\circ}C$, was much larger than that of gibbsite and calcined diatomite shown previously, and that kaolinite and corundum minerals were coexistently formed under any hydrothermal treatment conditions. The plasticity of synthesized kaolinite from under 2 ${\mu}{\textrm}{m}$ alumina and calcined diatomite was very poor, and that of the synthesized kaolinite from raw diatomite and gibbsite gave higher than that of calcined diatomite and gibbsite.

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A High-Resolution Transmission Electron Microscopy Study on the Lattice Defects Formed in the High Energy P Ion Implanted Silicon (고에너지 P이온 주입한 실리콘에 형성된 격자 결함에 관한 고분해능 투과전자현미경 연구)

  • 장기완;이정용;조남훈;노재상
    • Journal of the Korean Ceramic Society
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    • v.32 no.12
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    • pp.1377-1382
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    • 1995
  • A high-resolution transmission electron microscopy study on the lattice defects formed in the high energy P ion implanted silicon was carried out on an atomic level. Results show that Lomer dislocations, 60$^{\circ}$perfect dislocations, 60$^{\circ}$ dislocation dipole and extrinsic stacking fault formed in the near Rp of as-implanted specimen. In the annelaed specimens, interstitial Frank loops, 60$^{\circ}$perfect disolations, 60$^{\circ}$dislocation dipoles, stacking faults, precipitates, perfect dislocation loops and <112> rodlike defects existed exclusively near in the Rp with various annealing temperature and time. From these results, it is concluded that extended secondary defects as well as the point defect clusters could be formed without annealing. Even at low temperature annealing such as 55$0^{\circ}C$, small interstitial Frank loops could be formed and precipitates were also formed by $700^{\circ}C$ annealing. The defect band annealed at 100$0^{\circ}C$ for 1 hr could be divided into two regions depending on the distribution of the secondary defects.

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Column design of cold-formed stainless steel slender circular hollow sections

  • Young, Ben;Ellobody, Ehab
    • Steel and Composite Structures
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    • v.6 no.4
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    • pp.285-302
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    • 2006
  • This paper describes the design and behaviour of cold-formed stainless steel slender circular hollow section columns. The columns were compressed between fixed ends at different column lengths. The investigation focused on large diameter-to-plate thickness (D/t) ratio ranged from 100 to 200. An accurate finite element model has been developed. The initial local and overall geometric imperfections have been included in the finite element model. The material nonlinearity of the cold-formed stainless steel sections was incorporated in the model. The column strengths, load-shortening curves as well as failure modes were predicted using the finite element model. The nonlinear finite element model was verified against test results. An extensive parametric study was carried out to study the effects of cross-section geometries on the strength and behaviour of stainless steel slender circular hollow section columns with large D/t ratio. The column strengths predicted from the parametric study were compared with the design strengths calculated using the American Specification, Australian/New Zealand Standard and European Code for cold-formed stainless steel structures. It is shown that the design strengths obtained using the Australian/New Zealand and European specifications are generally unconservative for the cold-formed stainless steel slender circular hollow section columns, while the American Specification is generally quite conservative. Therefore, design equation was proposed in this study.

Crash Performance Evaluation of Hydro-formed Automotive DP-Steel Tube Considering Welding Heat Effects (용접부의 영향을 고려한 하이드로포밍된 자동차용 DP강관의 충돌 특성 평가)

  • Chung, K.H.;Kwon, H.S.;Park, S.H.;Ro, D.S.;Chung, K.
    • Transactions of Materials Processing
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    • v.15 no.8 s.89
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    • pp.568-573
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    • 2006
  • In order to numerically evaluate automotive hydro-formed DP-steel tubes on crash performance considering welding heat effects, the finite element simulations of crash behavior were performed for hydro-formed tubes with and without heat treatment effects. This work involves the mechanical characterization of the base material and the HAG-welded zone as well as finite element simulations of the crash test of hydro-formed tubes with welded brackets and hydro-forming of tubes. The welding heat effects on the crash performance are evaluated in efforts to improve the process optimization procedure of the engine cradle in the design stage. In particular, FEM simulations on indentations have been performed and experimentally verified for material properties of weld zone and heat affected zone.

Studies on Tropolones (Ⅲ) Structures and Reaction Mechanisms of the Adducts of Dichloroketene and Cyclopentadienes (Tropolone 類에 關한 硏究 (III) Dichloroketene과 Cyclopentadiene 類의 添加物의 構造와 그 反應機構)

  • Jae Hu Shim
    • Journal of the Korean Chemical Society
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    • v.13 no.1
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    • pp.89-95
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    • 1969
  • The structural investigations on the adducts, formed from dichloroketene with cyclopentadiene, methyl and ethylcyclopentadiene, have been carried out by means of infrared and nuclear magnetic resonance spectroscopy and also by their chemical behaviors. It was confirmed by this study that the adducts were formed by 1, 2-cycloaddition reaction and had the fundamental structure of bicyclo [3. 2. 0]-7,7-dichloro-2-heptene-6-one. These results were well agreed with the hypothesis that a diradical intermediate was formed as the first step in 1, 2-cycloaddition. The reaction mechanism for the process in which tropolones were formed from these adducts was also discussed.

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Dimesogenic Compounds Consisting of Two Identical Terminal N-(4-Oxybenzylidene)-4-n-butylaniline Units and a Central Polymethylene Spacer

  • Jung-Il Jin;Bong Young Chung;Joo-Hoon Park
    • Bulletin of the Korean Chemical Society
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    • v.12 no.5
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    • pp.583-588
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    • 1991
  • A series of dimesogenic compounds having two identical, terminal Schiff base type mesogens and a central polymethylene spacer were prepared and their properties were compared with those of the corresponding monomesogenic compounds. The mesomorphic properties of the compounds were studied by differential scanning calorimetry and on a hot-stage of a polarizing microscope. All of the dimesogenic compounds formed mesophases enantiotropically with the exception of pentamethylene-1,5-bis(4-oxybenzylidene 4-n-butylaniline). This compound was monotropic and formed only a nematic phase on heating the solid, whereas it formed nematic as well as smectic A phases on cooling the isotropic liquid. Those compounds containing longer (octamethylene and decamethylene) spacers favored the formation of nematic phase whereas those having shorter (dimethylene and tetramethylene) spacers formed smectic phases. In general, the variety of mesophase forms exhibited by the dimesogenic compounds was significantly less than that shown by the corresponding monomesogenic compounds.