• Title/Summary/Keyword: water electrolysis system

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Development of Water Treatment Device By Fluidization Electrolysis Using Granular Ceramics

  • Ishikawa, Katsumi;Tamura, Rokurou;Shuto, Rika;Miyawaki, Jinuchi;Tanabe, Kimiko
    • Proceedings of the Korean Society for Agricultural Machinery Conference
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    • 1996.06c
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    • pp.737-745
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    • 1996
  • In recent years, with the increase in the consumption of natural resources and energy, global environmental problems have appeared. This is a very serious environmental load on worldwide food production. For this reason, innovative techniques for production of low entropy by using effectively the energy for the ecosystemic agriculture have been expected. In this study, granular ceramics of 2 to 3mm in diameter having electrical charges at the surface were produced, using the natural raw materials of silicate minerals haing excellent moldabilities and sintering properties . Production of water having functions was attempted by effective use of the electrochemical energy of the ceramics with an efficient water treatment apparatus in which the ceramics were fluidized in water, differently from conventional systems. In the experimental results, the EC of water treated with the ceramics was not changed, but the ORP and also the pH and the DO were changed. The speed of oxidation -re uction reaction was high, and the ceramics -treated water enhanced the vigor of seeds. It can be expected that this treatment system, by which the ORP of water can be moderately controlled, is advantageous in controlling the growth of plants.

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Development of a Fault Diagnosis Model for PEM Water Electrolysis System Based on Simulation (시뮬레이션 기반 PEM 수전해 시스템 고장 진단 모델 개발)

  • TEAHYUNG KOO;ROCKKIL KO;HYUNWOO NOH;YOUNGMIN SEO;DONGWOO HA;DAEIL HYUN;JAEYOUNG HAN
    • Transactions of the Korean hydrogen and new energy society
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    • v.34 no.5
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    • pp.478-489
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    • 2023
  • In this study, fault diagnosis and detection methods developed to ensure the reliability of polymer electrolyte membrane (PEM) hydrogen electrolysis systems have been proposed. The proposed method consists of model development and data generation of the PEM hydrogen electrolysis system, and data-driven fault diagnosis learning model development. The developed fault diagnosis learning model describes how to detect and classify faults in the sensors and components of the system.

Development of Ballast Water Treatment Technology (Feasibility Study of NaOCl Produced by Electrolysis) (밸러스트수 처리기술개발 I (해수전해법의 적용가능성 연구))

  • Yoon, B.S.;Rho, J.H.;Kim, K.I.;Park, K.S.;Kim, H.R.
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.8 no.4
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    • pp.174-178
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    • 2005
  • Destruction of marine ecology system induced by the bal last water discharged from ships is one of the most serious problem among the various ship associated environmental impacts. International Maritime Organization (IMO) has actively dealt with this problem for a long time and is going to start to activate very strong international treatment for preventing ocean from such serious environmental impact. Various technologies of ballast water treatment are now being developed all over the world. In this paper, recent trend of existing ballast water treatment technologies is investigated in detail. Furthermore, in order to apply electrolysis technology to ballast wale r treatment, its basic principle is reviewed theoretically and its feasibility is checked through some in-situ experiments. Quite good results are shown in the experiments enough to confirm its applicability in ballast water treatment.

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Application of Response Surface Methodology to Optimize the Performance of the Electro-Chlorination Process (전기분해 염소소독공정의 반응표면분석법을 이용한 차아염소산나트륨 발생 최적화)

  • Ju, Jaehyun;Park, Chan-gyu
    • Journal of Environmental Health Sciences
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    • v.48 no.3
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    • pp.167-175
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    • 2022
  • Background: Disinfection is essential to provide drinking water from a water source. The disinfection process mainly consists of the use of chlorine and ozone, but when chlorine is used as a disinfectant, the problem of disinfection by-products arises. In order to resolve the issue of disinfection by-products, electro-chlorination technology that produces chlorine-based disinfectants from salt water through electrochemical principles should be applied. Objectives: This study surveys the possibility of optimally producing active chlorine from synthetic NaCl solutions using an electro-chlorination system through RSM. Methods: Response surface methodology (RSM) has been used for modeling and optimizing a variety of water and wastewater treatment processes. This study surveys the possibility of optimally producing active chlorine from synthetic saline solutions using electrolysis through RSM. Various operating parameters, such as distance of electrodes, sodium chloride concentration, electrical potential, and electrolysis time were evaluated. Results: Various operating parameters, such as distance of electrodes, sodium chloride concentration, electrical potential, and electrolysis time were evaluated. A central composite design (CCD) was applied to determine the optimal experimental factors for chlorine production. Conclusions: The concentration of the synthetic NaCl solution and the distance between electrodes had the greatest influence on the generation of hypochlorite disinfectant. The closer the distance between the electrodes and the higher the concentration of the synthetic NaCl solution, the more hypochlorous acid disinfectant was produced.

Ionomer Binder in Catalyst Layer for Polymer Electrolyte Membrane Fuel Cell and Water Electrolysis: An Updated Review (고분자 전해질 연료전지 및 수전해용 촉매층의 이오노머 바인더)

  • Park, Jong-Hyeok;Akter, Mahamuda;Kim, Beom-Seok;Jeong, Dahye;Lee, Minyoung;Shin, Jiyun;Park, Jin-Soo
    • Journal of the Korean Electrochemical Society
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    • v.25 no.4
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    • pp.174-183
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    • 2022
  • Polymer electrolyte fuel cells and water electrolysis are attracting attention in terms of high energy density and high purity hydrogen production. The catalyst layer for the polymer electrolyte fuel cell and water electrolysis is a porous electrode composed of a precious metal-based electrocatalyst and an ionomer binder. Among them, the ionomer binder plays an important role in the formation of a three-dimensional network for ion conduction in the catalyst layer and the formation of pores for the movement of materials required or generated for the electrode reaction. In terms of the use of commercial perfluorinated ionomers, the content of the ionomer, the physical properties of the ionomer, and the type of the dispersing solvent system greatly determine the performance and durability of the catalyst layer. Until now, many studies have been reported on the method of using an ionomer for the catalyst layer for polymer electrolyte fuel cells. This review summarizes the research results on the use of ionomer binders in the fuel cell aspect reported so far, and aims to provide useful information for the research on the ionomer binder for the catalyst layer, which is one of the key elements of polymer electrolyte water electrolysis to accelerate the hydrogen economy era.

Sterilization of Seawater for the Ballast Water Management System (선박평형수 관리시스템을 위한 해수 살균법)

  • YUN, YONGSUP;CHOI, JONGBEOM;KANG, JUN;LEE, MYEONGHOON
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2016.11a
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    • pp.172-172
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    • 2016
  • The International Maritime Organization(IMO) adopted the International Convention for the Control and Management of Ships' Ballast Water and Sediments in 2004 to prevent the transfer of aquatic organisms via ballast water. Forty ballast water treatment systems were granted final approval. A variety of techniques have been developed for ballast water treatment including UV treatment, indirect or direct electrolysis, ozone treatment, chemical compounds and plasma-arc method. In particular, using plasma and ozone nano-bubble treatments have been attracted in the fields. However, these treatment systems have a problem such as remained toxic substance, demand for high power source, low efficiency, ets. In this paper, we present our strilization results obtained from membrane type electrolytic-reduction treatment system The core of an electrolysis unit is an electrochemical cell, which is filled with pure water and has two electrodes connected with an external power supply. At a certain voltage, which is called critical voltage, between both electrodes, the electrodes start to produce hydrogen gas at the negatively biased electrode and oxygen gas at the positively biased electrode. The amount of gases produced per unit time is directly related to the current that passes through the electrochemical cell. From the results, we could confirm the sterilization effect of bacteria such as S. aureus, E. Coli and demonstrate the mechanism of sterilization phenomena by electrolytic-reduction treatment system.

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Reduction of Deposits on the Electrode by the Cell Modification in Direct Sea Water Electrolysis System (해수전해장치 전해조 개선에 의한 전극 부착물 저감)

  • Park, Seung-Soo;Kim, Ki-Hyoung;An, Hi-Soo;Park, Kwang-Kyu;Lee, Tae-Won
    • Applied Chemistry for Engineering
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    • v.16 no.4
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    • pp.563-569
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    • 2005
  • In a direct sea water electrolysis system, deposits on the electrode cause decrease in the performance and increase in electrode damage. To reduce the deposition on the electrode, the modified cells were developed, namely: replaced grating type anodes with plate type ones; reduced the number of anodes from 9 to 8; widened the electrode gap from 2.4 mm to 3.0 mm; and reduced the number of spacers. that maintained the electrode gap, from 27 to 10. The developed cells were installed and tested at a power plant. The modified cells reduced deposition by 36~60%. The current efficiency increased by 15~20%. The electricity consumption reduced by 20%. In each case, the comparisons were between the modified cells and standard cells.

Output Voltage Control Technique Using Current Forward Compensation for Phase Shifted Full Bridge Converter Without Output Capacitor (출력 커패시터가 없는 위상천이 풀브릿지 컨버터의 전류 전향 보상을 이용한 출력 전압 제어 기법)

  • Shin, You-Seung;Baek, Seung-Woo;Kim, Hag-Wone;Cho, Kwan-Yual;Kang, Jeong-Won
    • The Transactions of the Korean Institute of Power Electronics
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    • v.27 no.1
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    • pp.40-47
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    • 2022
  • At present, the low-voltage, high-current type power supply is mainly used for effective sterilization in the ballast water treatment system. Research on PSFB converters without output capacitors has been ongoing. Such converters effectively treat ballast water without a separate disinfectant through electric pulses by applying a pulse-type power to the output electrode without an output capacitor. However, in the case of the pulse-type electrolysis treatment method, voltage overshoot can occur due to abrupt voltage fluctuations when the load changes, resulting in circuit reliability problems because of the output capacitorless system. Therefore, a new voltage control algorithm is required. In this paper, we will discuss voltage control for pulsed electrolysis topology without an output capacitor. The proposed voltage control method has been verified using Simulation and experiment. The usefulness of the proposed control method has been proven by the experimental results.

Quality Characteristics during Storage of Ginseng Washed by Different Methods (세척방법에 따른 인삼의 저장 중 품질특성)

  • Lee, Hyun-Seok;Cha, Hwan-Soo;Kim, Byeong-Sam;Kwon, Ki-Hyun
    • Food Science and Preservation
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    • v.16 no.3
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    • pp.342-347
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    • 2009
  • We sought to improve the methods for washing fresh raw ginseng. The quality of ginseng surface-washed by different methods was evaluated during storage at 10C and $20^{\circ}C$. The raw ginseng surface-washing method was a full-cone spray-type procedure using water and air. The water for decontamination had an electrolysis value of 80 ppm, also known as electrolysis water $2^{\circ}C$ water and water containing 5 ppm chlorine dioxide, were also used for decontamination. The Hunter color (${\Delta}E$) of ginseng washed with water withan electrolysis value of 80 ppm, or water with 5 ppm chlorine dioxide, was greater than that seen after other washing methods were used. The weight loss after washing with 5 ppm chlorine dioxide water was similar to that seen after washing with $2^{\circ}C$ water or 80 ppm electrolysis water. Reductions in total microorganism levels, and counts of yeasts and molds, assayed 10 days after washing with 5 ppm chlorine dioxide water were greater than seen after use of other sterilization methods. Quality maintenance on storage, at both 10C and 20C, after washing with 80 ppm electrolysis water, was better than that noted after other sterilization methods. The moisture content of washed ginseng was similar under all storage conditions tested.

A Study on Phosphorus Removal Effects Per Iron Surface Area in FNR Process (철전기분해장치(FNR)에서 철판의 표면적이 인제거에 미친 영향에 관한 연구)

  • Kim, Young-Gyu
    • Journal of Environmental Health Sciences
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    • v.38 no.6
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    • pp.568-574
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    • 2012
  • Objectives: The purpose of this experiment is to understand the phosphorus removal ratio effects of iron plates per unit of surface area through the iron electrolysis system, which consists of an anoxic basin, aerobic basin, and iron precipitation apparatus. Methods: Iron electrolysis, which uses an iron precipitation reactor in anoxic and oxic basins, consisted of iron plates with total areas of 400 $cm^2$, 300 $cm^2$ and 200 $cm^2$ respectively. The FNR process was operated with a hydraulic retention time and a sludge retention time of 12 hours and three days, respectively. Wastewater used in the experiments was prepared by dissolving $KH_2PO_4$ in influent water. Results: The iron plates 400 $cm^2$ (16.6 $mA/cm^2$), 300 $cm^2$ (13.3 $mA/cm^2$) and 200 $cm^2$ (7.3 $mA/cm^2$) in surface area in the phosphorus reactor had respective phosphorus of 2.4 mg/l, 2.7 mg/l and 3.2 mg/l in the effluent and phosphorus removal respective efficiencies of 90.3%, 89.1% and 87.1%. The effluent in the reactor, where the iron plate was not used, had relatively very low phosphorus removal efficiency showing phosphorus concentration of 15.3 mg/l and a phosphorus removal efficiency about 38.3%. Phosphorus removal per ferrous was 0.472 mgP/mgFe in the iron electrolysis system where the surface area of iron was low. Phosphorus pollution load per active surface area and the phosphorus removal efficiency had an interrelation of RE = -0.27LS + 89.0 (r = 0.85). Conclusion: With larger iron plate surface area, the elution of iron concentration and phosphorus removal efficiency was higher. The removal efficiency of phosphorus has decreased by increasing the initial phosphate concentration in the iron electrodes. This shows a tendency of decreasing phosphorus removal efficiency because of decreasing of iron deposition as the phosphorus pollution load per active surface area increases.