• Title/Summary/Keyword: water vapor content

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Soil water retention and hysteresis behaviors of different clayey soils at high suctions

  • Li, Ze;Gao, You;Yu, Haihao;Chen, Bo;Wang, Long
    • Geomechanics and Engineering
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    • v.30 no.4
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    • pp.373-382
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    • 2022
  • Unsaturated soil at high suctions is widespread. Many civil engineering projects are related to the hydro-mechanical behavior of unsaturated soils at high suctions, particularly in arid and semiarid areas. To investigate water retention behaviors of nine clayey soils (one is classified as fat clay and the others are classified as lean clay according to the unified soil classification system), the high suction (3.29-286.7 MPa) was imposed on the specimens at zero net stress by the vapor equilibrium technique. In this paper, the effect of void ratio on the water retention behavior at high suction was discussed in detail. Validation data showed that soil types, i.e., different mineralogical compositions, are critical in the soil water retention behavior at a high suction range. Second, the hysteresis behavior at a high suction range is mainly related to the clay content and the specific surface area. And the mechanism of water retention and hysteresis behavior at high suctions was discussed. Moreover, the maximum suction is not a unique value, and it is crucial to determine the maximum suction value accurately, especially for the shear strength prediction at high suctions. If the soil consists of hydrophilic minerals such as montmorillonite and illite, the maximum suction will be lower than 106 kPa. Finally, using the area of hysteresis to quantify the degree of hysteresis at a high suction range is proposed. There was a good correlation between the area of hydraulic hysteresis and the specific surface area.

Aerobic Composting of sewage sludge Mixed Rice Hulls and Sawdusts (하수오니에 왕겨 및 톱밥을 혼합한 호기성 퇴비화)

  • 정봉수;강용태
    • Magazine of the Korean Society of Agricultural Engineers
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    • v.28 no.3
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    • pp.99-106
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    • 1986
  • This study was carried out to investigate the effects of moisture content, temperature, C/N ratio and pH of the sewage sludge mixed with hulle and sawdusts for making compost under aerobic condition and to improve the defect of the structure of experimental equipment heat lose and handling method. and obtained results were as follows 1.The temperature was reached 73$^{\circ}$ C around 50 hours fermentation in the condition of 0.8 L/min. of air and 60.4% of moisture content. and favorable moisture content of initial condition ranged from 50 to 65% 2.The temperature near bottom of the batch composter was decreased due to evaporate water vapor and lose the heat produced during aeration. and it is required to be improved. 3.The temperature in the batch composter from the center to the inside wall surface was gradually decreased. the temperatures of the points located in r=9cm and the wall surface were 4$^{\circ}$ C and 6$^{\circ}$ C respectively. and therefore it is required to be insulated. 4. The maximum C02 production was obtained as 7.3% per volume in the temperature of 63$^{\circ}$C at the moisture content of 60% 5.The temperature range of active microbes growth was found to be as 20$^{\circ}$C to 40$^{\circ}$C in the case of mesophiles and 50$^{\circ}$C to 65$^{\circ}$C in the case of thermophiles due to increase and decrease C02 production. 6.C/N ratio after decomposition was 1.3 to 2.6 smaller than that of initial one due to increase the amount of nitrogen. The more C/N ratio increased. the less the reaction velocity decresed. The optimum of it as found to be 30. 7.pH values after decomposition were slightly increased than that of initial ones. The reaction velocity was decreased at acid and alkall condition. Therefore it is neseseary to neutralize the medium to improve the reaction.

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Study of CO2 Adsorption Characteristics on Acid Treated and LiOH Impregnated Activated Carbons (산 처리 및 LiOH 첨착 활성탄에서 이산화탄소의 흡착 특성에 대한 연구)

  • Han, Jae Uk;Kim, Dae Jung;Kang, Min;Kim, Jin Won;Kim, Ji Man;Yie, Jae Eui
    • Applied Chemistry for Engineering
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    • v.16 no.3
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    • pp.312-316
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    • 2005
  • Adsorption characteristics of $CO_2$ on activated carbons were evaluated using dynamic adsorption method in a fixed bed with acid treatment, LiOH impregnation and water vapor supply. Physical and chemical properties of the activated carbons were measured using SEM, EDS, nitrogen adsorption, FTIR and XRD. Nitric acid treatment led to the decrease in BET surface area and the increase in oxygen content of virgin activated carbon, and it produced a new functional group that included nitrogen. For the reduction of BET surface area by LiOH impregnation, the nitric acid treated activated carbon (NAC) was less than the virgin activated carbon (AC). Large particles of LiOH were present on the carbon surface when the content of LiOH was over 2 wt%. The adsorbed amount of $CO_2$ on activated carbon in a fixed bed increased with the acid treatment, LiOH impregnation and water vapor supply. The XRD results indicated that LiOH was converted to $Li_2CO_3$ after the adsorption of $CO_2$ on LiOH precursor.

Analysis of Factors Affecting the Hygroscopic Performance of Thermally Treated Pinus koraiensis Wood (잣나무열처리재의 흡방습성능에 미치는 영향인자 분석)

  • Chang, Yoon-Seong;Han, Yeon-Jung;Eom, Chang-Deuk;Park, Joo-Saeng;Park, Moon-Jae;Choi, In-Gyu;Yeo, Hwan-Myeong
    • Journal of the Korean Wood Science and Technology
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    • v.40 no.1
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    • pp.10-18
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    • 2012
  • A high airtightness is required for the residential spaces constructed recently to save cooling and heating energy through improving insulation performance. Because the chances to release steam formed by human activity in building and inflow of water vapor in outdoor air to residential space are reduced, the natural humidity control performance of interior materials has become more important. In this study, hygroscopic performance of thermo-physically treated wood (Pinus koraiensis) was estimated. At various relative humidity condition, the water vapor adsorption and desorption rates of wooden materials were measured as well as equilibrium moisture content. Effects of roughness and surface microstructure as physical factors and functional groups as chemical factors on the hygroscopicity were analyzed. It is expected that the results from this study and further study of measuring moisture generation in residential spaces could contribute to install a system for evaluating the hygrothermal performance of wooden building.

The Study of Water Resistance and Water/Oxygen Barrier Properties of Poly(vinyl alcohol)/Water-soluble Poly(ethylene-co-acrylic acid) Blend Films (폴리비닐알콜/수분산 에틸렌-아크릴산 공중합체 블렌딩 필름의 내수성 및 수분/산소 차단성 연구)

  • Kim, Eun Ji;Park, Jae Hyung;Paik, In Kyu
    • Applied Chemistry for Engineering
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    • v.23 no.2
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    • pp.217-221
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    • 2012
  • Blending films having enhanced water-resistance and barrier properties were prepared using the mixtures of poly(vinyl alcohol) (PVA) aqueous solution and poly(ethylene-co-acrylic acid) (EAA) dispersed in water. Thermal-mechanical properties, contact angles, water-vapor transmission rates (WVTR) and oxygen transmission rates $(O_2TR)$ were measured with the content of EAA of blending films, and their water-resistance was evaluated. The tensile strength of the films was found to be $9.16{\sim}11.75\;kg/mm^2$ which showed no significant difference compared with that of PVA, and the hardness increased with the content of EAA. The glass transition temperature and melting temperature of the blending films were slightly improved. The film prepared with PVA/EAA (= 90/10), of which the swelling and solubility were measured to be 109 and 0%, respectively, showed improved water-resistance. The WVTR and $O_2TR$ for the PET film (thickness $50\;{\mu}m$) coated with PVA/EAA (= 90/10) film (thickness $2.5\;{\mu}m$) were measured to be $9.1\;g/m^2/day$ and $2.0\;cc/m^2/day$, respectively.

Improvement of Water Resistant Properties of a Linerboard for Corrugated Fiberboard Box by Coating with Na-alginate (알긴산 코팅에 의한 골판지 상자 제조용 라이너 원지의 수분저항성 증진)

  • Kim, Eun-Jung;Rhim, Jong-Whan;Kim, Byung-Yong
    • Korean Journal of Food Science and Technology
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    • v.38 no.6
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    • pp.762-766
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    • 2006
  • To improve water resistance of paperboard used to manufacture the corrugated boxes, effect of surface coating of the liner- board with Na-alginate was investigated by determining the optimum processing conditions such as a optimum alginate concentration for surface coating, plasticizer content, concentration of divalent cations their immersion times, For the surface coating of the liner-board, 2.5% Na-alginate solution was found to be the optimum concentration, and the concentration of glycerol used as plasticizer was effective when 35% alginate concentration was use was Used Immersion of the alginate coated paperboard for 3 min in a $CaCl_2$ solution improved the water resistance properties. As a divalent cation for the insolubilization of the alginate films, $Cu^{2+}$ was found to be as effective as $Ca^{2+}$. Among the platicizers tested, sorbitol was the most effective in reducing water vapor permeability and water solubility of alginate coated paperboard.

A circular economical application of eggshell waste as a bio-filler in the fabrication of gum Arabic composite film

  • Blessing A. Oredokun-Lache;Esther B. Ibrahim;Adekemi G. Oluwafemi;Georgina O. Erifeta;Sunday J. Josiah;Olarewaju M. Oluba
    • Food Science and Preservation
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    • v.31 no.3
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    • pp.394-407
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    • 2024
  • The poultry industry faces disposal difficulty in waste, but recent advancements in material science and sustainability have enabled the innovative transformation of waste into valuable resources. In this study, eggshell (EC) was added as a bio-filler to gum Arabic (GA) to fabricate a GA-EC bio-composite film. Bio-composites containing 0.5 g (GA-EC0.5) and 1.0 g (GA-EC1.0) EC dispersed in 30 mL of 15% GA solution were fabricated and characterized using standard analytical techniques. The GA-EC0.5 composites showed significantly higher moisture content, transparency, water solubility, and water vapor permeability but lower tensile strength and thermal stability than GA-EC1.0. Following a post-harvest wrapping of tomato fruits with the GA-EC composite films and storage at 25±2℃ for 20 days, significant (p>0.05) reductions in weight loss, pH, lycopene content, and activities of polyphenol oxidase and pectin methylesterase compared to unwrapped fruits were recorded. Adding EC to GA has enabled the fabrication of composite films with improved mechanical, barrier, and thermal properties with potential application in the post-harvest storage of tomato fruits.

Microclimatological Characteristics Observed from the Flux Tower in Gwangneung Forest Watershed (플럭스 타워에서 관측된 광릉 산림 소유역의 미기후학적 특징)

  • Choi Taejin;Lim Jong-Hwan;Chun Jung-Hwa;Lee Dongho;Kim Joon
    • Korean Journal of Agricultural and Forest Meteorology
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    • v.7 no.1
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    • pp.35-44
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    • 2005
  • Microclimate of Gwangneung forest watershed is characterized by analyzing wind, radiation, profiles of air temperature and humidity, soil and bole temperature, precipitation and soil water content measured at and around the flux tower from April 2000 to September 2003. Mountain-valley wind was prevalent due to the topographic effect with dominant wind from east during daytime and relatively weak wind from west during nighttime. Air temperature reaches its peak in July-August whereas monthly-averaged incoming shortwave radiation shows its peak in May due to summer monsoon. Albedo ranges from 0.12 to 0.16 during the growing season. Monthly-averaged bole temperature is in phase with monthly- averaged air temperature which is consistently higher. Monthly-averaged soil temperature lags behind air temperature and becomes higher with leaf fall. With the emergence of leafage in April, maximum temperature level during midday shifts from the ground surface to the crown level of 15-20m in May. Profiles of water vapor pressure show a similar shift in May but the ground surface remains as the major source of water. Vapor pressure deficit is highest in spring and lowest in winter. Monthly averaged surface soil temperatures range from 0 to 20℃ with a maximum in August. Monthly averaged trunk temperatures of the dominant tree species range from -5.8 to 21.6℃ with their seasonal variation and the magnitudes similar to those of air temperature. Annual precipitation amount varies significantly from year to year, of which >60% is from July and August. Vertical profiles of soil moisture show different characteristics that may suggest an important role of lateral movement of soil water associated with rainfall events.

Effects of Packaging Methods on Water Adsorption Rate and Shelf-life of Hot-air and Freeze Dried Garlic Slices (포장방법이 열풍 및 동결 건조마늘절편의 흡습속도와 Shelf-life 에 미치는 영향)

  • Koh, Ha-Young;Park, Hyung-Woo;Kang, Tong-Sam;Shin, Dong-Hwa
    • Korean Journal of Food Science and Technology
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    • v.20 no.3
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    • pp.380-384
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    • 1988
  • The coefficients of the hot-air and freeze dried garlic isotherms and the critical water activities of these were estimated to be 0.85-0.94 by the linear regression and 0.58-0.60 by the sensory evaluation and ${\Delta}E$ value. Water adsorption rate(K) of hot-air dried garlic packaged with $48{\mu}m$ low density polyethylene(LDPE) decreased from $0.12g\;H_2O/100g/day\;to\;0.093g\;H_2O$/100g/day with decreasing the package dimension from $0.051m^2\;to\;0.029m^2\;at\;40^{\circ}C$ and 75% RH, and that of freeze dried one decreased from $0.17g\;H_2O/100g/day\;to\;0.12g\;H_2O$/100g/day as the filling weight increased from 50g to 10g in the package of $0.051m^2$. Shelf-life of hot-air dried garlic packaged with $80{\mu}m$ LDPE were 99days at $40^{\circ}C,\;283day\;at\;30^{\circ}C\;and\;455\;days\;at\;15^{\circ}C$ in the 75% RH. The differences of water contents between predicted data with water vapor permeability of the conventional method and experimental data were 0-1.5% in the water content range of around 13-18%, but about 2 in the water content range of around 8-11%.

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Effect of Si Content on the Phase Formation Behavior and Surface Properties of the Cr-Si-Al-N Coatings (Cr-Si-Al-N 코팅의 상형성 및 표면 물성에 미치는 Si 함량의 영향)

  • Choi, Seon-A;Kim, Hyung-Sun;Kim, Seong-Won;Lee, Sungmin;Kim, Hyung-Tae;Oh, Yoon-Suk
    • Journal of the Korean institute of surface engineering
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    • v.49 no.6
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    • pp.580-586
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    • 2016
  • Cr-Si-Al-N coating with different Si content were deposited by hybrid physical vapor deposition (PVD) method consisting of unbalanced magnetron (UBM) sputtering and arc ion plating (AIP). The deposition temperature was $300^{\circ}C$, and the gas ratio of $Ar/N_2$ were 9:1. The CrSi alloy and aluminum targets used for arc ion plating and sputtering process, respectively. Si content of the CrSi alloy targets were varied with 1 at%, 5 at%, and 10 at%. The phase analysis, composition and microstructural analysis performed using x-ray diffraction (XRD) and field emission scanning electron microscopy (FESEM) including energy dispersive spectroscopy (EDS), respectively. All of the coatings grown with textured CrN phase (200) plane. The thickness of the Cr-Si-Al-N films were measured about $2{\mu}m$. The friction coefficient and removal rate of films were measured by a ball-on-disk test under 20N load. The friction coefficient of all samples were 0.6 ~ 0.8. Among all of the samples, the removal rate of CrSiAlN (10 at% Si) film shows the lowest values, $4.827{\times}10^{-12}mm^3/Nm$. As increasing of Si contents of the CrSiAlN coatings, the hardness and elastic modulus of CrSiAlN coatings were increased. The morphology and composition of wear track of the films was examined by scanning electron microscopy (SEM) and energy dispersive spectroscopy, respectively. The surface energy of the films were obtained by measuring of contact angle of water drop. Among all of the samples, the CrSiAlN (10 at% Si) films shows the highest value of the surface energy, 41 N/m.