• 제목/요약/키워드: water-vapor transmission rate

검색결과 75건 처리시간 0.047초

생고분자 필름의 투습도 측정 (Measurement of Water Vapor Permeability of Bio-polymer Films)

  • 임종환
    • 한국포장학회지
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    • 제5권1호
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    • pp.37-46
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    • 1999
  • Water vapor permeability of films is commonly calculated from the water vapor transmission rate of the film measured using a permeability cup method which is essentially a gravimetric method. This method was originally developed for petroleum based plastic films with low water vapor permeability. In the case of hydrophilic bio-polymer films, the resistance caused by a stagnant air layer, which is developed between the underside of the film mounted on the cup and the surface of the desiccant saturated salt solution or distilled water, can be significant and, if neglected, ran lead to underestimation of water vapor transmission rates. Therefore, it is necessary to correct water vapor transmission rate data to accurately estimate the water vapor permeability of bio-polymer films.

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방습 효과가 우수한 환경친화적 방습지(제1보) -방습제의 특성- (Environmentally Friendly Moisture-proof Paper with Superior Moisture Proof Property (I) -Properties of Moisture Proof Chemicals-)

  • 유재국;조욱기;이명구
    • 펄프종이기술
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    • 제33권4호
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    • pp.15-20
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    • 2001
  • The function of the moisture-proof paper is to prevent moisture from adsorbing into the packed goods. Water-vapor transmission rate of the moisture-proof paper should be less than 100g/$m^2$.24hr and the optimum rate would be less than 50g/$m^2$.24hr. In general the moisture-proof paper has been made by laminating polyethylene or polypropylene on top of the base paper. However this kind of moisture-proof paper has a problem in recycling so that it brings about environmental pollution. In general the moisture-proof paper has been made by laminating polyethylene or polypropylene on top of the base paper. However this kind of moisture-proof paper has a problem in recycling so that it brings about environmental pollution. The purpose of this paper was to make moisture-proof paper using the mixture of SB latex and wax emulsion which was recyclable and environmentally friendly. Water vapor transmission rate showed less than 50g/$m^2$.24hr in mixture ratio of 85:15, 87:13, 90:10. Especially the mixture ratio of 87:13 showed the most favorable water-vapor transmission rate. However, the moisture-proof layer was destroyed slightly by folding in packing. It has been observed that there was no close relationship between water-vapor transmission rate of the moisture-proof paper and grammage of the base paper, but the density of base paper had influenced on water vapor transmission rate. It was also observed that the moisture-proof paper could be recycled. The moisture-proof paper was similar to base paper in degree of the pulping, and there was no significant difference in dispersion between moisture-proof paper and base paper. Most of wax particles which caused the spots during drying process could be removed by flotation process. Tensile strength and tear strength of both moisture-proof paper and base paper after pulping were measured to examine the fiber bonding, and no significant difference in physical properties was observed.

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카라기난 필름의 투습 특성 (Water-Vapor Transfer Characteristics of Carrageenan-Based Edible Film)

  • 임종환;황금택;박현진;정순택
    • 한국식품과학회지
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    • 제28권3호
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    • pp.545-551
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    • 1996
  • 카라기난을 사용하여 제조한 생분해성 필름의 분말식품에 대한 응용성을 조사하기 위한 연구의 일환으로 3종의 두께(0.05, 0.08, 0.11 mm)로 제작된 카라기난 필름을 사용하여 5가지의 온도(20, 25, 30, 35, $4^{\circ}C$)와 3가지의 상대습도(50, 70, 90%RH) 조건에서 수증기투과율을 측정하여 카라기난 필름의 투습 특성을 조사하였다. 카라기난 필름의 수증기투과율은 PE 필름보다 2.3배 정도 높았으며, 투습계수는 PE 필름보다 45-230배 정도 높아 수증기투과도가 높음을 알 수 있었다. 카라기난 필름의 투습계수는 다른 친수성의 가식성 필름과 마찬가지로 필름의 두께가 증가할수록 직선적으로 증가하는 경향을 보였다. 카라기난 필름의 투습계수는 온도에 대한 의존성을 나타내지 않았으나, 수증기투과율은 온도에 대한 의존성을 나타냈다. 카라기난 필름의 수증기투과율의 활성화 에너지는 필름의 두께에 따라 7.898-12.872 kj/mol의 값을 보였다. 카라기난 필름의 수증기투과율은 활성화 에너지 값이 커짐에 따라 지수앞인자의 값도 증가하는 kinetic compensation 현상을 나타냈다.

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Layer-by-layer assembled graphene oxide films and barrier properties of thermally reduced graphene oxide membranes

  • Kim, Seon-Guk;Park, Ok-Kyung;Lee, Joong Hee;Ku, Bon-Cheol
    • Carbon letters
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    • 제14권4호
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    • pp.247-250
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    • 2013
  • In this study, we present a facile method of fabricating graphene oxide (GO) films on the surface of polyimide (PI) via layer-by-layer (LBL) assembly of charged GO. The positively charged amino-phenyl functionalized GO (APGO) is alternatively complexed with the negatively charged GO through an electrostatic LBL assembly process. Furthermore, we investigated the water vapor transmission rate and oxygen transmission rate of the prepared (reduced GO $[rGO]/rAPGO)_{10}$ deposited PI film (rGO/rAPGO/PI) and pure PI film. The water vapor transmission rate of the GO and APGO-coated PI composite film was increased due to the intrinsically hydrophilic property of the charged composite films. However, the oxygen transmission rate was decreased from 220 to 78 $cm^3/m^2{\cdot}day{\cdot}atm$, due to the barrier effect of the graphene films on the PI surface. Since the proposed method allows for large-scale production of graphene films, it is considered to have potential for utilization in various applications.

새로 개발한 실리콘젤시트의 물성에 대한 연구 (Comparison Study of Physical Properties between Two Silicone Gel Sheets)

  • 윤영묵;강낙헌;김태준
    • Archives of Plastic Surgery
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    • 제35권6호
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    • pp.659-662
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    • 2008
  • Purpose: Silicone gel sheet(SGS) is used for preventing and treating keloid or hypertrophic scars. Because the product is weak in tear strength and adherence, it requires several replacements, which requires high cost. As a solution for this problem, we developed a new silicone gel sheet, named as Scar Clinic, and confirmed its physical properties. Methods: Tensile strength, elongation rate, adhesiveness, and water vapor transmission rate were experimentally compared between the most commonly used SGS product and the Scar Clinic. Results: The newly developed SGS showed better results compared to the existed SGS in regards to tensile strength, elongation rate, adhesiveness, and water vapor transmission rate. Conclusion: The Scar Clinic showed higher durability and flexibility. It will be a useful product for treating scars clinically.

종이 물성이 전열교환 엘리먼트 성능에 미치는 영향 (Effect of Paper Properties on the Performance of a Enthalpy Exchanger)

  • 김내현;조진표;송길섭;김동훈
    • 대한설비공학회:학술대회논문집
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    • 대한설비공학회 2008년도 하계학술발표대회 논문집
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    • pp.414-418
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    • 2008
  • The effects of paper properties such as density, air permeability, water vapor transmission rate on the thermal performance of plate-type enthalpy exchanger were experimentally investigated. Three enthalpy exchanger samples having different properties were made, and were tested according to the standard test procedure (KS B 6879). Effective efficiencies were defined, which accounted for the air leakage between supply and exhaust streams. Results showed that paper density affected the sensible heat transfer of the samples. Sensible heat transfer increased with density of the paper. It was also shown that water vapor transmission rate alone was not a proper indicator for the efficiency of latent heat transfer. Air permeability should also be considered for adequate evaluation of the latent heat transfer. Best performance was obtained for the sample having highest paper density and moderate water vapor transmission ratio.

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종이 물성에 따른 판형 전열교환기의 성능 (Performance of a Plate-Type Enthalpy Exchanger Made of Papers Having Different Properties)

  • 김내현;조진표;송길섭;김동훈
    • 설비공학논문집
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    • 제20권8호
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    • pp.547-555
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    • 2008
  • The effects of paper properties such as density, air permeability, water vapor transmission rate on the thermal performance of plate-type enthalpy exchanger were experimentally investigated. Papers having different properties were made from the same pulp by calendering or refining. Enthalpy exchanger samples were made from the papers, and were tested according to the standard test procedure (KS B 6879). Effective efficiencies were obtained, which accounted for the air leakage between supply and exhaust streams. Results showed that paper density affected the sensible heat transfer of the samples. Sensible heat transfer increased with density of the paper. It was also shown that effective efficiency of latent heat transfer was approximately the same independent of the samples, which suggests that papers made of the same pulp show similar water vapor transmission characteristics independent of the degree of calendering or refining. Best performance was obtained for the sample having highest paper density and moderate water vapor transmission ratio.

Water vapor barrier properties of polymer-like amorphous carbon deposited polyethylene naphthalate film

  • 김정용;박규대;송예슬;이희진;;김성룡
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2016년도 제50회 동계 정기학술대회 초록집
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    • pp.303.1-303.1
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    • 2016
  • Polymer-like amorphous carbon films were deposited on polyethylene naphthalate (PEN) substrate by plasma-enhanced chemical vapor deposition (PECVD) and their water vapor transmission rates (WVTR) were tested. propane was used as precursors. To make a polymer-like amorphous carbon film the deposition rate, surface roughness, light transmittance, and WVTR of the films were characterized as a function of the precursor feed ratio and plasma power. The water vapor transmission rates of bare PEN film and single layer PAC on PEN substrate were 6.95 g/m2/day and 0.3 g/m2/day, respectively. The superior property the water vapor permeability of thin layers of PAC was attributed to uniform coverage and good adhesion between PAC film and PEN substrate.

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Improvement in the negative bias stability on the water vapor permeation barriers on Hf doped $SnO_x$ thin film transistors

  • 한동석;문대용;박재형;강유진;윤돈규;신소라;박종완
    • 한국재료학회:학술대회논문집
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    • 한국재료학회 2012년도 춘계학술발표대회
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    • pp.110.1-110.1
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    • 2012
  • Recently, advances in ZnO based oxide semiconductor materials have accelerated the development of thin-film transistors (TFTs), which are the building blocks for active matrix flat-panel displays including liquid crystal displays (LCD) and organic light-emitting diodes (OLED). However, the electrical performances of oxide semiconductors are significantly affected by interactions with the ambient atmosphere. Jeong et al. reported that the channel of the IGZO-TFT is very sensitive to water vapor adsorption. Thus, water vapor passivation layers are necessary for long-term current stability in the operation of the oxide-based TFTs. In the present work, $Al_2O_3$ and $TiO_2$ thin films were deposited on poly ether sulfon (PES) and $SnO_x$-based TFTs by electron cyclotron resonance atomic layer deposition (ECR-ALD). And enhancing the WVTR (water vapor transmission rate) characteristics, barrier layer structure was modified to $Al_2O_3/TiO_2$ layered structure. For example, $Al_2O_3$, $TiO_2$ single layer, $Al_2O_3/TiO_2$ double layer and $Al_2O_3/TiO_2/Al_2O_3/TiO_2$ multilayer were studied for enhancement of water vapor barrier properties. After thin film water vapor barrier deposited on PES substrate and $SnO_x$-based TFT, thin film permeation characteristics were three orders of magnitude smaller than that without water vapor barrier layer of PES substrate, stability of $SnO_x$-based TFT devices were significantly improved. Therefore, the results indicate that $Al_2O_3/TiO_2$ water vapor barrier layers are highly proper for use as a passivation layer in $SnO_x$-based TFT devices.

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Poly(3-Hydroxybutyric Acid)와 Chitosan 블렌드 필름의 기체 투과도, 유지 투과도 및 생분해도 (Gas and Lipid Permeabilities and Biodegradability of Poly(3-Hydroxybutyric Acid)/Chitosan Blend Film)

  • 김미라
    • 한국식품영양과학회지
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    • 제33권7호
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    • pp.1224-1229
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    • 2004
  • PHB/chitosan 필름의 수분 투과도는 PHB 필름께서 280.25 g/m$^2$ㆍ24 hr로 가장 높았고 chitosan의 함량이 증파할수록 수분 투과도는 낮아지는 경향을 보였다. PEG가 첨가된 PHB/chitosan 필름에서도 PHB-P 필름의 수분 투과도가 294.5 g/m$^2$ㆍ24 hr로 가장 높았고, chitosan의 함량이 증가할수록 수분 투과도는 낮아졌다. 산소 투과도의 경우 PHB 필름이 0.026${\times}$$10^{-10}$$cm^3$(STP) cm/$cm^2$ㆍsecㆍcmHg로 가장 높았으며 chitosan의 첨가 비율이 증가할수록 산소 투과도는 낮아졌다. 또한 가소제인 PEG가 첨가되지 않은 필름이 PEG가 첨가된 필름보다 산소 투과도가 더 낮았다. 유지 투과도에서는 PHB와 PHB-P를 제외한 필름들이 24시간동안 유지론 통과시키지 않아 유지 차단성이 우수한 것으로 나타났다. 필름의 생분해도 측정시 필름을 첨가하지 않은 대조군에 비해 필름이 첨가된 실험군의 산소 소모량이 높아 필름이 생분해되고 있음을 확인할 수 있었으며 필름의 PHB의 비율이 높을수록 분해도가 높은 것으로 나타났다.