• Title/Summary/Keyword: weak layers

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Effect of centrifugation on the structure and properties of silk sericin

  • Park, Chun Jin;Um, In Chul
    • International Journal of Industrial Entomology and Biomaterials
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    • v.33 no.2
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    • pp.144-148
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    • 2016
  • Recently, silk sericin has been studied extensively for biomedical and cosmetic applications because of its unique properties, including UV resistance and wound healing ability. For use in applications, sericin is fabricated in various forms including films and gels. However, the mechanical properties of sericin are too weak. In this basic study on improving the mechanical properties of sericin, a silk sericin aqueous solution was separated into two layers by centrifugation. The solution viscosity, molecular conformation, and mechanical properties of each separation layer of the sericin were examined. Sericin from the lower layer had a higher solution viscosity and film mechanical properties (strength and strain) than that from the upper layer, implying that sericin from the lower layer had a higher molecular weight than that from the upper layer. The molecular conformation of the sericin films varied depending on the casting solvent. In aqueous solution, the sericin film from the lower layer showed a ${\beta}$-sheet conformation, whereas that from the upper layer displayed a random coil conformation. All the sericin films showed a highly ${\beta}$-sheet-crystallized state when cast in formic acid, regardless of the separation layer.

A Visualization System for Multiple Heterogeneous Network Security Data and Fusion Analysis

  • Zhang, Sheng;Shi, Ronghua;Zhao, Jue
    • KSII Transactions on Internet and Information Systems (TIIS)
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    • v.10 no.6
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    • pp.2801-2816
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    • 2016
  • Owing to their low scalability, weak support on big data, insufficient data collaborative analysis and inadequate situational awareness, the traditional methods fail to meet the needs of the security data analysis. This paper proposes visualization methods to fuse the multi-source security data and grasp the network situation. Firstly, data sources are classified at their collection positions, with the objects of security data taken from three different layers. Secondly, the Heatmap is adopted to show host status; the Treemap is used to visualize Netflow logs; and the radial Node-link diagram is employed to express IPS logs. Finally, the Labeled Treemap is invented to make a fusion at data-level and the Time-series features are extracted to fuse data at feature-level. The comparative analyses with the prize-winning works prove this method enjoying substantial advantages for network analysts to facilitate data feature fusion, better understand network security situation with a unified, convenient and accurate mode.

Study on Phase Separation of Carbon Dioxide-reducible Polymer Blends (이산화탄소 저감형 고분자 블렌드의 상 분리 특성연구)

  • Cho, Yong-Kwang;Kim, Yeong-Woo;Lee, Hak Yong;Park, Sang-Bo;Park, Chan-Young;Lee, Won-Ki
    • Journal of Environmental Science International
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    • v.24 no.1
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    • pp.9-15
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    • 2015
  • Sustainable and eco-friendly polymers, natural polymers, bio-based polymers, and degradable polyesters, are of growing interest because of environmental concerns associated with waste plastics and emissions of carbon dioxide from preparation of petroleum-based polymers. Degradable polymers, poly(butylene adipate-co-terephthalate) (PBAT), poly(propylene carbonate) (PPC), and poly(L-lactic acid) (PLLA), are related to reduction of carbon dioxide in processing. To improve a weak mechanical property of a degradable polymer, a blending method is widely used. This study was forced on the component separation of degradable polymer blends for effective recycling. The melt-mixed blend films in a specific solvent were separated by two layers. Each layer was analysed by FT-IR, DSC, and contact angle measurements. The results showed that each component in the PPC/PLLA and PPC/PBAT blends was successfully separated by a solvent.

Ecological Model Experiments of the Spring Bloom at a Dumping Site in the Yellow Sea (생태계모델을 이용한 황해투기해역에서의 춘계 식물플랑크톤 대증식 연구)

  • Song, Kyu-Min;Lee, Sang-Ryong;Lee, Seok;Ahn, Yu-Hwan
    • Ocean and Polar Research
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    • v.29 no.3
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    • pp.217-231
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    • 2007
  • To explore limiting factors of spring bloom caused by waste disposal after dumping activity commenced in the Yellow Sea, we used a 1-dimensional temperature-ecological coupled model. The vertical structure of temperature and vertical diffusivity (Kh) are calculated by the temperature model with sea surface temperature using the 2.5 layers turbulence closure scheme. The ecological model applied results at the temperature model consisted of five state variables (DIN, DIP, phytoplankton, zooplankton, and detritus) forced by photosynthetically available radiation. We simulate year-to-year variations of plankton and nutrients using the coupled model from 1998 to 2000 and compare results of the model with observed data. It turned out that temperature is the growth factor of spring bloom in dumping area. During the winter the weak stratification made sufficient supply of the accumulated nutrients from the sea bed into the upper water column and led to the bloom in the coming spring. Radiation also turned out to be another important factor of spring bloom in the study area. Insufficient radiation of March 1999 showed low chlorophyll-a concentration despite sufficient nutrients in the surface.

Observation of Water Property Variations in the Western Channel of the Korea Strait During 2006-2010 (2006~2010년 기간 동안 대한해협 서수도에서 관측된 해수 물성의 변동)

  • Min, Hong-Sik;Park, Jae-Hun;Choi, A-Ra;Park, Young-Gyu;Shin, Kyoung-Soon;Jang, Pung-Guk
    • Ocean and Polar Research
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    • v.33 no.spc3
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    • pp.325-336
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    • 2011
  • Seasonal to inter-annual variations of water properties in the western channel of the Korea Strait are investigated using quasi-monthly hydrographic observations collected during 2006-2010. Weak vertical temperature and salinity gradients are observed during the winter months and these remain until May. At the upper layer, temperature increases from March and reaches a maximum in August, while salinity decreases during the same period. Near-bottom water shows low temperatures during late winter and fall with a minimum peak in September. Korea Strait Bottom Cold Water produces thick layers (>20 m) in 2006 and 2010, while it is observed very near the bottom with relatively high temperature in 2008 and 2009.

Extension of a new tailoring optimisation technique to sandwich shells with laminated faces

  • Icardi, Ugo
    • Structural Engineering and Mechanics
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    • v.43 no.6
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    • pp.739-759
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    • 2012
  • The tailoring optimization technique recently developed by the author for improving structural response and energy absorption of composites is extended to sandwich shells using a previously developed zig-zag shell model with hierarchic representation of displacements. The in-plane variation of the stiffness properties of plies and the through-the thickness variation of the core properties are determined solving the Euler-Lagrange equations of an extremal problem in which the strain energy due to out-of-plane strains and stresses is minimised, while that due to their in-plane counterparts is maximised. In this way, the energy stored by unwanted out-of-plane modes involving weak properties is transferred to acceptable in-plane modes. As shown by the numerical applications, the critical interlaminar stress concentrations at the interfaces with the core are consistently reduced without any bending stiffness loss and the strength to debonding of faces from the core is improved. The structural model was recently developed by the author to accurately describe strain energy and interlaminar stresses from the constitutive equations. It a priori fulfills the displacement and stress contact conditions at the interfaces, considers a second order expansion of Lame's coefficients and a hierarchic representation that adapts to the variation of solutions. Its functional d.o.f. are the traditional mid-plane displacements and the shear rotations, so refinement implies no increase of the number of functional d.o.f. Sandwich shells are represented as multilayered shells made of layers with different thickness and material properties, the core being treated as a thick intermediate layer.

A Case Report of Proventriculotomy for Impaction of Proventriculus in Ostrich (타조에서 전위절개술을 통한 매복의 치유예)

  • 김남수;이종일
    • Journal of Veterinary Clinics
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    • v.16 no.2
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    • pp.469-473
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    • 1999
  • A 120 kg, 3-year-old, male ostrich (Struthio camelus) was submitted to the veterinary teaching hospital, Chonbuk national university, for chronic weight loss, anorexia, small hard fecal pellets, and lethargy. Illness was first noticed approximately 2 weeks before submission. Although the bird was able to stand, he was extremely weak and cachectic. Blood examination indicated that the bird was dehydration (PCV: 55%). Fluoroscopic and lateral abdominal radio-graphic view indicated impaction of distended proventriculus with bigger rocks than normal. Anesthesia was induced with ketamine (10 mg/kg, IV)-xylazine (1 mg/kg, IV) combination and maintained with ketamine (10 mg/kg, IV) at intervals of 8 to 15 minutes during the entire procedure. After induction of general anesthesia, the bird was positioned in dorsal recumbency. The skin was incised approximately 15cm caudal to the caudal margin of the sternum and extended 20 to 25 cm caudally. After the proventriculotomy was peformed, the impacted material that weighed 3kg contained rocks in 4 to 6cm diameter was removed. The incision of proventriculus was closed in 2 layers. Cephalothin sodium (30 mg/kg, IV, q12hrs) and dexamethazone (2 mg/kg, IM, q24hrs) was administered before and after 5 days of the operation. The bird was eating well and defecating normal feces after 3 weeks of the surgery

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Preparation of PVDF/PEI double-layer composite hollow fiber membranes for enhancing tensile strength of PVDF membranes

  • Yuan, Jun-Gui;Shi, Bao-Li;Ji, Ling-Yun
    • Membrane and Water Treatment
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    • v.5 no.2
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    • pp.109-122
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    • 2014
  • Polyvinylidene fluoride (PVDF) hollow fiber membrane is widely used for water treatment. However, the weak mechanical strength of PVDF limits its application. To enhance its tensile strength, a double-layer composite hollow fiber membrane, with PVDF and polyetherimide as the external and inner layers, respectively, was successfully prepared through phase inversion technique. The effects of additive content, air gap distance, N,N-dimethyl-acetamide content in the inner core liquid, and the temperature of external coagulation bath on the membrane structure, permeation flux, rejection, tensile strength, and porosity were determined. Experimental results showed that the optimum preparation conditions for the double-layer composite hollow fiber membrane were as follows: PEG-400 and PEG-600, 5 wt%; air gap distance, 10 cm; inner core liquid and the external coagulation bath should be water; and temperature of the external coagulation bath, 40 C. A single layer PVDF hollow fiber membrane (without PEI layer) was also prepared under optimum conditions. The double-layer composite membrane remarkably improved the tensile strength compared with the single-layer PVDF hollow fiber membrane. The permeation flux, rejection, and porosity were also slightly enhanced. High-tensile strength hollow fiber PVDF ultrafiltration membrane can be fabricated using the proposed technique.

1D and 2D Cobalt(II) Coordination Polymers, Co(ox)(en): Synthesis, Structures and Magnetic Properties

  • Kang, Jaeun;Lee, Yumi;Kim, Seungjoo;Yun, Hoseop;Do, Junghwan
    • Bulletin of the Korean Chemical Society
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    • v.35 no.11
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    • pp.3244-3248
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    • 2014
  • Two ethylenediamine cobalt(II) oxalate complexes Co(ox)(en), 1 and $Co(ox)(en){\cdot}2H_2O$, 2 have been hydrothermally synthesized and characterized by single crystal X-ray diffraction, IR spectrum, TG analysis, and magnetic measurements. In 1, Co atoms are coordinated by two bis-bidentate oxalate ions in transconfiguration to form Co(ox) chains, which are further bridged by ethylenediamine molecules to produce 2D grid layers, Co(ox)(en). In 2, Co atoms are coordinated by bridging oxalate ions in cis-configuration to form Co(ox) chains, and the additional chelation of ethylenediamine to Co atoms completes 1D zigzag chain, Co(en)(ox). Two lattice water molecules stabilize the chains through hydrogen bonding. Magnetic susceptibility measurements indicate that both complexes exhibit weak antiferromagnetic coupling between cobalt(II) ions with the susceptibility maxima at 23 K for 1 and 20 K for 2, respectively. In 1 and 2, the oxalate ligands afford a much shorter and more effective pathway for the magnetic interaction between cobalt ions compared to the ethylenediamine ligands, so the magnetic behaviors of both complexes could be well described with 1D infinite magnetic chain model.

Analysis of Multi-Layered Structural Systems Using Nonlinear Finite Elements-Boundary Elements (반무한 다중 구조계의 비선형 유한요소 - 경계요소 해석)

  • 김문겸;장정범;이상도;황학주
    • Proceedings of the Computational Structural Engineering Institute Conference
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    • 1992.04a
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    • pp.58-64
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    • 1992
  • It is usual that underground structures are constructed within multi-layered medium. In this paper, an efficient numerical model ling of multi-layered structural systems is studied using coupled analysis of finite elements and boundary elements. The finite elements are applied to the area in which the material nonlinearity is dominated, and the boundary elements are applied to the far field area where the nonlinearity is relatively weak. In the boundary element model 1 ins of the multi-layered medium, fundamental solutions are restricted. Thus, methods which can utilize existing Kelvin and Melan solution are sought for the interior multi-layered domain problem and semi infinite domain problem. Interior domain problem which has piecewise homogeneous layers is analyzed using boundary elements with Kelvin solution; by discretizing each homogeneous subregion and applying compatibility and equilibrium conditions between interfaces. Semi-infinite domain problem is analyzed using boundary elements with Melan solution, by superposing unit stiffness matrices which are obtained for each layer by enemy method. Each methodology is verified by comparing its results which the results from the finite element analysis and it is concluded that coupled analysis using boundary elements and finite elements can be reasonable and efficient if the superposition technique is applied for the multi-layered semi-infinite domain problems.

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