• Journal of Korean Society of Forest Science
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• v.82 no.4
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• pp.347-353
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• 1993

Accumulation of air pollutants such as $SO_2$ and HF, chlorophyll contents, wax concentrations in needle tissue and needle growth of Pinus thunbergii were studied to verify possibilities of bioindicators of air pollution in Yochon Industrial Complex from July to October, 1991. The concentrations of water-soluble sulfur and fluorine increased nearer to the pollution sources regardless of sampling time, but water-soluble sulfur varied little during investigation and fluorine accumulated more with the passage of time. Total chlorophyll contents decreased a little in the slightly polluted site but sharply in the heavily polluted site. The higher the pollution level was, the more decreased chloroform-extractable wax. Air pollution exposure inhibited needle growth of Pinus tbunbergii during the latter part of growth period. Water soluble sulfur, fluorine and wax concentrations in needle of Pinus thunbergii were rather wood sensitive indicators of susceptibility to ambient air pollution from early July to early October. Chlorophyll contents seemed to be able to be used as a bioindicator of air pollution in early stage of needle development and in the severely polluted area. In the meanwhile needle length must be used as a bioindicator in latter part of growing season.

• Journal of environmental and Sanitary engineering
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• v.1 no.1 s.1
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• pp.97-107
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• 1986

This study was performed to investigate the air pollution tolerance of urban trees; Gingko biloba, Platanus occidentalis, Salix pseudolagiogyne and Purunus serrulata growing in Seoul, Taegu, Chungju area. Vitality of trees and water soluble sulfur content in the leaves were determined at 24 points in those cities. The ratio of the each number of Platanus occidentalis, Gingko biloba, Salix psuedolagiogyne and Prunus serrulata to the total number of urban tree in Seoul area was $49.38\%,\; 17.36\%,\; 13.42\%,\;2.43\%$, respectively. Its ratio in Taegu area was $36.76\%,\;14.25\%,\;13.36\%,\;3.32\%$ and in the Chungju area was $59.06\%,\;17.35\%,\;11.09\%,\;8.33\%$, respectively. The species deversity was 0.7017, 09067, 0.5297 in Seoul, Taegu, Chungju, respectively. The significant correlation between the S02 concentration and the tree vitality highly found on Platanus occidentalis, Gingko biloba, Salix pseudolagiogyne and Prunus serrulata. Positive correlation coefficient between $SO_2$ concentration and water soluble sulfur content were shown on Platanus occidentalis, Salix pseudolagiogyne and Prunus serrulata and that between tree vitality and water soluble sulfur content were shown on Platanus occidentalis and Gingko biloba. The tolerant to the S02 gas was high in order of Salix pseudolagiogyne, Gingko biloba, Prunus serrulata and Platanus occidentalis. Also the absorption activity to the $SO_2$ gas was high in order of Salix psuedolagiogyne, Gingko biloba, Platanus occidentalis and Prunus serrulata.

• Korean Journal of Organic Agriculture
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• v.23 no.3
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• pp.567-582
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• 2015

Botrytis cinerea infects stems, leaves and fruits of greenhouse tomato and can cause serious economic losses. This study was conducted to develop organic farming control method against tomato gray mold. Twenty two organic farming materials including mineral and plant extracts were screened for the suppressive activity against Botrytis cinerea, in vitro and in vivo. Among the organic farming materials, sulfur, copper, Chinese twinleaf extract and rhubarb extract decreased by 51.7-90% of the spore germination of Botrytis cinerea. Also, gray mold incidence was reduced more than 90% on tomato stems by treating sulfur, seaweed extracts, rhubarb root extracts and Chinese twinleaf extract. After the selected four organic farming materials were applied on tomato cultivated in greenhouse, their control effects against the tomato gray mold were tested. When the water soluble sulfur was foliar-sprayed on the tomato leaves infected by artificial inoculation with spore suspension of Botrytis cinerea, it showed 87.9% of control value. Also, control activity of the water soluble sulfur was paralleled with chemical fungicide, diethofencarb+carbendazim. The above mentioned results indicate the sulfur formulation can be used as chemical fungicide alternatives for controlling tomato gray mold in the greenhouse.

• Environmental Analysis Health and Toxicology
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• v.12 no.3_4
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• pp.61-66
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• 1997

Recently, incidences of pulmonary-related diseases are increasing and natural ecosystem is destroyed year by year owing to air pollutions by industrial noxious gases such as sulfur dioxide and carbon dioxide, etc. Sulfur dioxide produced by oxidation of sulfur compounds is water soluble and causes several kinds of pulmonary diseases, damaging on plants and animals. This study was undertaken to investigate effects of acute exposure of rats to sulfur dioxide using biochemical parameters. The sAST (aspartate transaminase) activity was not significantly affected but sALT (alanine transaminase), sLDH (lactate dehydrogenase) and sALP (alkaline phosphatase) activities were significantly increased by acute sulfur dioxide gas exposure. Also sulfur dioxide gas treatment significantly diminished serum cholinesterase activity. The total lipid, triglyceride, total-, HDL- and LDL-cholesterol contents were significantly increased by sulfur dioxide gas exposures. But the body and liver weight were generally diminished in comparison with control group. Our results' showed increased enzyme activities and lipid contents, but body and liver weight were all diminished by sulfur dioxide gas treatment.

• The Korean Journal of Pesticide Science
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• v.18 no.4
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• pp.376-382
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• 2014

The soluble loess-sulfur mixture allowed standing to remove insoluble component materials for five weeks after manufacturing. We decreased the pH level of soluble loess-sulfur mixture at pH 1.0 modified with decreasing 25% sodium hydroxide than original content. The pH ranges of soluble loess-sulfur mixture solutions were adjusted to pH 5.0-pH 11.0 (pH 1 unit) with brown rice vinegar (pH 2.8). The pH of original loess-sulfur mixture was about pH 13 and damaged the foliar parts and young leaves of tomato after twice application. These stock solutions can be diluted 500:1 with tap water to make a 0.05% working solution and were sprayed two times with 7 days interval to the leaf and stem of tomato, which were spontaneously infected with E. cichoracearum. Control efficacy of powdery mildew ranged from 85% to 90% at 7 days after first application. After second application, each loess-sulfur mixture solutions adjusted pH level significantly suppressed the powdery mildew disease in tomato. Consequently, loess-sulfur complex adjusted pH level with brown rice vinegar was suggested to be low in acute toxicity at all different pH values and suggested to use an agent for control of tomato powdery mildew in organic farming.

• Journal of the Korean Applied Science and Technology
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• v.13 no.2
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• pp.85-92
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• 1996

Chitosan itself has been prepared using chitin, one of the most abundant compounds in nature, as a starting material. We have synthesized the water-soluble chitosan derivative, N-dithiocarboxy chitosan sodium salt, through the reaction of water-soluble chitosan with carbon disulfide in the presence of alkali metal hydroxide. To elucidate this natural polymer capacity of adsorbing heavy metal ions, we have performed adsorption experiments using the water-soluble chitosan derivative various average molecular weight and of different percent contents of sulfur. The effect of pH, adsorption time and temperature on adsorption efficiency was also studied. The adsorbent derived from water-soluble chitosan of average molecular weight ranging $9,000{\sim}120,000$ was shown to have the highest capacity of adsorbing heavy metal ions. On the whole, adsorbing efficiency was increased as the reaction time goes longer and also increased as the reaction temperture goes higer in temperture range of $15^{\circ}C{\sim}45^{\circ}C$. The adsorption capacity at various pH, however, was appeared to vary depending on the heavy metal ions studied Judging from these finding, water-soluble N-dithiocarboxy chitosan sodium salt, a derivative of a biodegradable nature polymer, is believed to be a potential adsorbent for heavy metal ions since it not only is shown to lower the concentration of heavy metal ions to below the drainage quality standard, but also it would not cause acidification and hardening of soil which is one of the detrimental effects of synthetic macromolecular adsorbents present.

• Food Science and Biotechnology
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• v.17 no.5
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• pp.1032-1037
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• 2008

Lowly volatile heterocyclic sulfur compounds generated in autoclaved garlic extract were isolated and identified, and their antimicrobial activity was determined. Two kinds of unusual volatile sulfur compounds were separated from heated garlic by preparative recycling high performance liquid chromatography (HPLC), and identified by gas chromatography (GC)-mass spectrometry (MS) and $^1H$-nuclear magnetic resonance (NMR). They had heterocyclic structures with 4 to 5 sulfur atoms in the molecules. 4-Methyl-1,2,3-trithiolane (MTTT) is highly volatile and was not able to be concentrated, and was identified by GCMS only. MTTT and 6-methyl-1,2,3,4,5-pentathiepane (MPTP) are lowly volatile and were obtained in pure states to be positively identified for the first time. All 3 heterocyclic sulfur compounds began to appear by the time when the early-formed diallyl sulfides started to disappear. The minimum inhibitory concentration range of MTTT and MPTP was determined to be between 1 and 6 ppm against all yeasts tested. MTTT and MPTP were lowly volatile and sparingly soluble in water.

• Korean Chemical Engineering Research
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• v.48 no.1
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• pp.20-26
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• 2010

Water soluble organic and inorganic species are important components in atmospheric aerosol particles and may act as cloud condensation nuclei to indirectly affect the climate. To characterize organic and elemental carbon(OC and EC), water-soluble organic carbon(WSOC) and inorganic ionic species contents, daily $PM_{2.5}$ measurements were made during the wintertime at an urban site of Gwangju. Average concentrations of WSOC, $NO_3^-$, $SO_4^{2-}$ and $NH_4^+$, which are major components in the water-soluble fraction in PM2.5, are 2.11, 5.73, 3.51 and $3.31{\mu}g/m^3$, respectively, representing 12.0(2.9~23.9%), 21.0(12.9~37.6%), 11.6(2.5~25.9%) and 11.7%(3.8~18.6%) of the $PM_{2.5}$, respectively. Abundance of water soluble organic compounds ranged from 5.4 to 35.9% of total water soluble organic and inorganic components with a mean of 17.6%. Even though the sampling was performed during the winter, the average contributions of secondary OC and WSOC, as deduced from primary OC/EC(or WSOC/EC) ratio, were relatively high, accounting for 17.9%(0~44.4%) of the total OC and 11.2%(0.0~51.4%) of the total WSOC, respectively. During the sampling period, low $SO_4^{2-}/(SO_4^{2-}+SO_2$) ratio of 0.14(0.03~0.32) and relative humidity condition in the winter time suggest an possibility of impact of long-range transport and/or aqueous transformation processes such as metal catalyzed oxidation of sulfur, in-cloud processes, etc.

• Korean Journal of Soil Science and Fertilizer
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• v.26 no.3
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• pp.204-214
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• 1993

The purpose of this study was to elucidate the chemical changes and formation of sulfur minerals following reduction and subsequent oxidation of the acid sulfate soils derived from the fluvio-marine plains in Gimhae area. Changes in pH, Eh and water soluble $SO_4$, Fe, Al, K, na and Ca were determined in the soil under the reduced and oxidized conditions. These chemical properties were related to the formation of the pyrite and jarosite, the major sulfur minerals in the acid sulfate soils. On incubation, suspension pH tended to increase with decreaseing Eh in the reduction periods. Jarosite formation was favored by maintaining continuous low pH(below 4.0) and high Eh(above 400mV) during the oxidation periods, however, the conditions were not favorable for the soils with $Ca(OH)_2$. Water soluble K increased by reduction but decreased by oxidation, while the jarosite of the soil with $Ca(OH)_2$ was dissolved even under the oxidation conditon, resulting in rapid increase of water soluble K. The water soluble Ca decreased rapidly, indicating that gypsum was formed with $Ca(OH)_2$ during the oxidation periods. The formation of jarosite was favored by the oxidation condition, and hindered by the reduction condition. But the formation of pyrite was favored by reduction and hindered by oxidation. When the troll was treated with $Ca(OH)_2$, Jarosite was dissolved in both oxidized and reduced conditions.

• Journal of Korean Society for Atmospheric Environment
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• v.13 no.6
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• pp.487-495
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• 1997

The most desirable diesel oxidation catalyst (DOC) should have the properties of oxidizing CO, HC and SOF effectively at low exhaust gas temperature while minimizing the formation of sulfate at high exhaust gas temperature. Precious metals such as platinum and palladium have been known to be sufficiently active for oxidizing SOF and also to have high activity for the oxidation of sulfur dioxide $(SO_2)$ to sulfur trioxide $(SO_3)$. There is a need to develop a highly selective catalyst which can promote the oxidation SOF efficiently, on the other hand, suppress the oxidation of $SO_2$. In this study, a Pt-V catalyst was prepared by impregnating platinum and vanadium onto a Ti-Si wash coated ceramic monolith substrate. A prepared Pt-V catalytic converter was installed on a heavy duty diesel engine and the effect of fuel sulfur on particulate matter (PM) of heavy duty diesel engine was measured. The effect of fuel sulfur on PM of Pt-V was also compared with that of a commercialized Pt catalyst currently being used in some of the heavy duty diesel engines in advanced countries. Only 1 $\sim$ 3% of sulfur in the diesel fuel was converted to sulfate in PM for the engine without catalyst, but almost 100% of sulfur conversion was achieved for the engine with Pt catalyst at maximum loading condition. In the case of Pt-V catalyst, there was no big difference in conversion with the base engine even at maximum loading condition. The reason of SOF increase according to the increase of suflate emission was identified as the washing off effect of bound water in sulfate.